Skip to main content
SpringerLink
Log in

Synthesis of Ionizable Fiber-Forming Copolymers of Acrylonitrile and 2-Acrylamido-2-Methylpropanesulfonic Acid in DMF

  • Published:
Fibre Chemistry Aims and scope

Homogeneous synthesis of ionizable fiber-forming copolymers of acrylonitrile and 2-acrylamido-2-methylpropanesulfonic acid in DMF with the contents of the acidic comonomer varying from 20 to 50% (of the monomer mass) was investigated. The integral parameters of the empirical dynamics of copolymer synthesis were determined to simulate this process under manufacturing conditions. It was noted that 2-acrylamido-2-methylpropanesulfonic acid enhanced the process rate. The suitability of the ionizable copolymers for spinning fibrous materials from them was assessed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.

Similar content being viewed by others

References

  1. L. A. Shcherbina, E. A. Alekhina, et al., Khim. Volokna, No. 6, 31-35 (1994).

  2. B. E. Geller, L. A. Shcherbina, et al., in: Collection of Scientific Works: On the 30th Anniversary of Mogilev State University of Food Products [in Russian], Izd. Tsentr BGU, Minsk, 2003, pp. 67-72.

  3. B. E. Geller and L. A. Shcherbina, Khim. Volokna, No. 4, 18-24 (2002).

  4. V. A. Ogorodnikov, N. N. Stolyarova, and L. A. Shcherbina, Khim. Volokna, No. 4, 23-28 (2014).

  5. V. A. Ogordnikov, L. A. Shcherbina, and I. A. Budkute, Khim. Volokna, No. 4, 73-78 (2016).

  6. V. A. Ogorodnikov, L. A. Shcherbina, and V. M. Chikunskaya, Polim. Mater. Tekhnol., 4, No. 1, 47-56 (2018).

    Google Scholar 

  7. V. A. Ogorodnikov, L. A. Shcherbina, and V. M. Chikunskaya, Vestn. SPGUTD [St. Petersburg St. Univ. Technol. Des.], No. 3, 94-99 (2016).

  8. P. V. Nesteronok, E. G. Kosandrovich, et al., Vesti Nats. Akad. Nauk Resp. Belarus, Ser. Khim. Nauk, No. 4, 80-87 (2014).

  9. P. V. Nesteronok and V. S. Soldatov, Vesti Nats. Akad. Nauk Resp. Belarus, Ser. Khim. Nauk, No. 4, 72-79 (2014).

  10. D. N. Shakhidova, D. A. Gafurova, and M. G. Mukhamediev, Vestn. TaGU, Ser. Khim., No. 2, 104-110 (2018).

  11. M. V. Chertkova, E. V. Derbisher, et al., Izv. VolgGTU, No. 5 (92), 107-110 (2012).

  12. N. N. Zakharova, I. D. Zenkov, et al., Khim. Volokna, No. 2, 16-17 (1988).

  13. N. N. Zakhorova, E. S. Zashchepkina, et al., Khim. Volokna, No. 4, 16-18 (1990).

  14. M. P. Zverev, I. D. Zenkov, et al., Khim. Volokna, No. 5, 32-33 (1991).

  15. L. A. Shcherbina, Khim. Volokna, No. 6, 24-29 (2020).

  16. T. S. Yatsimirskaya and Yu. L. Spirin, Vysokomol. Soedin., Ser. A, 18, No. 8, 1850-1854 (1976).

    CAS  Google Scholar 

  17. M. D. Gol’dfein and B. A. Zyubin, Vysokomol. Soedin, Ser. A, 32, No. 11, 2243-2263 (1990).

    Google Scholar 

  18. G. P. Gladysheva and V. A. Popov, Radical Polymerization with High Degrees of Conversion [in Russian], Nauka, Moscow, 1974, 244 pp.

    Google Scholar 

  19. B. E. Geller, L. A. Shcherbina, and V. G. Chirtulov, Vesti Nats. Akad. Nauk Resp. Belarus, Ser. Khim. Nauk, No. 1, 99-105 (1998).

  20. L. A. Shcherbina, B. E. Geller, and V. G. Chirtulov, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 43, No. 5, 141-144 (2000).

    CAS  Google Scholar 

  21. L. A. Shcherbina, B. E. Geller, et al., Dokl. Nats. Akad. Nauk Belarusi, 422, No. 1, 63-66 (2008).

    Google Scholar 

  22. L. A. Shcherbina, B. E. Geller, et al., Dokl. Nats. Akad. Nauk Belarusi, 52, No. 5, 85-88 (2008).

    Google Scholar 

  23. A. S. Chegoli and N. M. Kvasha (eds.), Analytical Control of Synthetic Fiber Manufacturing. Handbook [in Russian], Khimiya, Moscow, 1982, 256 pp.

  24. A. A. Geller, B. E. Geller, and L. A. Shcherbina, Polymers [in Russian], in 2 Parts, Part 2, Synthesis and Modification of Fiber-forming Polymers [in Russian], MGUP, Mogilev, 2016, 192 pp.

  25. P. V. Chvirov, G. S. Tabunov, et al., in: Proceedings of the Third Belarusian Scientific-Practical Conference (with International Participation) “Scientific-Technical Problems in the Development of Chemical Fiber Manufacturing in Belarus” [in Russian], Mogilev, Dec. 13-15, 2006, Kontsern Belneftekhim, Mogilev-Minsk, 2007, pp. 157-161.

  26. I. D. Ivanova, G. V. Plyakin, and L. A. Shcherbina, Izv. Beloruss. Inzh. Akad., No. 1, 145-148 (2003).

  27. B. E. Geller, K. I. Kaminskii, and L. A. Shcherbina, in: Proceedings of the 2nd Belarusian Scientific-Practical Conference “Scientific-Technical Problems in the Development of Chemical Fiber Manufacturing in Belarus” [in Russian], Mogilev, Dec. 15-16, 2001, MGTI, Mogilev, 2002, pp. 136-146.

  28. L. A. Shcherbina, Candidate Dissertation in Technical Sciences, Minsk, 2002, 161 pp.

  29. Kh. S. Bagdasar’yan, Theory of Radical Polymerization [in Russian], Nauka, Moscow, 1966, 300 pp.

  30. I. S. Gorodnyakova, P. V. Chvirov, and L. A. Shcherbina, in: Proceedings of the International Scientific-Technical Conference-Seminar “Fibers and Films 2001” [in Russian], MGUP, Mogilev, 2011, pp. 173-175.

  31. N. V. Pchelova, L. A. Shcherbina, et al., Vestn. Vitebsk. Gos. Tekhnol. Univ., No. 2 (39), 118-129 (2020).

Download references

Author information

Authors and Affiliations

  1. Belorusian State University of Food and Chemical Technologies, Mogilev, Belarus

    L.A. Shcherbina

Authors
  1. L.A. Shcherbina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L.A. Shcherbina.

Additional information

Translated from Khimicheskie Volokna, No. 1, pp. 14-20, January-February, 2022.

Rights and permissions

Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shcherbina, L. Synthesis of Ionizable Fiber-Forming Copolymers of Acrylonitrile and 2-Acrylamido-2-Methylpropanesulfonic Acid in DMF. Fibre Chem 54, 14–20 (2022). https://doi.org/10.1007/s10692-022-10332-3

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10692-022-10332-3

Search

Navigation