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Features of thermochemical transformations during oxidation of m-,p-aramid–polyacrylonitrile fibrous composites

  • Chemistry and Technology of Chemical Fibres
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Fibre Chemistry Aims and scope

Thermal oxidation of m-,p-aramid − polyacrylonitrile polymer fibrous composites and their components was studied by instrumental analytical methods. It was found that mainly polyacrylonitrile fibre underwent chemical and structural transformations under the thermal oxidation conditions. Incorporation of up to 60% of it into a spinning mixture increased the oxygen index to the level of a thermally stable material (37%).

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Notes

  1. We thank Prof. A. V. Volokhina for supplying samples of the aramid − PAN fibrous mixture and for discussing the scope of the studies

References

  1. N. S. Zubkova and N. I. Konstantinova, Flame-Resistance of Textiles [in Russian], Inst. Inform. Tekhnol., Moscow, 2008, 228 pp.

  2. N. S. Zubkova, Polymeric Materials with Increased Fire Hazard [in Russian], A. N. Kosygin MSTU, Moscow, 2004, 198 pp.

  3. O. V. Strekalova, N. S. Zubkova, et al., Khim. Volokna, No. 1, 34–38 (2003).

  4. K. E. Perepelkin, Reinforced Fibres and Fibrous Polymer Composites [in Russian], Nauchnye Osnovy i Tekhnologii, St. Petersburg, 2009, 380 pp.

  5. N. N. Machalaba, G. A. Budnitskii, et al., Khim. Volokna, No. 4, 52–54 (2002).

  6. Lirsot Ltd. Product. Thermal and flame-resistant arlan fibres and threads [in Russian]; URL: http://www.advtech.ru/lirsot/index.htm (accession date Sept. 12, 2012).

  7. A. V. Volokhina, N. N. Babaeva, et al., Special-purpose Fibres and Threads: Production, Structure, Properties, Use: A Collection of Scientific Works [in Russian], No. 2, Sputnik+, Moscow, 2010, pp. 135–149.

  8. T. V. Druzhinina and A. V. Istomin, Khim. Tekhnol., No. 6, 345–354 (2011).

  9. A. V. Volokhina, V. N. Kiya-Oglu, et al., RU Pat. 23,107,101 C1, MPK D 01 F 11/16; “Method for production of thermally stable textiles,” Appl. Apr. 10, 2006; Publ. Nov. 20, 2007; Byull. No. 32.

  10. A. V. Volokhina, V. N. Kiya-Oglu, et al, Vysokomol. Soedin., 52, No. 11, 2044–2048 (2010).

    CAS  Google Scholar 

  11. K. Nakanishi, Infrared Absorption Spectroscopy. Practical, Holden—Day, San Francisco, 1962.

  12. GOST 12.1.044-89; Fire and Explosion Hazard of Substances and Materials. Nomenclature of Indicators and Methods for Their Determination; Eff. Jan. 1, 1991; Izdvo. Standartov, Moscow, 1989, 100 pp.

  13. A. A. Konkin (ed.), Thermally and Flame-Resistant and Non-flammable Fibres [in Russian], Khimiya, Moscow, 1978, 424 pp.

  14. O. A. Belyaeva, D. I. Krivtsov, et al, Khim. Volokna, No. 5, 7–13 (2012).

  15. A. V. Istomin and T. V. Druzhinina, Khim. Volokna, No. 4, 28–32 (2012).

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Translated from Khimicheskie Volokna, No. 3, pp. 10-16, May—June, 2013.

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Druzhinina, T.V., Istomin, A.V. Features of thermochemical transformations during oxidation of m-,p-aramid–polyacrylonitrile fibrous composites. Fibre Chem 45, 133–139 (2013). https://doi.org/10.1007/s10692-013-9496-y

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  • DOI: https://doi.org/10.1007/s10692-013-9496-y

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