A modernized scheme of the structure of native cotton cellulose microfibrils is proposed, providing for the presence of slit-shaped pores in its structure and satisfying most of the results of modern studies of its supramolecular structure and sorption properties. It is shown that within the framework of this scheme it is possible to determine the content of elementary fibrils in microfibrils and the degree of crystallinity of cellulose using 1H-NMR and sorption measurements. The mechanism and character of dispersion of microfibrils, accompanied by supramolecular rearrangements of moistened cellulose, was investigated.
Similar content being viewed by others
References
Yu. B. Grunin, et al., Biofizika, 60, No. 1, 53-64 (2015).
Yu. B. Grunin, et al., Vysokomol.soed. Ser. A, 54, No. 3, 397 (2012).
Yu. B. Grunin, et al., Vysokomol.soed. Ser. A, 57, No. 1, 46 (2015).
V. P. Nikolaev, A. A. Ageev, and Yu. G. Frolov, Proceedings of the D. Mendeleev University of Chemical Technology of Russia, 101, 84-101 (1978).
NMR analyzer “Spin Track”. URL: http://www.nmr-design.com.
Yu. B. Grunin, et al., Biofizika, 62, No. 2, 266-275 (2017).
D. P. Delmer and Y. Amor, Plant Cell., 7, 987-1000 (1995).
Q. Li and S. Renneckar, Biomacromolecules, 12, No. 3, 650-659 (2011).
S.-Y. Ding and M. E. Himmel, J. Agricultural a. Food Chemistry, 54, 597-606 (2006).
L. H. Thomas, Plant Physiology, 161, 465-476 (2013).
Y. Nishiyama, et al., Biomacromolecules, 9, 3133-3140 (2008).
Y. Nishiyama, J. Wood Sci., 55, 241-249 (2009).
H. Chanzy, J. F. Kennedy, et al., Cellulose Sources and Exploitation: Industrial Utilisation Biotechnology and Physicochemical Properties, Ellis Horwood, Chichester, UK (1990) p. 3-12.
C. Verlhac, J. Dedier, and H. Chanzy, J. Polymer Sci. Part A: Polymer Chemistry, 28, No. 5, 1171- 1177 (1990).
Y. Nishiyama, et al., J. Am. Chem. Soc., 125, 14300-14306 (2003).
Y. Nishiyama, P. Langan, and H. Chanzy, J. Am. Chem. Soc., 124, 9074-9082 (2002).
S. Greg and K. Sing, Absorption, Specific Surface Area, Porosity [in Russian], 2nd ed., trans. from English, Mir, Moscow (1984) 306 p.
Yu. B. Grunin, et al., Zh. Fiz. Khim., 87, No. 1, 84 (2013).
Yu. B. Grunin, et al., Zh. Fiz. Khim., 90, No. 11, 1696-1700 (2016).
Yu. B. Grunin et al., The Structure and Physico-Chemical Properties of Cellulose and Nanocomposites Based on It: A Monograph [in Russian], eds. L. A. Aleshina, V. A. Gurtov, and N. V. Melech, Izdatel’stvo PetrGU (Publishing house of the Petrozavodsk State University), Petrozavodsk (2014) 240 p.
Z. A. Rogovin, Chemistry of Cellulose [in Russian], Khimiya, Moscow (1972) 519 p.
W. G. Glasser, et al., Cellulose, 19, 589-598 (2012).
Ya. I. Gerasimov, A Course in Physical Chemistry [in Russian], in 2 vols, Vol.1, Khimiya, Moscow (1964) 624 p.
R. M. Brown, J. Polymer Sci. Part A: Polymer Chemistry, 42, 487-495 (2004).
A. D. French and M. S. Cintron, Cellulose, 20, 583-588 (2013).
H. F. Stoeckli, P. Rebstein, and L. Ballerini, Carbon, 28, No. 6, 907-909 (1990).
Y. Habibi, L.A. Lucia, and O. J. Rojas, Chem. Rev., 110, 3479-3500 (2010).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Khimicheskie Volokna, No. 5, pp. 31 – 36, September – October, 2017.
Rights and permissions
About this article
Cite this article
Grunin, Y.B., Grunin, L.Y., Gal’braikh, L.S. et al. Dispersion Peculiarities of Crystalline Cellulose Upon its Moistening. Fibre Chem 49, 321–326 (2018). https://doi.org/10.1007/s10692-018-9890-6
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10692-018-9890-6