Abstract
This work was conducted to explore heavy metal pollution in soils in an area near lead smelters in Jiyuan City, which is one of the main lead production areas in China. Altogether, 88 topsoil samples (0–20 cm) were collected from farmlands near the Yuguang lead smelting facilities; the sampling sites were 1570 to 6388 m to the main stack of the Yuguang. Analysis of the samples indicated that (i) the ranges of total Cd and Pb concentrations were 0.81–4.30 and 64.5–435 mg kg−1, respectively, mean pollution indices (concentration in soil/background value, PI) were 32.8 and 9.11, respectively, and the concentrations of total Cu, Zn, and Ni were slightly higher than the background values. Mean concentrations of DTPA-extractable Cd and Pb were 0.752 and 58.7 mg kg−1, respectively. (ii) The total concentrations of Cd, Pb and Pb/Cd ratios of samples decreased as the distance to the main stack of the Yuguang increased. Abnormal variations of these trends suggested these parameters of certain samples were affected by pollution sources other than the Yuguang. (iii) Judged by the results of this work, the area of the heavy metal-polluted land in Jiyuan was much greater than 115 km2, a value reported by an earlier investigation. These results indicate that the soil in the study area was polluted by Cd and Pb emissions from more than one polluting sources, the variation of Cd, Pb concentration and Pb/Cd ratios of samples to the distance of the pollution source can be potentially used for pollution source identification.
Similar content being viewed by others
References
Bi, X., Feng, X., Yang, Y., Qiu, G., Li, G., Li, F., Liu, T., Fu, Z., & Jin, Z. (2006). Environmental contamination of heavy metals from zinc smelting areas in Hezhang County, western Guizhou, China. Environment International, 32, 883–890.
Bi, X., Feng, X., Yang, Y., Li, X., Shin, G. P. Y., Li, F., Qiu, G., Li, G., Liu, T., & Fu, Z. (2009). Allocation and source attribution of lead and cadmium in maize (Zea mays L.) impacted by smelting emissions. Environmental Pollution, 157, 834–839.
Cheng, Y., Zhao, Z., Wang, Y., Qiu, K., Fu, Y., Zhao, X., & Li, L. (2014). Soil heavy metal pollution in the farmland near a lead-smelter in Henan Province. Chinese Journal of Soil Science, 45, 1505–1510.
Cheng, Y., Zhao, Z., Qiu, K., Li, A., Han, K., Liu, H., Mei, H., & Li, L. (2017). Remediation of lead smelting polluted area under the flooded line of a reservoir in Henan Province. Qinhai Environment, 27, 117–121.
Chinese Soil Taxonomy Research Group, Institute of Soil Science, Academi Sinica. (2001). Keys to Chinese soil taxonomy. Hefei: Press of University of Science and Technology of China.
Douay, F., Pruvot, C., Roussel, H., Ciesielski, H., Fourrier, H., Proix, N., & Waterlot, C. (2008). Contamination of urban soils in an area of northern France polluted by dust emissions of two smelters. Water, Air and Soil Pollution, 188, 247–260.
Eckel, W. P., Rabinowitz, M. B., & Foster, G. D. (2002). Investigation of unrecognized former secondary lead smelting sites: confirmation by historical sources and elemental ratios in soil. Environmental Pollution, 117, 273–279.
Ettler, V., Johan, Z., Kříbek, B., Veselovský, F., Mihaljevič, M., Vaněk, A., Penížek, V., Majer, V., Sracek, O., Mapani, B., Kamona, F., & Nyambe, I. (2016). Composition and fate of mine- and smelter-derived particles in soils of humid subtropical and hot semi-arid areas. Science of the Total Environment, 563-564, 329–339.
Ghayoraneh, M., & Qishlaqi, A. (2017). Concentration, distribution and speciation of toxic metals in soils along a transect around a Zn/Pb smelter in the northwest of Iran. Journal of Geochemical Exploration, 180, 1–14.
Government of Jiyuan City. (2017). Industrial base of cyclic economy of Jiyuan City of one trillion yuan output value. http://www.jiyuan.gov.cn/zjjy/xwzhx/ztzl/cyxm/201704/t20170412_325019.html. Accessed 23 Apr 2018.
Li, T., Wu, H., & Li, Y. (1991). Mapping of soil background content map in agricultural regions of China. Geographical Research, 10, 39–49.
Li, L., Ma, C., Xing, W., Xiang, G., & Yan, Q. (2012). Changes of lead levels and the physiochemical properties of soils in the vicinity of a lead smelter in the North China Plain. Acta Agriculturate Boreali-occidentalis Sinica, 21, 186–194.
Li, Q., Ji, H., Qin, F., Tang, L., Guo, X., & Feng, J. (2014). Sources and the distribution of heavy metals in the particle size of soil polluted by gold mining upstream of Miyun Reservoir, Beijing: implications for assessing the potential risks. Environmental Monitoring and Assessment, 186, 6605–6626.
