At present, lithium-ion batteries (LIBs) with excellent performance have attracted the attention of the industry, but there are still many fire and explosion risks, threatening the safety of human life and property. Therefore, as the last barrier, fire extinguishing is important and the performance of fire extinguishing device determines the ultimate fire extinguishing effect. In this study, a plunger type perfluorohexanone (C6F12O) fire extinguishing device was developed, and key components such as gas generating device and puncture valve were improved. The 271 Ah lithium iron phosphate battery was used to verify the fire extinguishing efficiency and environmental adaptability of this device in extreme environments. The results show that in the three groups of fire extinguishing experiments at normal temperature NT, − 40°C and 85°C, the time from the start of spraying to extinguishing the open fire is 11 s, 14 s and 9 s respectively, indicating that the fire extinguishing efficiency is good in extreme environments. Additionally, no re-ignition occurred and the safety valves of the other batteries did not open. The environment temperature didn’t exceed 90°C within 30 min after the fire was extinguished. The device can be started normally in extreme environments, which indicates the good environmental adaptability of the fire extinguishing device.
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Kulova TL, Fateev VN, Seregina EA, Grigoriev AS (2020) A brief review of post-lithium-ion batteries. Int J Electrochem Sci 15:7242–7259. https://doi.org/10.20964/2020.08.22
Schipper F, Aurbach D (2016) A brief review: past, present and future of lithium ion batteries. Russ J Electrochem 52:1095–1121. https://doi.org/10.1134/S1023193516120120
Xi ZW, Zhang X, Ma YS, Zhou C, Yang J, Wu YQ, Li XJ, Luo YF, Chen DY (2018) Recent progress in flexible fibrous batteries. ChemElectroChem 5:3127–3137. https://doi.org/10.1002/celc.201800741
Ma S, Jiang MD, Tao P, Song CY, Wu JB, Wang J, Deng T (2018) Temperature effect and thermal impact in lithium-ion batteries: a review. Prog Nat Sci Mater 28:653–666. https://doi.org/10.1016/j.pnsc.2018.11.002
Lu LG, Han XB, Li JQ, Hua JF, Ouyang MG (2013) A review on the key issues for lithium-ion battery management in electric vehicles. J Power Sources 226:272–288. https://doi.org/10.1016/j.jpowsour.2012.10.060
He W, Guo WB, Wu HL, Lin L, Liu Q, Han X, Xie QS, Liu PF, Zheng HF, Wang LS, Yu XQ, Peng DL (2021) Challenges and recent advances in high capacity Li-rich cathode materials for high energy density lithium-ion batteries. Adv Mater 33:1–35. https://doi.org/10.1002/adma.202005937
Tarascon JM, Armand M (2001) Issues and challenges facing rechargeable lithium batteries. Nature 414:359–367. https://doi.org/10.1038/35104644
Yao PH, Yu HB, Ding ZY, Liu YC, Lu J, Lavorgna M, Wu JW, Liu XJ (2019) Review on polymer-based composite electrolytes for lithium batteries. Front Chem 7:1–17. https://doi.org/10.3389/fchem.2019.00522
Wang QS, Mao BB, Stoliarov SI, Sun JH (2019) A review of lithium ion battery failure mechanisms and fire prevention strategies. Prog Energy Combust Sci 73:95–131. https://doi.org/10.1016/j.pecs.2019.03.002
Liu PJ, Liu CQ, Yang K, Zhang MJ, Gao F, Mao BB, Li H, Duan QL, Wang QS (2020) Thermal runaway and fire behaviors of lithium iron phosphate battery induced by over heating. J Energy Storage 31:1–10. https://doi.org/10.1016/j.est.2020.101714
Said AO, Stoliarov SI (2021) Analysis of effectiveness of suppression of lithium ion battery fires with a clean agent. Fire Saf. J 121:103296. https://doi.org/10.1016/j.firesaf.2021.103296
