Abstract
Water is a scarce resource in the Mediterranean region where adverse climatic conditions promoting water shortages tend to increase with climate change. Under water scarcity conditions and high atmosphere evaporative demand, the risks of decreased water quality, and land salinization are major threats to the sustainability of irrigated agriculture in this region. The assessment of the quality of irrigation water is increasingly important to ensure the maintenance of long-term salt balance at a crop, farm, and regional scale. This study is focused on the spatial and temporal variability of water quality for irrigation in the Alqueva reservoir (Southern Portugal). The assessment was performed every 2 months during a distinctive drought year (2017) and included inorganic ions (Na+, Ca2+, Mg2+, K+, NH4+, Cl−, F−, SO42−, NO3−, and NO2−), pH, and electric conductivity (ECW) of water. Sodium adsorption ratio (SAR) was calculated, and potential soil permeability problems were estimated. The assessment showed significantly higher values of the physicochemical parameters in the most upstream sites, located near tributaries inflows, and an upward trend in ion concentrations throughout the year, with significantly higher concentrations of Na+, Mg2+, Cl−, and SO42, registered through May to November, reflecting the severe drought felt in the summer, autumn, and winter. The evaluation of water quality for irrigation indicated a slight to moderate risk of reduced infiltration rates, which should be considered whenever sprinkler irrigation is used, mainly in fine-textured soils, which are prevalent in the irrigated area. The multivariate statistical approach, using principal component analysis and factor analysis, identified two principal components related to salinity and nutrient concentrations. The cluster analysis revealed three groups of similarity between samples pointing to a more time- than space-controlled pattern. Overall, the temporal dynamics of the water physicochemical parameters could indicate that an abnormal annual distribution of precipitation and temperature may distort seasonal differences. To prevent water and soil degradation, a more frequent assessment of the water quality should be considered, allowing for the selection of appropriate soil and water management measures in irrigated areas.
This is a preview of subscription content, access via your institution.





References
ARH Alentejo (Administração da Região Hidrográfica do Alentejo - Administration of the Hydrographic Region of Alentejo). (2011). Plano de gestão das bacias hidrográficas integradas nas regiões hidrográficas 6 e 7: Região Hidrográfica 7. Lisboa: Administração da Região Hidrográfica do Alentejo I.P., Ministério do Ambiente e do Ordenamento do Território.
APHA (American Public Health Association). (1998). Standard methods for the examination of water and wastewater (twentieth ed.). Washington DC: American Public Health Association, American Water Works Association and Water Environmental Federation.
Ayers, R.S. & Westcot, D.W. (1985). Water quality of agriculture. FAO irrigation and drainage paper no. 29, revision 1. Rome: Food and agriculture Organization of the United Nations.
Bauder, T.A., Waskom, R.M., Sutherland, P.L.& Davis, J.G. (2014). Irrigation water quality criteria. Fact sheet no. 0.506, crop series – Irrigation, Colorado State University extension. https://extension.colostate.edu/docs/pubs/crops/00506.pdf. Accessed 7 September 2018.
Beltrán, J. M. (1999). Irrigation with saline water: Benefits and environmental impact. Agricultural Water Management, 40, 183–194.
Cattell, R. B. (1966). The Scree test for the number of factors. Multivariate Behavioral Research, 1(2), 245–276. https://doi.org/10.1207/s15327906mbr0102_10.
Chotpantarat, S., & Boonkaewwan, S. (2018). Impacts of land-use changes on watershed discharge and water quality in a large intensive agricultural area in Thailand. Hydrological Sciences Journal, 63(9), 1386–1407. https://doi.org/10.1080/02626667.2018.1506128.
Compton, A. (2011). A review of rationale for EC and SAR standards. Montana Dept. of Environmental Quality.
COTR (Centro Operativo e de Tecnologia de Regadio - Irrigation Technology and Operation Center) (2017) SAGRA – Sistema Agrometeorológico para a Gestão da Rega no Alentejo. http://www.cotr.pt/cotr/sagra.asp. Accessed 12 May 2018.
