The results of physicochemical and spectroscopic investigations of deciduous sulfate cellulose at various stages of ECF bleaching are presented. Significant changes in whiteness, the content of organochlorine compounds (OCC), the intensity of absorption bands for the conjugated and unconjugated CP%O groups at the first stages of bleaching, and their stabilization at later stages are demonstrated. The weak effect of multistage bleaching on the structure of the cellulose is demonstrated. Calibration models were constructed for rapid assessment of the parameters of the OCCs and whiteness from the IR spectra.
Similar content being viewed by others
References
K. G. Bogolitsyn, Ros. Khim. Zhurn., XLVIII, No. 6, 105-123 (2004).
V. M. Glyad, N. K. Politova, D. A. Ponomarev, Khimiya Rastit. Syr’ya, No. 4, 27-30 (2009).
A. V. Koksharov, O. B. Stebunov, Proceedings of IV All-Russia Scientific Conference “Chemistry and Technology of Plant Substances” [in Russian], Ufa (2008), p.155.
A. V. Koksharov, O. B. Stebunov, Proceedings of IV All-Russia Scientific Conference “New Achievements in the Chemistry and Chemical Technology of Plant Substances” [in Russian], Barnaul (2009), p.276.
O. B. Stebunov, A. V. Koksharov, Proceedings of II International Scientific-Technical Conference “Problems of Mechanics of Pulp and Paper Materials,” Arkhangelsk (2013), p. 192.
R.T. Clapp, C.A. Truemper, et al., Tappi J., 79, No. 3, 111-113 (1996).
D. A. Sukhov, Izv. Vuzov. Tekhnol. Leg. Prom-sti, 17, No. 3, 53-56 (2012).
A. V. Fedorov, O. Yu. Derkacheva, D. A. Sukhov, Izv. Vuzov. Lesnoi. Zhurn., No. 2-3 75-81.
I. I. Osovskaya, V. S. Antonova, et al., Khim. Rastit. Syr’ya, No. 1, 13-20 (2018).
O. E. Rodionova, A. L. Pomerantsev, Uspekhi Khimii, 75, No. 4, 302–321 (2006).
A. L. Pomerantsev, O. E. Rodionova, J. Chemometrics, 26, 299-310 (2012).
The work was carried out with financial support within the framework of state project 10.6052.2017/8.9.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Khimicheskie Volokna, No. 3, pp. 72-75, May-June, 2018.
Rights and permissions
About this article
Cite this article
Koksharov, A.V., Derkacheva, O.Y., Sukhov, D.A. et al. Variation of Parameters of Organochlorine Compounds, Whiteness, and Absorption Spectra During Multistage Bleaching of Cellulose. Fibre Chem 50, 215–218 (2018). https://doi.org/10.1007/s10692-018-9963-6
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10692-018-9963-6