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An Experimental Investigation on the Durability of Clay-Bearing Rocks in Different pH Conditions

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Abstract

Rocks containing clay minerals are the most important and applicable problematic weak rocks. Considering the critical role of these rocks in engineering projects, various test methods have been introduced for assessing their durability. In the current research, various tests were carried out on eight samples of clay-bearing rocks to evaluate their durability properties under different pH conditions. For this purpose, some of their mechanical and physical characteristics were measured. Next, three durability tests including the dynamic slake durability test (ID), static slaking test (Is), and jar slake test (R values) were performed. Three solutions with pH values of 3, 5, and 7 were prepared by sulfuric acid for studying the pH impact on the disintegration of the studied rocks. Eventually, the slake durability test was performed at the aforementioned pH levels for up to 10 cycles. Based on the obtained results, it was concluded that the durability index decreases upon decreasing the pH value. The rock samples used in this study exhibited a remarkable durability reduction of ~ 100% at pH of 3. Moreover, simple regression analysis results revealed a statistically significant relationship between ID, Is, and R value.

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Data Availability

The datasets generated during and/or analysed during the current study are available from the corresponding author on reasonable request.

References

  • Ahmed L, Akram MS (2022) Durability based classification and characterization of the rocks of the sub-Himalayas, Pakistan. Geotech Geol Eng 40:4069–4081. https://doi.org/10.1007/s10706-022-02140-7

    Article  Google Scholar 

  • Arman H (2021a) Correlation of uniaxial compressive strength with indirect tensile strength (Brazilian) and 2nd cycle of slake durability index for evaporitic rocks. Geotech Geol Eng 39(2):1583–1590. https://doi.org/10.1007/s10706-020-01578-x

    Article  Google Scholar 

  • Arman H (2021b) Effects of slaking fluid pH on the index properties of carbonate rocks. Geotech Geol Eng 39:5843–5855. https://doi.org/10.1007/s10706-021-01870-4

    Article  Google Scholar 

  • Arman H, Hussein S, Abouhaligah HEY, Osman M, Abdirahman Hag DB, Ali Agaishi AH (2019) Predicting weathering characteristics of carbonate rocks under different geo-environmental conditions, IOP conference series. Earth Environ Sci 362(012016):1–14

    Google Scholar 

  • Arman H, Abdelghany O, Saima MA et al (2021a) Slaking behavior of evaporitic rocks from Abu Dhabi area, united Arab Emirates. Arab J Geosci 14:924

    Article  Google Scholar 

  • Arman H, Saima MA, Abdelghany O, Paramban S (2021b) Comparative study on degradability characteristics of evaporitic and carbonate rocks from Al Ain, united Arab Emirates. IOP Conf Ser Earth Environ Sci 906(1):012130. https://doi.org/10.1088/1755-1315/906/1/012130

    Article  Google Scholar 

  • ASTM C-830 (2000) Standard test methods for apparent porosity, liquid absorption, apparent specific gravity, and bulk density of refractory shapes by vacuum pressure. American Society for Testing and Materials, West conshohocken, PA 19.

  • ASTM D-4644 (1990) Standard test method for slake and durability of shales and similar weak rocks, In: Annual Book of ASTM Standards: American Society for Testing and Materials, Philadelphia, 4.08:863–865.

  • Bell FG (1993) Durability of carbonate rock as building stone with comments on its preservation. Environ Geol 21:187–200

    Article  Google Scholar 

  • Bell FG, Entwisle DC, Culshaw MG (1997) A geotechnical survey of some British coal measures mudstones, with particular emphasis on durability. Eng Geol 46:115–129

    Article  Google Scholar 

  • Beyhan S, Özgür A, and Özdemir M (2020) Effect of pH value of the testing liquid on the slake durability of marl. Paper presented at the ISRM International Symposium - EUROCK 2020, physical event not held, June 2020.