Li, Q., Zhao, X., Li, H., Cheng, X., Liu, J., Ding, J., Zhu, J., & Cheng, Y. (2016). Pollution and potential ecological risk assessment of heavy metals in agricultural soils of gas-type pollution. Journal of Zhengzhou University (Medical Science), 51, 718–723.
Liang, Q. (2016). Spatial variability and evaluation of soil heavy metals pollution in Jiyuan Plain. Dissertation for master degree. North China University of Water Resources and Electric Power.
Lu, R. (2000). Methods of soil and agro-chemical analysis. Beijing: China Agricultural Science and Technology Press.
Lü, J., Jiao, W.-B., Qiu, H.-Y., Chen, B., Huang, X.-X., & Kang, B. (2018). Origin and spatial distribution of heavy metals and carcinogenic risk assessment in mining areas at You’xi County Southeast China. Geoderma, 310, 99–106.
Ministry of Environmental Protection, Ministry of Land Resources. (2014). Bulletin of soil pollution survey of China. http://www.mee.gov.cn/gkml/sthjbgw/qt/201404/t20140417_270670.htm. Assessed 1 Oct 2018.
Qiu, K., Xing, W., Scheckel, K. G., Cheng, Y., Zhao, Z., Ruan, X., & Li, L. (2016). Temporal and seasonal variations of As, Cd and Pb atmospheric deposition flux in the vicinity of lead smelters in Jiyuan, China. Atmospheric Pollution Research, 7, 170–179.
Qu, J., Liang, Q., Hu, Y., Yu, F., & Li, H. (2016). Spatial variability and pollution evaluation of heavy metals in the soil in a lead and zinc industry district in Jiyuan. Journal of North China University of Water Resources and Electric Power (Natural Science Edetion), 37, 47–51.
Ran, Y., Xing, W., Liang, S., Xiang, G., & Li, L. (2010). Heavy metal availability in soil near a lead smelter in the North China Plain. Asian Journal of Ecotoxicology, 5, 592–598.
Shao, D., Zhan, Y., Zhou, W., & Zhu, L. (2016). Current status and temporal trend of heavy metals in farmland soil of the Yangtze River Delta region: field survey and meta-analysis. Environmental Pollution, 219, 329–336.
Shen, X., Wang, X., Zhu, G., Xiong, D., Wu, X., & Sun, Y. (1991). Atmospheric pollution with Pb and Cd from zinc smelting with indigenous methods. Environmental Monitoring of China, 7, 8–9.
Shen, F., Liao, R., Ali, A., Mahar, A., Gao, D., Li, R., Sun, X., Awasthi, M. K., Wang, Q., & Zhang, Z. (2017). Spatial distribution and risk assessment of heavy metals in soil near a Pb/Zn smelter in Feng County, China. Ecotoxicology and Environmental Safety, 139, 254–262.
Wei, K. (2004). Soils in Henan. Beijing: China Agricultural Press.
Wei, Y. (2008). Solution of distance calculation between two points considering curvature of the Earth. Aero Weaponry, 3, 7–12.
Xing, W., Zhang, H., Scheckel, K. G., & Li, L. (2016). Heavy metal and metalloid concentrations in components of 25 wheat (Triticum aestivum) varieties in the vicinity of lead smelters in Henan province, China. Environmental Monitoring and Assessment, 188, 23.
Yao, D., Li, A., & Cao, L. (2015). Study of the heavy metal characteristics of an area. Resources Economization and Environmental Protection, 8, 69.
Zhang, X., Yang, L., Li, Y., Li, H., Wang, W., & Ye, B. (2012). Impacts of lead/zinc mining and smelting on the environment and human health in China. Environmental Monitoring and Assessment, 184, 2261–2273.
Zhao, X., Yao, D., Cheng, Y., Yuan, Z., Wang, L., Ju, H., & Zhang, L. (2017). Function analysis on the total and available contents of heavy metal in soils of a lead smelting area. Environmental Monitoring of China, 33, 68–74.
Zhou, X., Lei, M., Yang, J., Zhou, G., Guo, G., Chen, T., Wan, X., Liang, Q., & Qiao, P. (2013). Effect of lead on soil quality and human health around a lead smelter. Environmental Science, 34, 3675–3678.
Acknowledgements
The authors want to thank Mr. Wuzheng Zhai, Ming Cai, Xiaojian Hu, and Juntao Liu for their help in sample collection and processing. Although EPA contributed to this article, the research presented was not performed by or funded by EPA and was not subject to EPA’s quality system requirements. Consequently, the views, interpretations, and conclusions expressed in this article are solely those of the authors and do not necessarily reflect or represent EPA’s views or policies.
Funding
This work was sponsored by The National Key Research and Development Program of China (2016YFE0106400 and 2018YFD0800304) and National Natural Science Foundation of China (41471253).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Xing, W., Zheng, Y., Scheckel, K.G. et al. Spatial distribution of smelter emission heavy metals on farmland soil. Environ Monit Assess 191, 115 (2019). https://doi.org/10.1007/s10661-019-7254-1
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10661-019-7254-1