Aspects of implementing the homophasic free-radical synthesis in DMSO of a fiber-forming tercopolymer (FTP) based on acrylonitrile, methacrylate, and 2-acrylamide-2-methylpropanesulfonic acid with a given intrinsic viscosity are considered. The macrokinetic process parameters, yield, and intrinsic viscosity of the FTP as a function of the initiator content in the reaction solution are established. General and distinguishing features of the FTP syntheses in DMSO and DMF are discussed.
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References
B. E. Geller, Khim. Volokna, No. 3, 3-11 (2002).
O. I. Gladunova and A. A. Lysenko, Kompoz. Mir, No. 3, 28-33 (2021).
A. S. Kolobkov and S. S. Malakhovskii, Khim. Volokna, No. 5, 3-7 (2020),
L. A. Shcherbina, P. V. Chvirov, et al., in: Proceedings of the Conference “Fibers and fibrous materials for special uses. Research and development.” Collection of Papers [in Russian], Jul. 14, 2015, Minsk, pp. 30-34.
L. A. Shcherbina, “Development and synthesis of fiber-forming tercopolymer of acrylonitrile in a hydrotropic solvent,” Candidate Dissertation in Textile Science, May 17, 2006, MGUP, Minsk, 2002, 161 pp.
M. M. Iovleva, V. N. Smirnova, and G. A. Budnitskii, Fiber Chem., 33, No. 4, 262-264 (2001); doi: https://doi.org/10.1023/A:1012934313303.
B. E. Geller, K. I. Kaminskii, and L. A. Shcherbina, in: Proceedings of the IInd Belarusian Scientific-Practical Conference “Scientific and technical problems with the development of the chemical fiber industry in Belarus” [in Russian], MGTI, Mogilev, Dec. 15-16, 2001, pp. 136-146.
Kh. S. Bagdasarˆ yan, Theory of Radical Polymerization: Monograph [in Russian], Akademiya Nauk, Moscow, 1959, 296 pp.
A. A. Geller, B. E. Geller, and L. A. Shcherbina, Polymeric Compounds, in 2 parts/Part 2: Synthesis and Modification of Fiber-forming Polymers [in Russian], MGUP, Mogilev, 2016, 192 pp.
B. E. Geller, A. A. Geller, and V. G. Chirtulov, Practical Guide on the Physical Chemistry of Fiber-forming Polymers. Study Aide for Higher Educational Institutions [in Russian], 2nd Ed., Revised and Supplemented, Khimiya, Moscow, 1996, 432 pp.
P. J. Flory, Principles of Polymer Chemistry, J. Wiley & Sons, New York, 1953, 324 pp.
Kh. S. Bagdasarˆ yan, Theory of Radical Polymerization [in Russian], Nauka, Moscow, 1966, 300 pp.
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Translated from Khimicheskie Volokna, No. 5, pp. 11-19, September—October, 2022.
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Shcherbina, L.A., Chikunskaya, V.M., Ogorodnikov, V.A. et al. Synthesis of a Fiber-Forming Copolymer of Acrylonitrile in Dimethylsulfoxide. Fibre Chem 54, 288–295 (2023). https://doi.org/10.1007/s10692-023-10394-x
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DOI: https://doi.org/10.1007/s10692-023-10394-x