The characteristic features of the structural hierarchy of the formation of iron-containing catalytic sites on polymeric carriers based on modified polyacrylonitrile and copolymer of acrylonitrile with methyl acrylate were determined using optical and X-ray spectroscopy. It has been shown that some of the short ring structures that appear in the creation of a polydentate ligand lose their ability to coordinate the metal and may not be included in the composition of catalytically active particles entering the complex formation reaction.
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R. F. Vitkovskaya, I. G. Rumynskaya, and A. Yu. Smirnov, Khim. Volokna, 3, 26-28 (2008).
R. F. Vitkovskaya, I. G. Rumynskaya, et al., Khim. Volokna, 5, 30-35 (2013).
I. G. Rumynskaya and R. F. Vitkovskaya, Fizikokhimiya polimerov, 17, 223-227, Tver’, (2011).
I. G. Rumynskaya, S. A. Agranova, et al., Vysokomol. Soedin., 41B, No. 7, 1195-1199 (1999).
A. V. Novoselov, V. N. Zgonnik, et al., Vysokomol. Soedin., 35B, No. 5, 510-514 (1993).
O. M. Oranskaya, V. N. Filimonov, and E. Ya. Shmulyakovsky, Questions in Molecular Spectroscopy, Nauka, Novosibirsk, 195-198 (1974).
E. P. Talsi and D. E. Babuschkin, Macromol. Chem. Phys., 202, 2046-2051 (2001).
The work is funded by the Ministry of Education and Science of the Russian Federation (State task No. 2014/186). Project No. 2094.
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Translated from Khimicheskie Volokna, No. 5, pp. 43-46, September – October, 2015.
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Rumynskaya, I.G., Romanova, E.P., Vitkovskaya, R.F. et al. Hierarchy of Structural Associates of Catalytically Active Sites on an Acrylonitrile-Based Polymeric Fibrous Carrier. Fibre Chem 47, 380–383 (2016). https://doi.org/10.1007/s10692-016-9697-2
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DOI: https://doi.org/10.1007/s10692-016-9697-2