  • Deo P (1972) Shales as embankment materials. Dissertation, University of Purdue

  • Dick JC, Shakoor A, Wells N (1994) Geological approach toward developing a mudrock durability classification system. Can Geotech J 31:17–27

    Article  Google Scholar 

  • Edy Tonnizam M, Rosli S, Alavi Nezhad SV (2011) Durability assessment of weak rock by using jar slaking test. Electron J Geotech Eng 16:1319–1335

    Google Scholar 

  • Erguler ZA, Shakoor A (2009) Relative contribution of various climatic processes in disintegration of clay-bearing rocks. Eng Geol 108:36–42

    Article  Google Scholar 

  • Erguler ZA, Ulusay R (2009) Assessment of physical disintegration characteristics of clay-bearing rocks: disintegration index test and a new durability classification chart. Eng Geol 105:11–19

    Article  Google Scholar 

  • Erguler ZA (2007) Investigation of the effect of water content on engineering behavior of the clay-bearing rocks. Dissertation, University of Hacettepe

  • Franklin JA (1983) Evaluation of shales for construction projects: an Ontario shale rating system: Report RR 229. Research and Development Branch Ministry of Transportation and Research, Toronto

    Google Scholar 

  • Franklin JA, Chandra A (1972) The slake-durability test. Int J Rock Mech Min Sci 9:325–341

    Article  Google Scholar 

  • Gamble JC (1971) Durability-Plasticity classification of shales and other argillaceous rocks. Dissertation, University of Illinois

  • Gautam TP, Shakoor A (2016) Comparing the slaking of clay-bearing rocks under laboratory conditions to slaking under natural climatic conditions. Rock Mech Rock Eng 49:19–31

    Article  Google Scholar 

  • Gautam TP, Shakoor A (2017) A Durability classification of clay-bearing rocks based on particle size distribution of slaked material. Environ Eng Geosci 23:125–136

    Article  Google Scholar 

  • Ghobadi M, Mousavi S (2014) The effect of pH and salty solutions on durability of sandstones of the Aghajari formation in Khouzestan province, southwest of Iran. Arab J Geosci 7:641–653

    Article  Google Scholar 

  • Ghobadi MH, Mousavai S (2017) The influence of pH of water and chemical composition on the durability of different rocks from the Qom formation, East and Northeast of Hamedan, Iran. J Eng Geol 10(4):3699–3718

  • Gokceoglu C, Ulusay R, Sonmez H (2000) Factors affecting the durability of selected weak and clay-bearing rocks from Turkey, with particular emphasis on the influence of the number of drying and wetting cycles. Eng Geol 57:215–237

    Article  Google Scholar 

  • Gupta V, Ahmed I (2007) The effect of pH of water and mineralogical properties on the slake durability (degradability) of different rocks from the Lesser Himalaya, India. Eng Geol 95:79–87

    Article  Google Scholar 

  • He MC, Zhou L, Li DJ, Wang CG, Nie W (2008) Experimental research on hydrophilic characteristics of mudstone in deep well. Chin J Rock Mechan Eng 27:1113–1120

    Google Scholar 

  • Heidari M, Rafie B, Mohebi Y, Torabi-Kave M (2015) Assessing the behavior of clay-bearing rocks using static and dynamic slaking indices. Geotech Geol Eng 33:1017–1030

    Article  Google Scholar 

  • International Society for Rock Mechanics (ISRM) (1981), ISRM suggested methods: rock characterization, testing and monitoring. In: Brown ET (ed) Pergamon Press, London, pp 211

  • Johnson RB, De Graff JV (1988) Principles of engineering geology. Wiley, Newyork, p 497

    Google Scholar 

  • Kalyoncu Erguler G (2021) The failure, slaking, and self-sealing behavior of clay-bearing rocks. Arab J Geosci 13:857

    Article  Google Scholar 

  • Kayabali K, Beyaz T, Kolay E (2006) The effect of the pH of the testing liquid on the slake durability of gypsum. Bull Eng Geol Env 65:65–71

    Article  Google Scholar 

  • Koncagul EC, Santi PM (1999) Predicting the unconfined compressive strength of the Breathitt shale using slake durability, Shore hardness and rock structural properties. Intern J Rock Mechan and Min Sci 36(2):139–153

