Abstract
A study was undertaken to decipher the uranium distribution in relation to a number of hydrogeological factors in groundwater of southwest Punjab. Existing geological information for the region suggests that the shallow alluvial aquifer extends up to 50–70 m below ground level (bgl) and is in turn underlain by a deeper aquifer which extends to a depth of 250 m bgl. The presence of clayey units limits the vertical mixing of groundwater between the shallow and deep aquifers. Water level data (averaged over 5 years period) indicates that the south and southwestern regions of the study area have shallow water levels (3–5 m bgl) while the north and northeast regions have deep water levels (20–28 m bgl). This difference in water levels is found to be increasing with time. Higher concentrations of uranium occur in the central, southern, and southwestern parts of the study area where the water table occurs at shallow depth. Groundwater in the northern and northeastern parts of the study area shows U concentration within permissible levels for potable use (< 30 μg/L) while the highest concentration of U (341 μg/L) was found in the central part of the study area. Seasonal variation in dissolved U concentration is found to be statistically significant. The observed increases in U concentrations during the post-monsoon season are due to the addition of bicarbonate from the root zone as well as increased dissolved oxygen, nitrate, and sulphate concentration (oxic condition) in the groundwater while the decrease in U concentration is attributed to quick recharge by precipitation through sand dunes and contribution of surface water. Deeper groundwater does not show much seasonal variation in dissolved U concentration. Correlation between U and other hydrochemical parameters was evaluated. Cluster analysis of the data also indicates the oxidative mobilization of U from the sediments. Based on the lithological, hydrogeological, and dissolved U data, a schematic map is prepared depicting the various factors affecting the U distribution in alluvial aquifers, which can also be applied to other regions of similar hydrogeological setup.
Similar content being viewed by others
References
Ayotte, J. D., Flanagan, S. M., & Morrow, W. S. (2007). Occurrence of uranium and 222Radon in glacial and bedrock aquifers in the northern United States, 1993–2003: U.S. Geological Survey Scientific Investigations Report 2007–5037, p. 84.
Bajwa, B. S., Kumar, S., Singh, S., Sahoo, S. K., & Tripathi, R. M. (2017). Uranium and other heavy toxic elements distribution in the drinking water samples of SW-Punjab, India. Journal of Radiation Research and Applied Science, 10(1), 13–19.
Bhalla, A., Singh, G., Kumar, S., Shahi, J. S., & Mehta, D. (2011). Elemental analysis of groundwater from different regions of Punjab State (India) using EDXRF technique and the sources of water contamination. In: Proc. of International Conference on Environmental and Computer Science, pp. 156–164, IACSIT Press, Singapore. http://www.ipcbee.com/vol19/31-ICECS2011R20009.pdf.
Brindha, K., Elango, L., & Nair, R. N. (2011). Spatial and temporal variation of uranium in a shallow weathered rock aquifer in southern India. Journal of Earth System Science, 120(5), 911–920.
CGWB. (2007). Groundwater information booklet. Bathinda District, Punjab. Central ground water board. A report.
CGWB. (2013). Groundwater information booklet. Bathinda District, Punjab. Central Ground Water Board. A report http://cgwb.gov.in/District_Profile/Punjab/Bathinda.pdf. Accessed 19 Nov 2018.
CGWB. (2014). Water quality issues and challenges in Punjab, pp. 1–182. Central Ground Water Board. http://cgwb.gov.in. Accessed 19 Nov 2018.
Chatton, E., Aquilina, L., Petelet-Giraud, E., Cary, L., Bertrand, G., Labasque, T., et al. (2016). Glacial recharge, salinisation and anthropogenic contamination in the coastal aquifers of Recife (Brazil). Science of the Total Environment, 569, 1114–1125.
Dhiman, S. C. (2012). Aquifer systems of India, Central Ground Water Board, Ministry of Water Resources, Government of India, p. 103. http://www.cgwb.gov.in/AQM/India.pdf. Accessed 19 Nov 2018.
Di Lorenzo, T., Borgoni, R., Ambrosini, R., Cifoni, M., Galassi, D. M. P., & Petitta, M. (2015). Occurrence of volatile organic compounds in shallow alluvial aquifers of a Mediterranean region: baseline scenario and ecological implications. Science of the Total Environment, 538, 712–723.
Filippini, M., Stumpp, C., Nijenhuis, I., Richnow, H. H., & Gargini, A. (2015). Evaluation of aquifer recharge and vulnerability in an alluvial lowland using environmental tracers. Journal of Hydrology, 529, 1657–1668.
