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Gaseous and particulate reactive nitrogen species in the indoor air of selected households in New Delhi

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Abstract

The present study reports the indoor abundance of inorganic trace gases (NH3, NO2 and SO2) and their corresponding particulates (NH4+, NO3− and SO42−) along with other major ionic species present in the aerosol form (Cl−, F−, Na+, K+, Ca2+ and Mg2+), in the urban households of megacity Delhi (India). Two different households (DH site and MH site) were selected in the city based on the variation in the land use patterns of the locations in which they were situated. Trace gases followed the order NH3 > SO2 > NO2 at both the sites with NH3 contributing about 90% and 85% to the total Nr species at DH and MH sites, respectively. NH3 showed maximum indoor concentrations during monsoon season whereas NO2 and SO2 were higher during winter season. The gas to particle conversion of the inorganic trace gases was studied by calculating their oxidation ratios which followed the order SOR > NOR > NHR, indicating that SO2 showed more oxidative conversion to SO42− as compared to NO2 and NH3 in the indoor setup. The chemical composition of the particulates revealed that Ca2+ and SO42− were the most abundant cation and anion, respectively, among the measured ionic species at both sites and the concentrations of all the major ions were higher for the industrial MH site as compared to the residential DH site. Source apportionment using principal component analysis and mass ratios showed that indoor activities such as cooking, cleaning along with others such as biomass burning and dust resuspension were responsible for the indoor composition of particulates at DH site whereas outdoor influences such as coal burning and industrial emissions from local sources were prominent at MH site due to its industrialized surroundings. For naturally ventilated households (such as the present study), it was observed that the emissions generated indoors as well as the characteristic outdoor influences seem to influence the overall indoor air composition and quality.

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References

  • Abbatt, J. P., & Wang, C. (2020). The atmospheric chemistry of indoor environments. Environmental Science: Processes & Impacts, 22(1), 25–48.

    CAS  Google Scholar 

  • Balasubramanian, R., & Lee, S. S. (2007). Characteristics of indoor aerosols in residential homes in urban locations: a case study in Singapore. Journal of the Air & Waste Management Association, 57(8), 981–990.

    Article  CAS  Google Scholar 

  • Brauer, M., Koutrakis, P., Keeler, G. J., & Spengler, J. D. (1991). Indoor and outdoor concentrations of inorganic acidic aerosols and gases. Journal of the Air & Waste Management Association, 41(2), 171–181.

    Article  CAS  Google Scholar 

  • Colbeck, I., & Harrison, R. M. (1984). Ozone—secondary aerosol—visibility relationships in North-West England. Science of the total environment, 34(1–2), 87–100.

    Article  CAS  Google Scholar 

  • Notification, C. P. C. B. (2009). The Gazatte of India, Part III – Section 4. NAAQS.

    Google Scholar 

  • Dockery, D. W., & Spengler, J. D. (1981). Indoor-outdoor relationships of respirable sulfates and particles. Atmospheric Environment, 15(3), 335–343.

    Article  CAS  Google Scholar 

  • EANET. (2000). Quality Assurance/Quality Control (QA/QC) Program for Wet Deposition Monitoring in East Asia, March 2000. Acid Deposition Monitoring Network in East Asia. https://www.eanet.asia/wp-content/uploads/2019/04/qaqcwet.pdf

  • Gupta, A., Kumar, R., Kumari, K. M., & Srivastava, S. S. (2003). Measurement of NO2, HNO3, NH3 and SO2 and related particulate matter at a rural site in Rampur. India. Atmospheric Environment, 37(34), 4837–4846.

    Article  CAS  Google Scholar 

  • Goyal, S. K., Gavane, A. G., & Aggarwal, A. L. (2000). Effect of temperature on absorption efficiency of NO2 in arsenite method. Environmental monitoring and assessment, 61(2), 285–291.

    Article  Google Scholar 

  • Hsieh, L. T., Wang, Y. F., Li, P., & Chen, K. C. (2011). Removal of particle-bound water-soluble ions 1251 from cooking fume using bio-solution wet scrubber. Aerosol and Air Quality Research, 11, 508–518.

    Article  CAS  Google Scholar 

  • Huang, R. J., Duan, J., Li, Y., Chen, Q., Chen, Y., Tang, M., Yang, L., Ni, H., Lin, C., Xu, W., & Liu, Y. (2020). Effects of NH3 and alkaline metals on the formation of particulate sulfate and nitrate in wintertime Beijing. Science of the Total Environment, 717, 137190.

    Article  CAS  Google Scholar 

  • Jayamurugan, R., Kumaravel, B., Palanivelraja, S., & Chockalingam, M. P. (2013). Influence of temperature, relative humidity and seasonal variability on ambient air quality in a coastal urban area. International Journal of Atmospheric Sciences, 2013.

  • Kaneyasu, N., Ohta, S., & Murao, N. (1995). Seasonal variation in the chemical composition of atmospheric aerosols and gaseous species in Sapporo. Japan. Atmospheric Environment, 29(13), 1559–1568.

