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Assessment of geogenic input into Bilina stream sediments (Czech Republic)

Abstract

Over the past 100 years, the area along the River Bílina has been influenced by open-cast brown-coal mining, coal processing, petroleum refineries, and chemical plants. As a result, the extensive industrial activity has changed the overall character as well as the morphology of the landscape. A survey was underway to investigate the occurrence and distribution of various elements in the sediments of the River Bílina—a tributary of the River Elbe, a watercourse running through the Czech Republic and Germany—in order to discern the natural background from anthropogenic pollution. The study evaluated the content of selected elements (As, Zn, Pb, Cr, Ni, V, and Cu) in stream sediments of the River Bílina. Samples were taken at 20 sampling sites throughout the 82-km-long watercourse. For all the samples, the content of the elements was determined using ICP-MS after each of the sample was digested using HF and HNO3. The results of analyses of elemental composition of stream sediments were compared with those found through such analyses made within the surrounding geological units—more specifically, Proterozoic crystalline, Tertiary volcanic, Quaternary loess, Neogene sediments, and Neogene coal. All the samples of the stream sediments examined revealed increased amounts of As, V, Ni, Cr, and Pb. Using the enrichment factor established on the basis of the regional geological background values proved that elevated levels of elements in stream sediments are not always the result of industrial contamination.

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Funding

The present paper was supported by the Ministry for the Environment of the Czech Republic, project ID: MZP-OOHPP-87/08/GP and the project entitled Centre for Texture Analysis (project ID: CZ.2.16/3.1.00/21538) implemented as part of the Operational Programme Prague - Competitiveness. The present paper was also financially supported by RECETOX (LM2015051 and CZ.02.1.01/0.0/0.0/16_013/0001761) and CzechPolar2 (CZ.02.1.01/0.0/0.0/16_013/0001708) research infrastructures and contributes to Masaryk University Project MUNI/A/1251/2017 and the long-term conceptual development research organisation RVO: 67985891.

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Correspondence to Eva Geršlová.

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Vöröš, D., Geršlová, E., Nývlt, D. et al. Assessment of geogenic input into Bilina stream sediments (Czech Republic). Environ Monit Assess 191, 114 (2019). https://doi.org/10.1007/s10661-019-7255-0

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  • DOI: https://doi.org/10.1007/s10661-019-7255-0

Keywords

  • Origin of geogenic elements
  • Enrichment factor
  • Stream sediments
  • River Bílina
  • Czech Republic