Decree-Law No 236/1998, 1 of August. On water quality assessment. Diário da República, 1ª SÉRIE-A N° 176 — 1-8-1998.
EC (European Commission) (2000). The environmental impacts of irrigation in the European Union. A report to the Environment Directorate of the European Commission, 147 pp http://ec.europa.eu/environment/agriculture/pdf/irrigation.pdf. .
EDIA (Empresa de Desenvolvimento e Infraestruturas de Alqueva – Alqueva Development and Infrastructures Company) (2017). Anuário Agrícola de Alqueva 2017. Empresa de Desenvolvimento e Infraestruturas de Alqueva, S.A. http://www.edia.pt/pt/o-que-fazemos/apoio-ao-agricultor/anuario-agricola/225. .
EEA (European Environment Agency) (2012). Climate change impacts and vulnerability in Europe 2012, 304 pp www.eea.europa.eu. Accessed 12 May 2018.
Etteieb, S., Cherif, S., & Tarhouni, J. (2017). Hydrochemical assessment of water quality for irrigation: A case study of, the Medjerda River in Tunisia. Applied Water Sciences, 7, 469–480. https://doi.org/10.1007/s13201-015-0265-3.
GPAa (Grupo de Projecto Alqueva Agrícola - Alqueva Agricultural Project Group) (2005). Atlas Rural Zona de Intervenção de Alqueva. Tomo 5 in Plano de intervenção para a zona de Alqueva http://sir.dgadr.gov.pt/conteudos/gpaa/ Accessed 2 May 2018.
Gkiougkis, I., Kallioras, A., Pliakas, F., Pechtelidis, A., Diamantis, V., Diamantis, I., Ziogas, A., & Dafnis, I. (2015). Assessment of soil salinization at the eastern Nestos River Delta, N.E. Greece. Catena, 128, 238–251. https://doi.org/10.1016/j.catena.2014.06.024.
Hanson, B.R. (2006a). How water quality affects infiltration. In: Hanson, B.R., Grattan, S.R. & Fulton, A. (Eds.), Agricultural salinity and drainage (pp 47-50). University of California, Davis: Division of agriculture and natural resources publication 3375, University of California Irrigation Program.
Hanson, B.R. (2006b). Leaching fractions and irrigation uniformity. In: Hanson, B.R., Grattan, S.R. & Fulton, A. (Eds.), Agricultural salinity and drainage (pp 131-132). University of California, Davis: Division of agriculture and natural resources publication 3375, University of California Irrigation Program.
Hillel, D. (2000). Salinity Management for Sustainable Irrigation. Integrating science, environment, and economics. Environmentally and socially sustainable development. Washington DC: The World Bank.
Hu, Q., Yang, Y., Han, S., & Wang, J. (2019). Degradation of agricultural drainage water quantity and quality due to farmland expansion and water-saving operations in arid basins. Agricultural Water Management, 213, 185–192. https://doi.org/10.1016/j.agwat.2018.10.019.
Iakunin, M., Salgado, R., & Potes, M. (2018). Breeze effects at a large artificial lake: Summer case study. Hydrology and Earth System Sciences, 22, 5191–5210. https://doi.org/10.5194/hess-22-5191-2018.
ICT (Institute of Earth Sciences) (2019). Atmospheric sciences water and climate. http://www.i-c-t.pt/g1/index.php/observations-and-forecast/ Accessed 2 January 2019.
Iglesias, A., Santillán, D., & Garrote, L. (2018). On the barriers to adaption to less water under climate change: Policy choices in Mediterranean countries. Water Resources Management, 2018, 1–14. https://doi.org/10.1007/s11269-018-2043-0.
IPCC (Intergovernmental Panel on Climate Change) (2014). Climate change 2014 synthesis report, 133 pp. www.ipcc.ch/ Accessed 2 May 2018.
IPMA (Instituto Português do Mar e da Atmosfera - Portuguese Institute of the Sea and Atmosphere) (2017). Boletim Climatológico Anual de Portugal Continental 2017. Instituto Português do Mar e da Atmosfera, IP. http://www.ipma.pt/resources.www/docs/im.publicacoes/edicoes.online/20180323/cHAXzjMhUzLfdgCRJIKG/cli_20171201_20171231_pcl_aa_co_pt.pdf Accessed 12 May 2018.