  • Liu W, Zhang ZH (2020) Experimental characterization and quantitative evaluation of slaking for strongly weathered mudstone under cyclic wetting-drying condition. Arab J Geosci 13:65

    Article  Google Scholar 

  • Loanna L, Dimitrios R, Theodora P, Paris T (2009) Geotechnical and mineralogical properties of weak rocks from central greece. Central Eur J Geosci 1:431–442

    Google Scholar 

  • Moon VG, Beattie AG (1995) Textural and microstructural influences on the durability of Waikato coal measures mudrocks. Q J Eng GeolHydrogeol 28:303–312

    Article  Google Scholar 

  • Nadeesha H, Koralegedara NH, Maynard JB (2017) Chemical, mineralogical and textural properties of the Kope formation mudstones: how they affect its durability. Eng Geol 228:312–322

    Article  Google Scholar 

  • Ozdogan MV (2020) Effects of pH of testing liquid on the degradation of rocks. Geotech Test J 43:1120–1129

    Article  Google Scholar 

  • Sadisun IA, Shimada H, Ichinose M, Matsui K (2005) Study on the physical disintegration characteristics of Subang claystone subjected to a modified slaking index test. Geotech Geol Eng 23:199–218

    Article  Google Scholar 

  • Sadisun IA, Shimada H, Ichinose M, Matsui K (2002) Evaluation of physical deterioration of slake-prone rock subjected to static slaking test. In: The 11th Japan national symposium for rock mechanics

  • Santi PM (1998) Improving the jar slake, slake index, and slake durability tests for shales. Environmental Engineering Geosciences 4:385–396

    Article  Google Scholar 

  • Santi PM (1995) Classification and testing of weak and weathered rock materials: a model based on Colorado shales: unpublished Ph.D. Dissertation. Colorado School of Mines, Golden, CO.

  • Singh TN, Verma AK, Singh V, Sahu A (2005) Slake durability study of shaly rock and its predictions. Environ Geol 47:246–253

    Article  Google Scholar 

  • Singh TN, Sharma PK, Khandelwal M (2006) Effect of pH on the physico-mechanical properties of marble. Bull Eng Geol Env 66:81–87

    Article  Google Scholar 

  • Taylor RK (1988) Coal measures mudrocks: composition, classification and weathering processes. Q J Eng GeolHydrogeol 21:85–99

    Article  Google Scholar 

  • Wood LE, Deo P (1975) A suggested system for classifying shale materials for embankment. Bull Eng Geol Env 12:39–55

    Google Scholar 

  • Yagiz S (2018) The effect of pH of the testing liquid on the degradability of carbonate rocks. Geotech Geol Eng 36:2351–2363

    Article  Google Scholar 

  • Zhou CY, Tan XS, Deng YM, Zhang LM, Wang JH (2005) Research on softening micro-mechanism of special soft rocks. Chin J Rock Mechan Eng 24:394–400

    Google Scholar 

Download references

Acknowledgements

The authors would like to thank the Faculty of Science, Bu-Ali Sina University for the financial supports. Also, the collaboration of Kermanshah Province Gas Company is gratefully acknowledged.

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The authors have no relevant financial or non-financial interests to disclose.

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Authors and Affiliations

  1. Department of Geology, Faculty of Sciences, Bu-Ali Sina University, Hamedan, Iran

    Naser Mehdiabadi & Gholamreza Khanlari

  2. Department of Geology, Faculty of Sciences, Lorestan University, Khoramabad, Iran

    Yasin Abdi

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  1. Naser Mehdiabadi
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  2. Yasin Abdi
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  3. Gholamreza Khanlari
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Correspondence to Yasin Abdi.

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Mehdiabadi, N., Abdi, Y. & Khanlari, G. An Experimental Investigation on the Durability of Clay-Bearing Rocks in Different pH Conditions. Geotech Geol Eng 41, 2645–2663 (2023). https://doi.org/10.1007/s10706-023-02418-4

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