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Thermodynamics of Swelling in Glassy Amorphous/Crystalline Polymers in Water Vapor

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Fibre Chemistry Aims and scope

Swelling of amorphous/crystalline polymers is a complex phenomenon, accompanied by a change in the internal energy of the polymer, the absorbate, and the solid solution, and also by transition of the polymer from the glassy state to the rubbery (high elasticity) state. The derivative of the internal energy (a thermodynamic characteristic of the solid solution) is the internal pressure. The excess internal pressure is the basic characteristic of the swelling process: the swelling pressure. We have analyzed the behavior of the change in swelling pressure, the common features and differences from swelling of gels and from osmotic phenomena.

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References

  1. A. A. Tager, Physical Chemistry of Polymers [in Russian], Nauchnyi Mir, Moscow (2007). 576 pp.

  2. L. I. Surdutovich, A. A. Tager et al., Vysokomol. Soedin., 14A, No. 2, 324-330 (1972).

  3. P. J. Flory, Principles of Polymer Chemistry, Ithaca University, New York (1953). 584 pp.

  4. S. P. Papkov, The Gel State in Polymers [in Russian], Khimiya, Moscow (1974). 256 pp.

  5. G. Helfferich, Ion Exchangers [in German], Verlag Chemie, Weinheim (1959). 490 pp.

  6. Yu. A. Kokotov and V. A. Pasechnik, Equilibrium and Kinetics of Ion Exchange [in Russian], Khimiya, Leningrad (1970). 336 pp.

  7. G. E. Zaikov, A. A. Iordanskii, and V. S. Markin, Diffusion of Electrolytes in Polymers [in Russian], Khimiya, Moscow (1984). 240 pp.

  8. M. Safiollah, Modeling of Water Sorption and Swelling in Polymer Electrolyte Membranes, Simon Fraser University (2015). 70 pp.

  9. E. Ya. Denisyuk, Vysokomol. Soedin., 50A, No. 7, 1255-1268 (2008).

  10. L. Z. Rogovina, V. G. Vasil’eva, and E. E. Braudo, Vysokomol. Soedin., 50C, No. 7, 1397-1406 (2008).

  11. M. A. Lagutina, “Swelling pressure in lightly crosslinked polymer hydrogels,” Author’s Abstract, Dissertation in competition for the academic degree of Candidate of Physical and Mathematical Sciences, Inst. Khim. Fiziki RAN, Moscow (1996). 22 pp.

  12. A. P. Safronov, I. A. Kamalov et al., Vysokomol. Soedin., 54A, No. 11, 1685-1696 (2012).

  13. E. Ya. Denisyuk, Vysokomol. Soedin., 52A, No. 4, 634-645 (2010).

  14. O. E. Filippova, Vysokomol. Soedin., 42C, No. 12, 2328-2352 (2000).

    Google Scholar 

  15. M. A. Lagutina, K. S. Dubrovskii, and K. S. Kazanskii, Vysokomol. Soedin., 37B, No. 3, 528-532 (1995).

    Google Scholar 

  16. S. A. Dubrovskii, M. V. Afanas’eva et al., Vysokomol. Soedin., 32A, No. 1, 165-170 (1990).

  17. S. F. Grebennikov, N. P. Lebedeva et al., Vysokomol. Soedin., 57A, No. 5, 383-389 (2015).

  18. Ya. I. Gerasimov et al., Course in Physical Chemistry. Vol. 1 [in Russian], Khimiya, Moscow (1969). 592 pp.

  19. A. A. Askadskii and V. I. Kodrashehenko, Computer-Aided Materials Science of Polymers [in Russian], Nauchnyi Mir, Moscow (1999). 544 pp.

  20. Ya. I. Gerasimov and V. A. Geiderikh, Thermodynamics of Solutions [in Russian], MGU, Moscow (1980). 184 pp.

  21. V. V. Serpinskii and T. S. Yakubov, Izv. Akad. Nauk SSSR, Ser. Khim., No. 1, 71-76 (1981).

  22. S. P. Papkov and E. Z. Fainberg, Interaction of Cellulose and Cellulose Materials With Water [in Russian], Khimiya, Moscow (1976). 232 pp.

  23. S. F. Grebennikov and Yu. A. El’tekov, Sorption in Polymer Systems [in Russian], SPGUTD, St. Petersburg (2014). 286 pp.

  24. L. E. Klyuev, A. T. Kynin, and S. F. Grebennikov, Zh. Prikl. Khim., No. 5, 1177-1179 (1989).

  25. G. Gregor and M. Frederick, Ann. N. Y. Acad. Sci., 57, No 3, 87 (1953).

    Article  CAS  Google Scholar 

  26. E. Glueckauf, Proc. Roy. Soc., A214, 207 (1952).

    Article  Google Scholar 

  27. T. V. Smotrina and S. F. Grebennikov, Polymer Sci., 59A, No. 2, 206-214 (2017).

    Google Scholar 

  28. I. Prigogine and R. Defay, Chemical Thermodynamics, Longmans, Green, London (1954). 509 pp.

  29. D. W. van Krevelen, Properties of Polymers, Elsevier, Amsterdam (1997). 887 pp.

  30. V. V. Zhizhenkov, S. F. Grebennikov et al., Vysokomol. Soedin., 59A, No. 2, 156-164 (2017).

  31. S. F. Grebennikov, A. T. Kynin et al., Khim. Volokna, No. 4, 37-39 (1989).

  32. I. I. Perepechko and S. S. Yakovenko, Vysokomol. Soedin., 23A, No. 5, 1166-1170 (1981).

  33. S. F. Grebennikov, A. T. Kynin, and V. T. Tiranov, Izv. Vuzov Khimiya i Khim. Tekhnol., 28, No. 12, 101-103 (1985).

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Authors and Affiliations

  1. St. Petersburg State University of Industrial Technologies and Design, 18 ul. Bol’shaya Morskaya, St. Petersburg, 191186, Russia

    S. F. Grebennikov, A. N. Aitova & E. S. Abramova

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  1. S. F. Grebennikov
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  2. A. N. Aitova
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  3. E. S. Abramova
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Correspondence to S. F. Grebennikov.

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Translated from Khimicheskie Volokna, Vol. 50, No. 3, pp. 41-47, May-June, 2018.

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Grebennikov, S.F., Aitova, A.N. & Abramova, E.S. Thermodynamics of Swelling in Glassy Amorphous/Crystalline Polymers in Water Vapor. Fibre Chem 50, 179–187 (2018). https://doi.org/10.1007/s10692-018-9956-5

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