IPMA (Instituto Português do Mar e da Atmosfera - Portuguese Institute for Sea and Atmosphere) (2018). Normais climatológicas 1981-2010 provisórias de Beja. Instituto Português do Mar e da Atmosfera, IP. https:// www.ipma.pt/pt/oclima/normais.clima/1981-2010/002/ Accessed 12 May 2018.
IUSS Working Group WRB (2014). World reference base for soil resources 2014, Update 2015. Rome: World Soil Resources Report N° 106, FAO. http://www.fao.org/3/a-i3794e.pdf Accessed 12 May 2018.
Jones, E., & van Vliet, M. T. H. (2018). Drought impacts on river salinity in the southern US: Implications for water scarcity. Science of the Total Environment, 644, 844–853. https://doi.org/10.1016/j.scitotenv.2018.06.373.
Li, T., Li, S., Lian, C., Bush, R. T., & Xiong, L. (2018). A comparative assessment of Australia’s lower lakes water quality under extreme drought and post-drought conditions using multivariate statistical techniques. Journal of Cleaner Production, 190, 1–11. https://doi.org/10.1016/j.jclepro.2018.04.121.
Liu, C.-W., Lin, K.-H., Kuo, Y.-M. (2003) Application of factor analysis in the assessment of groundwater quality in a blackfoot disease area in Taiwan. Science of The Total Environment 313 (1-3):77-89
Lutz, S. R., Mallucci, S., Diamantini, E., Majone, B., Bellin, A., & Merz, R. (2016). Hydroclimatic and water quality trends across three Mediterranean river basins. Science of the Total Environment, 571, 1392–1406. https://doi.org/10.1016/j.scitotenv.2016.07.102.
Machado, R. M. A., & Serralheiro, R. P. (2017). Soil salinity: Effect on vegetable crop growth. Management practices to prevent and mitigate soil salinization. Horticulturae, 3(30), 1–13. https://doi.org/10.3390/horticulturae3020030.
Maas, E. V., & Hoffman, G. J. (1977). Crop Salt Tolerance-Current Assessment. Journal of the Irrigation and Drainage Division, 103(2), 115–134.
Merchán, D., Causapé, J., & Abrahão, R. (2013). Impact of irrigation implementation on hydrology and water quality in a small agricultural basin in Spain. Hydrological Sciences Journal, 58(7), 1400–1413. https://doi.org/10.1080/02626667.2013.829576.
Mil-Homens, M., Stevens, R. L., Cato, I., & Abrantes, F. (2007). Regional geochemical baselines for Portuguese shelf sediments. Environmental Pollution, 148(2), 418–427. https://doi.org/10.1016/j.envpol.2006.12.007
Mosley, L. M., Zammit, B., Leyden, E., Heneker, T. M., Hipsey, M. R., Skinner, D., & Aldridge, K. T. (2012). The impact of extreme low flows on the water quality of the lower Murray River and lakes (South Australia). Water Resources Management, 26, 3923–3946. https://doi.org/10.1007/s11269-012-0113-2.
Mosley, L. M. (2015). Drought impacts on the water quality of freshwater systems; review and integration. Earth-Science Reviews, 140, 203–214. https://doi.org/10.1016/j.earscirev.2014.11.010.
Morais, M. M., Serafim, A. M., Pinto, P., Ilhéu, A., & Ruivo, M. (2007). Monitoring the water quality in Alqueva reservoir, Guadiana River, southern Portugal. In G. Gunter & M. Carmo (Eds.), The 12nd international specialized conference on watershed & river basin management (pp. 96–112). Germany: Technical University of Berlin.
Muangthong, S., & Shrestha, S. (2015). Assessment of surface water quality using multivariate statistical techniques: Case study of the Nampong River and Songkhram River, Thailand. Environmental Monitoring and Assessment, 187, 548. https://doi.org/10.1007/s10661-015-4774-1.
