Skip to main content
SpringerLink
Log in

Hydrolytic polymerization of caprolactam accompanied by crystallization of the polymer

  • Published:
Fibre Chemistry Aims and scope

Abstract

Caprolactam was polymerized in the presence of 3 wt. % water at 443–473 K, accompanied by crystallization of the melt of the polymer formed. It was found that the time of onset of crystallization of the melt is shifted to the region of lower degrees of conversion of caprolactam into a polymer, and the efficiency of the solid-phase stage of the reaction increases with a decrease in the temperature of synthesis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. Klare, E. Fritzsche, and F. Grebe, Synthetic Polyamide Fibres [Russian translation], Z. A. Rogovin (ed.), Mir, Moscow (1966).

    Google Scholar 

  2. A. K. Kuznetsov, Candidate Dissertation, Ivanovo Chemical Engineering Institute, Ivanovo (1984).

    Google Scholar 

  3. D. A. Siganov, Candidate Dissertation, Ivanovo Chemical Engineering Institute, Ivanovo (1990).

    Google Scholar 

  4. Yu. M. Bazarov, L. N. Mizerovskii, et al., RF Patent No. 2145329; published Byull, No. 4 (2000).

  5. L. N. Mizerovskii, Yu. M. Bazarov, and M. G. Pavlov, Khim. Volokna, No. 5, 15–19 (2003).

  6. L. N. Mizerovskii, Yu. M. Bazarov, and M. G. Pavlov, Khim. Volokna, No. 6, 9–14 (2003).

  7. Yu. M. Bazarov, M. G. Pavlov, et al., Khim. Volokna, No. 1, 8–11 (2007).

  8. L. N. Mizerovskii and I. N. Smirnov, Khim. Volokna, No. 6, 11–14 (2004).

  9. Y. M. Bazarov, Candidate Dissertation, Ivanovo Chemical Engineering Institute, Ivanovo (1980).

    Google Scholar 

  10. L. N. Mizerovskii, A. K. Kuznetsov, et al., Vysokomolek. Soedin., A24, No. 6, 1174–1179 (1982).

    Google Scholar 

  11. N. V. Sholichev, Candidate Dissertation, Ivanovo Chemical Engineering Institute, Ivanovo (1975).

    Google Scholar 

  12. Yu. M. Bazarov, A. Yu. Tsenin, and L. N. Mizerovskii, Khim. Volokna, No. 2, 15–18 (1998).

  13. L. N. Mizerovskii, Yu. M. Bazarov, and N. I. Lytkina, Khim. Volokna, No. 2, 43–46 (2006).

Download references

Author information

Authors and Affiliations

  1. Ivanovo State Chemical Engineering University, Russia

    Yu. M. Bazarov

  2. Institute of Chemistry of Solutions, Russian Academy of Sciences, Russia

    L. N. Mizerovskii

Authors
  1. Yu. M. Bazarov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. N. Mizerovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

__________

Translated from Khimicheskie Volokna, No. 1, pp. 22–25, January–February, 2007.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bazarov, Y.M., Mizerovskii, L.N. Hydrolytic polymerization of caprolactam accompanied by crystallization of the polymer. Fibre Chem 39, 26–30 (2007). https://doi.org/10.1007/s10692-007-0006-y

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10692-007-0006-y

Keywords

Search

Navigation