Structural transitions of Fe-containing fibrous and microcrystalline flax and hemp cellulose during heat treatment in an inert medium were studied using IR spectroscopy, x-ray diffraction, electron microscopy, thermogravimetric analysis, and N2 adsorption. Mesoporous ferromagnetic graphitecontaining carbon composites with specific surface area 280-550 m2/g were produced. The nature and shape of the cellulose matrix and the iron-salt anion were found to affect the composition, shape, and size of metal particles and the catalytic graphitization process.
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Y. Zhang, A. Wang, and T. Zhang, Chem. Commun., 46, 862-864 (2010).
K. P. De Jong and J. W. Geus, Catal. Rev.: Sci. Eng., 42, 481-510 (2000).
F. Rodriguez-Reinoso, Carbon, 36, 159-175 (1998).
J. Blanchard and N. Abatzoglou, Catal. Today, 237, 150-156 (2014).
R. L. McCreery, Chem. Rev., 108, 2646-2687 (2008).
C. Merlet, B. Rotenberg, et al., Nat. Mater., 11, 306-310 (2012).
T. Hyeon, S. Han, et al., Angew. Chem., Int. Ed., 42, 4352-4356 (2003).
X. Wang, P. Zhang, et al., RSC Adv., 5, 57828-57832 (2015).
H. Wang, Z. Li, et al., Carbon, 57, 317-328 (2013).
E. M. Lotfabad, J. Ding, et al., ACS Nano, 8, 7115-7129 (2014).
F. Shen, H. Zhu, et al., ACS Appl. Mater. Interfaces, 7, 23291-23296 (2015).
J. S. Zhang, M. W. Zhang, et al., ACS Catal., 2, 940-948 (2012).
X. H. Li, J. S. Zhang, et al., Chem. Mater., 23, 4344-4348 (2011).
Q. Li, J. P. Yang, et al., Nano Res., 3, 632-642 (2010).
Y. C. Zhao, Z. Liu, et al., Adv. Mater., 20, 1777-1781 (2008).
A. Loupy, C. R. Chim., 7, 103-112 (2004).
B. M. Moshtaghioun, R. Poyato, et al., J. Eur. Ceram. Soc., 32, 1787-1794 (2012).
F. Cagide, J. Reis, et al., Tetrahedron Lett., 52, 6446-6449 (2011).
R. V. Kumar, Y. Mastai, et al., J. Mater. Chem., 11, 1209-1213 (2001).
H. Wang, J. Zhang, et al., J. Cryst. Growth, 244, No. 1, 88-99 (2002).
Z. Meng, X. Xiaodang, and Z. Millin, Mater. Lett., 62, No. 3, 385-388 (2008).
M. P. Pileni, B. W. Ninham, et al., Adv. Mater., 11, 1358-1362 (1999).
C. Qin and S. Coulombe, Mater. Lett., 60, 1973-1976 (2006).
J. Peternela, M. F. Silva, et al., Mater. Res., 11, 1-29 (2017).
Y. Tan, Z. Jia, et al., J. Mater. Chem. A, 5, 24139-24144 (2017).
R. Sergiienko, E. Shibata, et al., Ultrason. Sonochem., 13, 6-12 (2006).
W. Bak, H. S. Kim, et al., J. Mater. Chem. A, 5, 24139-24144 (2017).
R. E. Franklin, Proc. R. Soc. A, 209, 196-205 (1951).
M. Sevilla, C. Salinas Martinez-de Lecea, et al., Phys. Chem. Chem. Phys., 10, 1433-1442 (2008).
K. T. Lee, X. Ji, et al., Angew. Chem., Int. Ed., 48, 5661-5665 (2009).
O. P. Krivoruchko, A. N. Shmakov, and V. I. Zaikovskii, Nucl. Instrum. Methods Phys. Res., Sect. A, 470, 198-201 (2001).
R. Anton, Carbon, 47, 856-865 (2009).
M. Sevilla and A. B. Fuertes, Carbon, 44, 468-473 (2006).
A. H. Lu, W. C. Li, et al., Angew. Chem., Int. Ed., 49, 1615-1618 (2010).
J. W. Long, M. Laskoski, et al., J. Mater. Chem., 21, 3477-3484 (2011).
M. Sevilla, C. Sanchis, et al., J. Phys. Chem. C, 111, 9749-9756 (2007).
E. Thompson, A. E. Danks, et al., Green Chem., 117, 551-556 (2015).
A. M. Herring, J. T. McKinnon, J. Am. Chem. Soc., 125, 9916-9917 (2003).
M. Sevilla and A. B. Fuertes, Chem. Phys. Lett., 490, 63-68 (2010).
S. Glatzel, Z. Schnepp, and C. Giordano, Angew. Chem., Int. Ed., 52, 2355-2358 (2013).
J. Hoekstra, M. Versluijs-Helder, et al., ChemSusChem, 8, 985-989 (2015).
J. Hoekstra, A. M. Beale, et al., J. Phys. Chem. C, 119, 10653-10661 (2015).
H. Zhu, F. Shen, et al., Nano Energy, 33, 37-44 (2017).
A. N. Prusov, S. M. Prusova, et al., RF Pat. No. 2,353,626, Apr. 27, 2009; “Method of obtaining fibrous cellulose from cellulose-containing fiber”; Byull., No. 12.
J. Hoekstra, A. M. Beale, et al., J. Phys. Chem. C, 119, 10653-10661 (2015).
J. Hoekstra, A. M. Beale, et al., Carbon, 107, 248-260 (2016).
F. Tuinstra and J. L. Koenig, J. Chem. Phys., 53, 1126-1130 (1970).
The research was sponsored by the Russian Science Foundation under RSF Grant No. 17-13-01240.
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Translated from Khimicheskie Volokna, No. 3, pp. 16-22, May—June, 2018.
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Prusov, A.N., Prusova, S.M., Zakharov, A.G. et al. Iron-Containing Carbon Nanocomposites Based on Cellulose. Fibre Chem 50, 154–160 (2018). https://doi.org/10.1007/s10692-018-9952-9
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DOI: https://doi.org/10.1007/s10692-018-9952-9