Fishman, R. M., Siegfried, T., Raj, P., Modi, V., & Lall, U. (2011). Over-extraction from shallow bedrock versus deep alluvial aquifers: Reliability versus sustainability considerations for India's groundwater irrigation. Water Resources Research, 47(6). https://doi.org/10.1029/2011WR010617.
Foster, S. S. D., & Chilton, P. J. (2003). Groundwater: the processes and global significance of aquifer degradation. Philosophical Transactions of the Royal Society, B: Biological Sciences, 358(1440), 1957–1972.
Gómez, P., Garralón, A., Buil, B., Turrero, M. J., Sánchez, L., & De la Cruz, B. (2006). Modeling of geochemical processes related to uranium mobilization in the groundwater of a uranium mine. Science of the Total Environment, 366(1), 295–309.
Gupta, S. (2009). Groundwater management in alluvial areas of Punjab. Bhujal News Quarterly Journal, 24(4), 74–81. http://www.cgwb.gov.in/documents/Bhujal-News-24-4.pdf. Accessed 19 Nov 2018.
Gupta, S., & Thakur, R. S. (1989). Report on Hydrogeology of District Bathinda, Punjab State, CGWB, NW region, Chandigarh.
Gupta, A., Ronghang, M., Kumar, P., Mehrotra, I., Kumar, S., Grischek, T., et al. (2015). Nitrate contamination of riverbank filtrate at Srinagar, Uttarakhand, India: a case of geogenic mineralization. Journal of Hydrology, 531, 626–637.
Jurgens, B. C., Burow, K. R., Dalgish, B. A., & Shelton, J. L. (2008). Hydrogeology, water chemistry, and factors affecting the transport of contaminants in the zone of contribution of a public-supply well in Modesto, eastern San Joaquin Valley, California. U. S. Geological Survey.
Jurgens, B. C., Fram, M. S., Belitz, K., Burow, K. R., & Landon, M. K. (2010). Effects of groundwater development on uranium: Central Valley, California, USA. Groundwater, 48(6), 913–928.
Keesari, T., Ramakumar, K. L., Chidambaram, S., Pethperumal, S., & Thilagavathi, R. (2016). Understanding the hydrochemical behavior of groundwater and its suitability for drinking and agricultural purposes in Pondicherry area, South India – a step towards sustainable development. Groundwater for Sustainable Development, 2–3, 143–153.
Keesari, T., Sharma, D. A., Rishi, M. S., Pant, D., Mohokar, H. V., Jaryal, A. K., & Sinha, U. K. (2017). Isotope investigation on groundwater recharge and dynamics in shallow and deep alluvial aquifers of southwest Punjab. Applied Radiation and Isotopes, 129, 163–170.
Kochhar, N., Gill, G. S., Tuli, N., Dadwal, V., & Balaram, V. (2007). Chemical quality of ground water in relation to incidence of cancer in parts of SW Punjab, India. Asian Journal of Water, Environment and Pollution, 4(2), 107–112.
Kochhar, N., Dadwal, V., Rishi, M., Sharma, N. K., & Balaram, V. (2012). Evaluation of chemical quality of groundwater in parts of Sirsa (Harayana), Mansa, Bhatinda and Muktsar districts, SW Punjab with emphasis on uranium in relation to human health. Proc. of IGWC-2012 on the Assessment and Management of Groundwater Resources in Hard Rock Systems with Special Reference to Basaltic Terrain, pp. 611–626.
Kulkarni, H., & Shah, M. (2013). Punjab water syndrome. Economic & Political Weekly, 48(52), 65.
Kumar, A., Usha, N., Sawant, P. D., Tripathi, R. M., Raj, S. S., Mishra, M., et al. (2011a). Risk assessment for natural uranium in subsurface water of Punjab State, India. Human and Ecological Risk Assessment, 17(2), 381–393.
Kumar, A., Rout, S., Narayanan, U., Mishra, M. K., Tripathi, R. M., Singh, J., et al. (2011b). Geochemical modelling of uranium speciation in the subsurface aquatic environment of Punjab State in India. Journal of Geology and Mining Research, 3(5), 137–146.
Lapworth, D. J., MacDonald, A. M., Krishan, G., Rao, M. S., Gooddy, D. C., & Darling, W. G. (2015). Groundwater recharge and age-depth profiles of intensively exploited groundwater resources in northwest India. Geophysical Research Letters, 42(18), 7554–7562.