    Article  CAS  Google Scholar 

  • Kulshrestha, M. J., Kulshrestha, U. C., Parashar, D. C., & Vairamani, M. (2003). Estimation of SO4 contribution by dry deposition of SO2 onto the dust particles in India. Atmospheric Environment, 37(22), 3057–3063.

    Article  CAS  Google Scholar 

  • Kulshrestha, U. C., Raman, R. S., Kulshrestha, M. J., Rao, T. N., & Hazarika, P. J. (2009). Secondary aerosol formation and identification of regional source locations by PSCF analysis in the Indo-Gangetic region of India. Journal of Atmospheric Chemistry, 63(1), 33–47.

    Article  CAS  Google Scholar 

  • Leaderer, B. P., Zagraniski, R. T., Berwick, M., & Stolwijk, J. A. (1986). Assessment of exposure to indoor air contaminants from combustion sources: methodology and application. American Journal of Epidemiology, 124(2), 275–289.

    Article  CAS  Google Scholar 

  • Lazaridis, M., Aleksandropoulou, V., Hanssen, J. E., Dye, C., Eleftheriadis, K., & Katsivela, E. (2008). Inorganic and carbonaceous components in indoor/outdoor particulate matter in two residential houses in Oslo, Norway. Journal of the Air & Waste Management Association, 58(3), 346–356.

    Article  CAS  Google Scholar 

  • Li, Y., & Harrison, R. M. (1990). Comparison of indoor and outdoor concentrations of acid gases, ammonia and their associated salts. Environmental technology, 11(4), 315–326.

    Article  Google Scholar 

  • Lunden, M. M., Revzan, K. L., Fischer, M. L., Thatcher, T. L., Littlejohn, D., Hering, S. V., & Brown, N. J. (2003). The transformation of outdoor ammonium nitrate aerosols in the indoor environment. Atmospheric Environment, 37(39–40), 5633–5644.

    Article  CAS  Google Scholar 

  • Marcazzan, G. M., Vaccaro, S., Valli, G., & Vecchi, R. (2001). Characterisation of PM10 and PM2.5 1336 particulate matter in the ambient air of Milan (Italy). Atmospheric Environment, 35, 4639–4650.

    Article  CAS  Google Scholar 

  • Meng, Z., Xu, X., Lin, W., Ge, B., Xie, Y., Song, B., & Cheng, H. (2018). Role of ambient ammonia in particulate ammonium formation at a rural site in the North China Plain. Atmospheric Chemistry & Physics, 18(1).

  • Monn, Ch., Fuchs, A., Kogelschatz, D., & Wanner, H. U. (1995). Comparison of indoor and outdoor concentrations of PM-10 and PM-2.5. Journal of Aerosol Science, 26, 515–516.

    Article  Google Scholar 

  • Mu, L., Zheng, L., Liang, M., Tian, M., Li, X., & Jing, D. (2019). Characterization and source analysis of water-soluble ions in atmospheric particles in Jinzhong. Aerosol and Air Quality Research, 19, 2396–2409.

    Article  CAS  Google Scholar 

  • Nath, S., & Yadav, S. (2018). A comparative study on fog and dew water chemistry at New Delhi. India. Aerosol and Air Quality Research, 18(1), 26–36.

    Article  CAS  Google Scholar 

  • Nazaroff, W. W., & Weschler, C. J. (2020). Indoor acids and bases.

  • Ohta, S., & Okita, T. (1990). A chemical characterization of atmospheric aerosol in Sapporo. Atmospheric Environment. Part A. General Topics, 24(4), 815–822.

    Article  Google Scholar 

  • Plaza, J., Pujadas, M., Gómez-Moreno, F. J., Sánchez, M., & Artíñano, B. (2011). Mass size distributions of soluble sulfate, nitrate and ammonium in the Madrid urban aerosol. Atmospheric environment, 45(28), 4966–4976.

    Article  CAS  Google Scholar 

  • Salonen, H., Salthammer, T., & Morawska, L. (2019). Human exposure to NO2 in school and office indoor environments. Environment international, 130, 104887.

    Article  CAS  Google Scholar 

  • See, S. W., & Balasubramanian, R. (2008). Chemical characteristics of fine particles emitted from different gas cooking methods. Atmospheric Environment, 42, 8852–8862.

    Article  CAS  Google Scholar 

  • Sharma, M., Kishore, S., Tripathi, S. N., & Behera, S. N. (2007). Role of atmospheric ammonia in the formation of inorganic secondary particulate matter: a study at Kanpur. India. Journal of Atmospheric Chemistry, 58(1), 1–17.

    Article  CAS  Google Scholar 

  • Singh, S., & Kulshrestha, U. C. (2012). Abundance and distribution of gaseous ammonia and particulate ammonium at Delhi. India. Biogeosciences, 9(12), 5023–5029.