Liu YJ, Duan QL, Xu JJ, Li H, Sun JH, Wang QS (2020) Experimental study on a novel safety strategy of lithium-ion battery integrating fire suppression and rapid cooling. J Energy Storage 28:1–9. https://doi.org/10.1016/j.est.2019.101185
Yuan S, Chang CY, Yan SS, Zhou P, Qian XM, Yuan MQ, Liu K (2021) A review of fire-extinguishing agent on suppressing lithium-ion batteries fire. J Energy Chem 62:262–280. https://doi.org/10.1016/j.jechem.2021.03.031
Wang QS, Ping P, Zhao XJ, Chu GQ, Sun JH, Chen CH (2012) Thermal runaway caused fire and explosion of lithium ion battery. J Power Sources 208:210–224. https://doi.org/10.1016/j.jpowsour.2012.02.038
Wang QS, Shao GZ, Duan QL, Chen M, Li YQ, Wu K, Liu BJ, Peng P, Sun JH (2016) The efficiency of heptafluoropropane fire extinguishing agent on suppressing the lithium titanate battery fire. Fire Technol 52:387–396. https://doi.org/10.1007/s10694-015-0531-9
Lisbona D, Snee T (2011) A review of hazards associated with primary lithium and lithium-ion batteries. Process Saf Environ 89:434–442. https://doi.org/10.1016/j.psep.2011.06.022
Liu YJ, Duan QL, Xu JJ, Chen HD, Lu W, Wang QS (2018) Experimental study on the efficiency of dodecafluoro-2-methylpentan-3-one on suppressing lithium-ion battery fires. RSC Adv 8:42223–42232. https://doi.org/10.1039/c8ra08908f
Linteris GT (2011) Clean agent suppression of energized electrical equipment fires. Fire Technol 47:1–68. https://doi.org/10.1007/s10694-009-0109-5
Liu YJ, Yang K, Zhang MJ, Li S, Gao F, Duan QL, Sun JH, Wang QS (2022) The efficiency and toxicity of dodecafluoro-2-methylpentan-3-one in suppressing lithium-ion battery fire. J Energy Chem 65:532–540. https://doi.org/10.1016/j.jechem.2021.05.043
Pagliaro JL, Linteris GT (2017) Hydrocarbon flame inhibition by C6F12O (Novec 1230): unstretched burning velocity measurements and predictions. Fire Saf J 87:10–17. https://doi.org/10.1016/j.firesaf.2016.11.002
Taniguchi N, Wallington TJ, Hurley MD, Guschin AG, Molina LT, Molina MJ (2003) Atmospheric chemistry of C2F5C(O)CF(CF3)2: photolysis and reaction with Cl atoms, OH radicals and ozone. J Phys Chem A 107:2674–2679. https://doi.org/10.1021/jp0220332
Xing HR, Lu S, Yang H, Zhang HP (2022) Review on research progress of C6F12O as a fire extinguishing agent. Fire Switzerland 5:1–20. https://doi.org/10.3390/fire5020050
Wang QS, Li K, Wang Y, Chen HD, Duan QL, Sun JH (2018) The efficiency of dodecafluoro-2-methylpentan-3-one on suppressing the lithium ion battery fire. J Electrochem Energy 15:1–10. https://doi.org/10.1115/1.4039418
Association NFP (2000) NFPA 2001 standard on clean agent fire extinguishing systems. Association NFP, Quincy
GB/T 2423.2–2008 (2009) Environmental testing—part 2: test methods—tests B: dry heat
CCCF/XFJJ-01 (2018) Technical specifications for fire prevent and control equipment for lithium ion battery cabin of electric bus
Zhai HJ, Chi MS, Li JY, Li DF, Huang ZH, Jia ZZ, Sun JH, Wang QS (2022) Thermal runaway propagation in large format lithium ion battery modules under inclined ceilings. J Energy Storage 51:104477. https://doi.org/10.1016/j.est.2022.104477
This work is supported by the National Key R&D Program of China (No.2021YFB2402003), the Key Research and Development Plan of Anhui Province (No. 202104a07020003), the China Postdoctoral Science Foundation (No. 2022T150615). Dr. Q.S Wang is supported by Youth Innovation Promotion Association CAS (No. Y201768).
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Liang, C., Jin, K., Liu, P. et al. The Efficiency of Perfluorohexanone on Suppressing Lithium-Ion Battery Fire and Its Device Development. Fire Technol (2023). https://doi.org/10.1007/s10694-023-01365-z
- Lithium-ion battery safety
- Fire extinguishing device