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Sulfur-Containing Polyarylenes for Thermally and Chemically Resistant Films and Fibers

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Fibre Chemistry Aims and scope

Amorphous high-molecular-mass poly(1,4-phenylene sulfide sulfone)s with a glass-transition temperature of 206°C were synthesized via polycondensation of 4,42-dichlorodiphenyl sulfone with sodium sulfide. Fibers and films were produced by spinning from their melt. Solid-state oxidation of the sulfide bonds into sulfones directly in the film or fiber produced high-melting and insoluble chemically stable poly(1,4-phenylene sulfone) fibers and films capable of operating at temperatures up to 400°C. The physicomechanical properties of the starting films and fibers and the oxidized samples were studied.

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References

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  2. V. I. Nedel’kin, B. A. Zachernyuk, and O. B. Andrianova, Ross. Khim. Zh., 49, No. 6, 3-6 (2005).

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  4. L. N. Slesareva, E. P. Perepechkina, et al., in: First International Symposium on Chemical Fibers [in Russian], Kalinin, 1974, Proceedings, pp. 45-49.

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Authors and Affiliations

  1. A. N. Kosygin Russian State University, Moscow, Russia

    V. I. Nedel’kin & K. I. Kobrakov

  2. Moscow State University of Food Production, Moscow, Russia

    B. A. Zachernyuk & E. N. Solov’eva

Authors
  1. V. I. Nedel’kin
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  2. B. A. Zachernyuk
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  3. E. N. Solov’eva
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  4. K. I. Kobrakov
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Corresponding author

Correspondence to V. I. Nedel’kin.

Additional information

Translated from Khimicheskie Volokna, No. 6, pp. 47-49, November—December, 2021

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Nedel’kin, V.I., Zachernyuk, B.A., Solov’eva, E.N. et al. Sulfur-Containing Polyarylenes for Thermally and Chemically Resistant Films and Fibers. Fibre Chem 53, 415–417 (2022). https://doi.org/10.1007/s10692-022-10317-2

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  • DOI: https://doi.org/10.1007/s10692-022-10317-2

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