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A new spectroscopic approach to characterization of porous and filled polymeric materials

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Fibre Chemistry Aims and scope

An effective and simple spectroscopic method is proposed for determining the degree of filling and porosity of polymeric materials and the distribution of the filler particle or pore size in the polymer matrix is proposed and consists of separation and analysis of absorbing and scattering components of the radiation falling on the sample. The possibilities and advantages of the spectroscopic approach in comparison to visual methods of optical and electron microscopy are demonstrated on a wide range of objects (track membranes, porous xerogel films, polymer composites and blends, etc.).

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References

  1. J. Z. Liang, J. Appl. Polym. Sci., 104, 1692–1696 (2007).

    Article  CAS  Google Scholar 

  2. R. Haggenmueller, C. Guthy, et al., Macromolecules, 40, 2417–2421 (2007).

    Article  CAS  Google Scholar 

  3. P. M. Pakhomov, E. V. Nazarova, et al., Russ. J. Appl. Chem., 76, 464–467 (2003).

    Article  CAS  Google Scholar 

  4. L. Yu, K. Dean, and L. Li, Prog. Polym. Sci., 31, 576–602 (2006).

    Article  CAS  Google Scholar 

  5. P. M. Pakhomov, High-Strength Polymer Fibres [in Russian], Versk. Gos. Un-t, Tver' (1993).

    Google Scholar 

  6. F. E. Kesting, Synthetic Polymer Membranes, Wiley, New York (1985).

    Google Scholar 

  7. M. B. Satterfield, P. W. Majstrik, et al., J. Polym. Sci. Part B: Polym. Phys., 44, 2327–2345 (2006).

    Article  CAS  Google Scholar 

  8. D. Dasgupta and A. K. Nandi, Macromolecules, 40, 2008–2018 (2007).

    Article  CAS  Google Scholar 

  9. P. M. Pakhomov, E. V. Kruglova, and S. D. Khizhnyak, Vysokomolek. Soedin., B42, No. 6, 1081–1088 (2000).

    Google Scholar 

  10. P. M. Pakhomov, M. N. Malanin, et al., Vysokomolek. Soedin., 43, No. 4, 764–768 (2001).

    CAS  Google Scholar 

  11. P. M. Pakhomov, S. D. Khizhnyak, et al., Zav. Lab.: Diagnost. Mater., 68, No. 5, 31–33 (2002).

    CAS  Google Scholar 

  12. P. M. Pakhomov, M. N. Malanin, and S. D. Khizhnyak, Vysokomolek. Soedin., B47, No. 6, 1066–1072 (2005).

    Google Scholar 

  13. M. N. Malanin, E. Moeller, and P. M. Pakhomov, Zh. Prikl. Khim., 79, No. 6, 1014–1018 (2006).

    Google Scholar 

  14. P. M. Pakhomov, M. N. Malanin, et al., Zh. Prikl. Khim., 80, No. 6, 983–987 (2007).

    Google Scholar 

  15. S. D. Khizhnyak, M. N. Malanin, et al., Vysokomolek. Soedin., B50, No. 6, 1115–1123 (2008).

    Google Scholar 

  16. M. N. Malanin, R. V. Savkin, et al., Physical Chemistry of Polymers [in Russian], Vol. 8, Tversk. Gos. Un-t, Tver' (2002), pp. 18–22.

    Google Scholar 

  17. J. Dechant, Ultrarotspektroskopische Untersuchungen an Polymeren, Akademie, Berlin (1972).

    Google Scholar 

  18. G. A. Zisman and O. M. Todes, Course in General Physics [in Russian], Vol. 3, Nauka, Moscow (1970).

    Google Scholar 

  19. J. F. Rabek, Experimental Methods in Polymer Chemistry, Wiley, New York (1980).

    Google Scholar 

  20. L. I. Slutsker and V. A. Marikhin, Opt. Spektrosk., 10, No. 2, 232–239 (1961).

    Google Scholar 

  21. P. M. Pakhomov, M. N. Malanin, and S. D. Khizhnyak, Vysokomolek. Soedin., B50, No. 6, 1113–1115 (2008).

    Google Scholar 

  22. P. M. Pakhomov, M. N. Malanin, et al., Vysokomolek. Soedin., B50, No. 7, 1230–1235 (2008).

    Google Scholar 

  23. S. D. Khizhnyak, K. O. Vorob'eva, et al., Physical Chemistry of Polymers [in Russian], Vol. 13, Tversk. Gos. Un-t, Tver' (2007), pp. 75–82.

    Google Scholar 

  24. P. M. Pakhomov, Polymer Spectroscopy [in Russian], Tversk. Gos. Un-t, Tver' (1997).

    Google Scholar 

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Authors and Affiliations

  1. Tver’ State University, Tver’, Russia

    P. M. Pakhomov & S. D. Khizhnyak

  2. Institute for the Textile and Light Industries, Tver’, Russia

    S. Yu. Zharov

  3. Institute of Polymer Studies, Dresden, Germany

    K.-J. Eichhorn

Authors
  1. P. M. Pakhomov
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  2. S. D. Khizhnyak
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  3. S. Yu. Zharov
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  4. K.-J. Eichhorn
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Additional information

Translated from Khimicheskie Volokna, No. 3, pp. 63–71, May–June, 2008.

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Pakhomov, P.M., Khizhnyak, S.D., Zharov, S.Y. et al. A new spectroscopic approach to characterization of porous and filled polymeric materials. Fibre Chem 40, 253–265 (2008). https://doi.org/10.1007/s10692-008-9052-3

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  • DOI: https://doi.org/10.1007/s10692-008-9052-3

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