The effect on the dynamics of ripening of viscose in the presence of carbonyl-containing compounds: hexamethylenetetramine (urotropin), sodium sulfoxylate (Rongalite C), and dimethylolurea, was investigated. A hypothesis was advanced concerning the possibility of formation of mixed cellulose xanthate methylol derivatives whose presence alters the chemistry and kinetics of hydrolysis of cellulose esters in the spinning bath.
References
R. G. Zhbankov and P. V. Kozlov, in: Physics of Cellulose and Its Derivatives [in Russian], B. I. Stepanov (ed.), Nauka i Tekhnika, Minsk (1983).
P. H. Hermans, Kunstseide, 16, 173-182 (1934).
K. Goetze, Viscose Rayon Fibres, Springer, Berlin (1967).
A. T. Serkov, Production of Viscose Staple Fibres [in Russian], Khimiya, Moscow (1986).
B. E. Geller, A. A. Geller, and V. G. Chirtulov, in: Practical Handbook of the Physical Chemistry of Fibre-Forming Polymers [in Russian], B. E. Geller (ed.), Khimiya, Moscow (1996).
S. P. Papkov and E. Z. Fainberg, Reaction of Cellulose and Cellulose Fibres with Water [in Russian], Khimiya, Moscow (1976).
W. J. Roff, J. Text. Inst., 48, 646-663 (1958).
R. E. Wagner and E. Pacsu, Text. Res. J., 22, 12-20 (1952).
R. E. Wagner and E. Pacsu, Text. Res. J., 22, 12-20 (1952).
A. J. Hall, J. Silk Rayon, 22, 1689-1692 (1948).
V. A. Gruzdev and A. B. Pakshver, Finishing of Viscose Fibre [in Russian], Gizlegprom, Moscow (1956).
N. M. Bikales and L. Segal, Cellulose and Its Derivatives, 2nd ed., Wiley-Interscience, New York (1971).
A. K. Dibrova and V. S. Matveev (eds.), Analytical Control of Production of Man-Made Fibres [in Russian], Khimiya, Moscow (1986).
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Translated from Khimicheskie Volokna, No. 2, pp. 40-44, March-April, 2009.
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Khoroneko, O.V., Geller, B.E. Effect of carbonyl-containing compounds on the dynamics of ripening of viscose. Fibre Chem 41, 123–127 (2009). https://doi.org/10.1007/s10692-009-9140-z
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DOI: https://doi.org/10.1007/s10692-009-9140-z