Oster, J. D., & Schroer, F. W. (1979). Infiltration as influenced by irrigation water quality. Soil Science Society of America Journal, 43, 444–447.
Palma, P., Alvarenga, P., Palma, V., Fernandes, R. M., Soares, A. M. V. M., & Barbosa, I. R. (2010). Assessment of anthropogenic sources of water pollution using multivariate statistical techniques: A case study of the Alqueva's reservoir, Portugal. Environmental Monitoring and Assessment, 165, 539–552. https://doi.org/10.1007/s10661-009-0965-y.
Palma, P., Ledo, L., Soares, S., Barbosa, I. R., & Alvarenga, P. (2014a). Spatial and temporal variability of the water and sediments quality in the Alqueva reservoir (Guadiana Basin; southern Portugal). Science of the Total Environment, 470–471, 780–790. https://doi.org/10.1016/j.scitotenv.2013.10.035.
Palma, P., Köck-Schulmeyer, M., Alvarenga, P., Ledo, L., Barbosa, I. R., López de Alda, M., & Barceló, D. (2014b). Risk assessment of pesticides detected in surface water of the Alqueva reservoir (Guadiana basin, southern of Portugal). Science of the Total Environment, 488–489, 208–219. https://doi.org/10.1016/j.scitotenv.2014.04.088.
Palma, P., Ledo, L., & Alvarenga, P. (2015). Assessment of trace element pollution and its environmental risk to freshwater sediments influenced by anthropogenic contributions: The case study of Alqueva reservoir (Guadiana Basin). Catena, 128, 174–184. https://doi.org/10.1016/j.catena.2015.02.002.
Palmer, W.C. (1965). Meteorological drought. Res. Paper no. 45, Washington, D.C.: Weather bureau.
Paranychianakis, N. V., & Chartzoulakis, K. S. (2005). Irrigation of Mediterranean crops with saline water: From physiology to management practices. Agriculture, Ecosystems & Environment, 106, 171–187. https://doi.org/10.1016/j.agee.2004.10.006.
Potes, M., Salgado, R., Costa, M. J., Morais, M., Bortoli, D., Kostadinov, I., & Mammarella, I. (2017). Lake–atmosphere interactions at Alqueva reservoir: A case study in the summer of 2014 (p. 691). Tellus A: Dynamic Meteorology and Oceanography. https://doi.org/10.1080/16000870.2016.1272787.
Rengasamy, P. (2010). Soil processes affecting crop production in salt-affected soils. Functional Plant Biology, 37, 613–620. https://doi.org/10.1071/FP09249.
Rhoades, J.D. (1977). Potential for using saline agricultural drainage waters for irrigation. Free. Proc. water Management for Irrigation and Drainage. ASCE. Reno, Nevada. 20-22 July 1977, pp 85-116.
Rhoades, J. D., Kandiah, A., & Mashali, A. M. (1992). The use of saline waters for crop production. In FAO irrigation and drainage paper 48. Rome: Food and Agriculture Organization of the United Nations.
Scanlon, B., Jolly, I., Sophocleous, M., & Zhang, L. (2007). Global impacts of conversions from natural to agricultural ecosystems on water resources: Quantity versus quality. Water Resources Research, 43, 1–18. https://doi.org/10.1029/2006WR005486.
Serafim, A., Morais, M., Guilherme, P., Sarmento, P., Ruivo, M., & Magriço, A. (2006). Spatial and temporal heterogeneity in the Alqueva reservoir, Guadiana River, Portugal. Limnetica, 25(3), 161–176.
Shrestha, S., & Kazama, F. (2007). Assessment of surface water quality using multivariate statistical techniques: A case study of the Fuji river basin, Japan. Environmental Modelling & Software, 22, 464–475. https://doi.org/10.1016/j.envsoft.2006.02.001.
Simeonov, V., Stratis, J. A., Samara, C., Zachariadis, G., Voutsa, D., & Anthemidis, A. (2003). Assessment of surface water quality in northern Greece. Water Research, 37(17), 4119–4124.