    Article  CAS  Google Scholar 

  • Singh, S., Sharma, A., Kumar, B., & Kulshrestha, U. C. (2017). Wet deposition fluxes of atmospheric inorganic reactive nitrogen at an urban and rural site in the Indo-Gangetic Plain. Atmospheric Pollution Research, 8(4), 669–677.

    Article  Google Scholar 

  • Singh, S., Gupta, G. P., Kumar, B., & Kulshrestha, U. C. (2014). Comparative study of indoor air pollution using traditional and improved cooking stoves in rural households of Northern India. Energy for Sustainable Development, 19, 1–6.

    Article  CAS  Google Scholar 

  • Smolík, J., Dohányosová, P., Schwarz, J., et al. (2008). Characterization of indoor and outdoor aerosols in a suburban area of Prague. Water, Air, & Soil Pollution: Focus, 8, 35–47.

    Article  Google Scholar 

  • Spicer, C. W., Kenny, D. V., Ward, G. F., & Billick, I. H. (1993). Transformations, lifetimes, and sources of NO2, HONO, and HNO3 in indoor environments. Air & Waste, 43(11), 1479–1485.

    Article  CAS  Google Scholar 

  • Stockwell, W. R., Watson, J. G., Robinson, N. F., Steiner, W., & Sylte, W. W. (2000). The ammonium nitrate particle equivalent of NOx emissions for wintertime conditions in Central California’s San Joaquin Valley. Atmospheric Environment, 34(27), 4711–4717.

    Article  CAS  Google Scholar 

  • Sun, Y., Zhuang, G., Tang, A., Wang, Y., & Ann, Z. (2006). Chemical characteristics of PM2. 5 and PM10 in haze− fog episodes in Beijing. Environmental Science & Technology, 40(10), 3148–3155.

  • Tan, C. C. L., Finney, K. N., Chen, Q., Russell, N. V., Sharifi, V. N., & Swithenbank, J. (2012). Experimental Investigation of Indoor Air Pollutants in Residential Buildings. Indoor and Built Environment, 22(3), 471–489.

    Article  Google Scholar 

  • Tiwari, R., & Kulshrestha, U. (2019). Wintertime distribution and atmospheric interactions of reactive nitrogen species along the urban transect of Delhi–NCR. Atmospheric environment, 209, 40–53.

    Article  CAS  Google Scholar 

  • Trebs, I., Metzger, S., Meixner, F.X., Helas, G., Hoffer, A., Rudich, Y., Falkovich, A.H., Moura, M.A., da Silva Jr, R.S., Artaxo, P. & Slanina, J. (2005). The NH4+‐NO3−‐Cl−‐SO42−‐H2O aerosol system and its gas phase precursors at a pasture site in the Amazon Basin: How relevant are mineral cations and soluble organic acids?. Journal of Geophysical Research: Atmospheres, 110(D7).

  • Triche, E. W., Belanger, K., Bracken, M. B., Beckett, W. S., Holford, T. R., Gent, J. F., & Leaderer, B. P. (2005). Indoor heating sources and respiratory symptoms in nonsmoking women. Epidemiology, 377–384.

  • Verma, N., Satsangi, A., Lakhani, A., & Kumari, K. M. (2017). Low molecular weight monocarboxylic acids in PM 2.5 and PM 10: quantification, seasonal variation and source apportionment. Aerosol and Air Quality Research., 17, 485–498.

    Article  CAS  Google Scholar 

  • Wallace, L. (2006). Indoor sources of ultrafine and accumulation mode particles, size distributions, size-resolved concentrations, and source strengths. Aerosol Science and Technology, 40, 348–360.

    Article  CAS  Google Scholar 

  • World Health Organization. (2006). Air quality guidelines: global update 2005: particulate matter, ozone, nitrogen dioxide, and sulfur dioxide. World Health Organization.

  • Zhang, T., Cao, J. J., Tie, X. X., Shen, Z. X., Liu, S. X., Ding, H., Han, Y. M., Wang, G. H., Ho, K. F., Qiang, J., & Li, W. T. (2011). Water-soluble ions in atmospheric aerosols measured in Xi’an, China: seasonal variations and sources. Atmospheric Research, 102(1–2), 110–119.

    Article  CAS  Google Scholar 

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Acknowledgements

We thank Jawaharlal Nehru University for providing the infrastructure to carry out this study. Author Ankita Katoch sincerely acknowledges the financial assitance from CSIR-UGC and UKRI GCRF South Asian Nitrogen Hub. This study is a part of DRS-Net (Deposition Research Network through students)-India.

Funding

This study is financially supported by the DST PURSE.

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  1. School of Environmental Sciences, Jawaharlal Nehru University, New Delhi, 110067, India

    Ankita Katoch & U. C. Kulshrestha

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  1. Ankita Katoch
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  2. U. C. Kulshrestha
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Correspondence to U. C. Kulshrestha.

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Katoch, A., Kulshrestha, U.C. Gaseous and particulate reactive nitrogen species in the indoor air of selected households in New Delhi. Environ Monit Assess 193, 231 (2021). https://doi.org/10.1007/s10661-021-08991-6

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