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Heavy metal removal and cyanide destruction in the metal plating industry: an integrated approach from egypt

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Abstract

Wastewater produced from a metal plating is a major environmental problem. Industrial auditing revealed that the main source of pollution mainly originated from rinsing water. The characterization of final effluent showed that it is highly contaminated with hazardous heavy metals and cyanide. The concentration of copper, hexavalent chromium, nickel, and cyanide in the rinsing water of metal plating department was 14.8, 40.9, 13.3, and 19 mg/l, respectively. The concentration of cyanide and zinc from the galvanizing department reached 60 and 80 mg/l. The remediation scheme included the application of in-plant control measures via changing the rinsing process followed by the destruction of cyanide and reduction of hexavalent chromium bearing wastes. The pretreated wastes were then mixed with other industrial wastes prior to a combined chemical coagulation-sedimentation using lime and/or lime in combination with ferric chloride. The results indicated that, after applying the waste minimization measures alone at the source, prior to final treatment of industrial waste, removal rates of cyanide, copper, nickel, and chromium concentrations were 23.2%, 14.9%, 32.3%, and 55.3%, respectively in the rinse water from metal plating department. Furthermore, the removal rates of cyanide and zinc in the galvanizing department reached 59.7% and 24.3. The integrated control measures and treatment scheme led to more than 99% removal of copper, nickel, chromium, and zinc, while the complete removal of cyanide was achieved in the final effluent.

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References

  • Abou-Elela, S. I. (1993). Treatment of industrial waste water from metal industries (case studies, Egypt). Second Egyptian seminar on industrial waste water management, April 4–6, pp 92–105, Cairo, Egypt.

  • Abou-Elela, S. I., El-Kamah, H. M., & El-Awady, R. A. (1998). Waste minimization in the electroplating industry (case study). The International Journal of Environmental Studies 55, 287–296.

    Article  CAS  Google Scholar 

  • APHA. (2001). Standards methods for the examination of water and wastewater (20th ed.). Washington DC: American Public Health Association.

    Google Scholar 

  • Chang, L. Y. (1995). A waste minimization study of a chelated copper complex in wastewater—treatability and process analysis. Waste Management 15(3), 209–220.

    Article  CAS  Google Scholar 

  • Chang, L. Y. (1998a). Waste minimization study, chelated complex in wastewater. In: Encyclopedia of chemical processing and design (Vol. 64, pp. 419–439). Marcel Dekker.

  • Chang, L. Y. (1998b). Wastewater pollution prevention, precipitation, and separation. In: Encyclopedia of chemical processing and design (Vol. 65, pp. 399–417). Marcel Dekker.

  • Christie, W. N. (1998). In industrial waste stream generation. New Jersey: Prentice Hall.

    Google Scholar 

  • Eckenfelder, W. W. Jr. (2000). Industrial water pollution control. Boston: McGraw Hill.

    Google Scholar 

  • El-Gohary, F. A., Abou El-Ela, S. I., El-Kamah, H. M., & Aly, H. I. (1993). Pollution control of electroplating wastewater (case study). Al-Azhar Engineering Third International Conference, pp. 694–702.

  • Environmental Protection Agency (EPA). (1987). Technical resource document, treatment technologies for metal/cyanide-containing wastes. Hazardous Waste Engineering Research Laboratory, NTIS Order Number PB 38-143896.

  • Environmental Protection Agency (EPA). (1995). Profile of the fabricated metal products. Office of Compliance Sector Notebook Project. EPA/310-R-95-007.

  • Freeman, H. M. (1995). Industrial pollution prevention. Handbook. New York: McGraw Hill, Inc.

    Google Scholar 

  • Li, Y. J., Zeng, X. P., Liu, Y. F., Yan, S. S., Hu, Z. H., & Ni, Y. M. (2003). Study on the treatment of copper-electroplating wastewater by chemical trapping and flocculation. Separation Purification Technology, 31, 91–95.

    Article  Google Scholar 

  • Magalhães, J. A. (2002). Inertization of galvanic sludge by its incorporation in ceramic bodies, Ph.D. Thesis, University of Minho, p. 311.

  • Ministry of State for Environmental Affairs. (2000). Egyptian Law 93/62. Discharge to Sewer. System (as modified. by Decree 44/2000).

  • Nemerow, N. J., & Agardy, F. J. (1998). Strategies of industrial and hazardous waste management. New York: Van Nostrand Reinhold.

    Google Scholar 

  • Patterson, J. W. (1988). Metal treatment and recovery. In J. R. Kramer & H. E. Allen (Eds.), Metal speciation: theory, analysis, and application (pp. 333–345) Chelsea: Lewis Publishers, Inc.

    Google Scholar 

  • Peters, R. W., Ku, Y., & Bhattacharyya, D. (1985). Evaluation of recent treatment techniques for removal of heavy metals from industrial wastewaters. AICHE Symposium Series, Separation of Heavy Metals and Other Contaminants, 81(243), 165–203.

  • PRC Environmental Management, Inc. (PRC). (1989). Hazardous waste reduction in the metal finishing industry. Park Ridge: Noyes Data Corporation.

    Google Scholar 

  • Silva, J. E., Soares, D., Paiva, A. P., Labrincha, J. A., & Castro, F. (2005). Leaching behaviour of a galvanic sludge in sulphuric acid and ammoniacal media. Journal of Hazardous Materials, B121, 195–202.

    Article  Google Scholar 

  • Theodore, L., & McGuin, Y. C. (1992). Pollution prevention. New York: Van Nostrand Reinhold.

    Google Scholar 

  • Thimothy, L. K., Lotayef, D., Jago, P. A., & Kandeel, M. (1997). Industrial pollution prevention opportunities in Egypt. First International and Trade Fair on Environmental Management and Technologies, Feb. 16–18, Cairo, Egypt.

  • Wang, L. K., & Wang, S. M. H. (1992). Handbook of industrial waste treatment (Vol. 1). New York: Marcel Dekker, Inc.

    Google Scholar 

  • World Bank Group. (1998). Pollution prevention and abatement handbook 1998: Toward cleaner production. Washington, D.C: The World Bank Group.

    Google Scholar 

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Correspondence to Sohair I. Abou-Elela.

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Abou-Elela, S.I., Ibrahim, H.S. & Abou-Taleb, E. Heavy metal removal and cyanide destruction in the metal plating industry: an integrated approach from egypt. Environmentalist 28, 223–229 (2008). https://doi.org/10.1007/s10669-007-9132-6

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  • DOI: https://doi.org/10.1007/s10669-007-9132-6

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