StatSoft, Inc. (2004). STATISTICA (data analysis software system), version 7. https://www.tibco.com/products/tibco-statistica
Tanji, K. K., & Kielen, N. C. (2002). Agricultural drainage water management in arid and semi-arid areas. In FAO irrigation and drainage paper 61. Rome: Food and Agriculture Organization of the United Nations.
Tomaz, A., Patanita, M., Guerreiro, I., Dôres, J., Boteta, L., & Ferro Palma, J. (2018). Efficient use of water and nutrients in irrigated cropping systems in the Alqueva region. Spanish Journal of Soil Science, 8(1), 12–23. https://doi.org/10.3232/SJSS.2018.V8.N1.02.
U.S. Salinity Laboratory Staff. (1954). Diagnosis and improvement of saline and alkali soils. Handbook no. 60. Washington, DC: US Department of Agriculture.
Valverde, P., Serralheiro, R., Carvalho, M., Maia, R., Oliveira, B., & Ramos, V. (2015). Climate change impacts on irrigated agriculture in the Guadiana river basin (Portugal). Agricultural Water Management, 152, 17–30. https://doi.org/10.1016/j.agwat.2014.12.012.
van Vliet, M. T. H., & Zwolsman, J. J. G. (2008). Impact of summer droughts on the water quality of the Meuse river. Journal of Hydrology, 353, 1–17. https://doi.org/10.1016/j.jhydrol.2008.01.001.
Vicente-Serrano, S. M., Lopez-Moreno, J., Beguería, S., Lorenzo-Lacruz, J., Sanchez-Lorenzo, A., García-Ruiz, J. M., Azorin-Molina, C., Morán-Tejeda, E., Revuelto, J., Trigo, R., Coelho, F., & Espejo, F. (2014). Evidence of increasing drought severity caused by temperature rise in southern Europe. Environmental Research Letters, 9, 44001, 9 pp. https://doi.org/10.1088/1748-9326/9/4/044001.
Ward Jr., J. H. (1963). Hierarchical grouping to optimize an objective function. Journal of the American Statistical Association, 58, 236–244.
Weil, R. R., & Brady, N. C. (2016). The nature and properties of soils (fifteenth ed.). Columbus: Pearson.
Wilcox, L. V. (1955). Classification and use of irrigation waters, circular no. 969. Washington, D.C.: United States Department of Agriculture.
Williams, W. D. (1999). Salinisation: A major threat to water resources in the arid and semi-arid regions of the world. Lakes & Reservoirs: Research and Management, 4, 85–91.
Yang, J., Strokal, M., Kroeze, C., Wang, M., Wang, J., Wu, Y., Bai, Z., & Ma, L. (2019). Nutrient losses to surface waters in Hai he basin: A case study of Guanting reservoir and Baiyangdian lake. Agricultural Water Management, 213, 62–75. https://doi.org/10.1016/j.agwat.2018.09.022.
Zalidis, G., Stamatiadis, S., Takavakoglou, V., Eskridge, K., & Misopolinos, N. (2002). Impacts of agricultural practices on soil and water quality in the Mediterranean region and proposed assessment methodology. Agriculture, Ecosystems & Environment, 88, 137–146.
Funding
This work was co-financed by the European Union through the European Regional Development Fund, under ALENTEJO 2020 (Alentejo Regional Operational Program) through the project “ALOP: Observation, forecasting and warning systems in the atmosphere and water reservoirs of the Alentejo” under the reference ALT20-03-0145-FEDER-000004.
This work is a contribution to the Projects UID/GEO/04035/2013 and UID/GEO/04683/2019, funded by FCT – Fundação para a Ciência e aTecnologia, Portugal.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
On behalf of all authors, the corresponding author states that there is no conflict of interest.
Additional information
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Tomaz, A., Palma, P., Fialho, S. et al. Spatial and temporal dynamics of irrigation water quality under drought conditions in a large reservoir in Southern Portugal. Environ Monit Assess 192, 93 (2020). https://doi.org/10.1007/s10661-019-8048-1
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10661-019-8048-1