Mittal, S., Kaur, G., & Vishwakarma, G. S. (2014). Effects of environmental pesticides on the health of rural communities in the Malwa Region of Punjab, India: a review. Human and Ecological Risk Assessment: An International Journal, 20(2), 366–387.
Moon, H. S., Komlos, J., & Jaffé, P. R. (2007). Uranium reoxidation in previously bioreduced sediment by dissolved oxygen and nitrate. Environmental Science & Technology, 41(13), 4587–4592.
Mukherjee, A., Saha, D., Harvey, C. F., Taylor, R. G., Ahmed, K. M., & Bhanja, S. N. (2015). Groundwater systems of the Indian sub-continent. Journal of Hydrology: Regional Studies, 4, 1–14.
Nikic, Z., Kovacevic, J., & Papic, P. (2008). Uranium in the groundwater of Permo-Triassic aquifers of the Visok region, StaraPlanina, eastern Serbia. Water, Air, and Soil Pollution, 192(1–4), 47–58.
Nolan, J., & Weber, K. A. (2015). Natural uranium contamination in major US aquifers linked to nitrate. Environmental Science & Technology Letters, 2(8), 215–220.
Pant, D., Keesari, T., Sharma, D., Rishi, M., Singh, G., Jaryal, A., & Tripathi, R. M. (2017). Study on uranium contamination in groundwater of Faridkot and Muktsar districts of Punjab using stable isotopes of water. Journal of Radioanalytical and Nuclear Chemistry, 313(3), 635–639.
Patnaik, R., Lahiri, S., Chahar, V., Naskar, N., Sharma, P. K., Avhad, D. K., et al. (2016). Study of uranium mobilization from Himalayan Siwaliks to the Malwa region of Punjab state in India. Journal of Radioanalytical and Nuclear Chemistry, 308(3), 913–918.
Peterson, R. E., Rockhold, M. L., Serne, R. J., Thorne, P. D., & Williams, M. D. (2008). Uranium contamination in the subsurface beneath the 300 Area, Hanford site, Washington (no. PNNL-17034). Richland: Pacific Northwest National Laboratory (PNNL).
Phadke, A. V., Mahadevan, T. M., Narayan Das, G. R., & Saraswat, A. C. (1985). Uranium mineralisation in some phanerozoic sandstones of India. Geological environments for sandstone-type uranium deposits. IAEA-TECDOC-328, pp. 121–134.
Porcelli, D., & Swarzenski, P. W. (2003). The behavior of U-and Th-series nuclides in groundwater. Reviews in Mineralogy and Geochemistry, 52(1), 317–361.
Prikryl, J. D., Jain, A., Turner, D. R., & Pabalan, R. T. (2001). UraniumVI sorption behavior on silicate mineral mixtures. Journal of Contaminant Hydrology, 47(2–4), 241–253.
Rishi, M. S., Keesari, T., Sharma, D. A., Pant, D., & Sinha, U. K. (2017). Spatial trends in uranium distribution in groundwaters of Southwest Punjab, India- a hydrochemical perspective. Journal of Radioanalytical and Nuclear Chemistry, 311(3), 1937–1945.
Sahoo, S. K., Mohapatra, S., Chakrabarty, A., Sumesh, C. G., Jha, V. N., Tripathi, R. M., & Puranik, V. D. (2010). Determination of uranium at ultra trace level in packaged drinking water by laser fluorimeter and consequent ingestion dose. Radioprotection, 45(1), 55–66.
Shalev, N., Burg, A., Gavrieli, I., & Lazar, B. (2015). Nitrate contamination sources in aquifers underlying cultivated fields in an arid region–the Arava Valley, Israel. Applied Geochemistry, 63, 322–332.
Sharma, A. D., & Rishi, M. S. (2016). Presence of uranium in groundwater of Punjab: an overview. In Geostatistical and geospatial approaches for the characterization of natural resources in the environment (pp. 231–236). Cham: Springer.
Sharma, N., & Singh, J. (2016). Radiological and chemical risk assessment due to high uranium contents observed in the ground waters of Mansa District (Malwa region) of Punjab state, India: an area of high cancer incidence. Exposure and Health, 8(4), 513–525.
Sharma, D. A., Rishi, M. S., Keesari, T., & Sinha, U. K. (2016). Assessment of groundwater quality of Bathinda district, Punjab with reference to nitrate contamination. Journal of Applied Geochemistry, 18(4), 480.
Sharma, D. A., Rishi, M. S., & Keesari, T. (2017a). Evaluation of groundwater quality and suitability for irrigation and drinking purposes in southwest Punjab, India using hydrochemical approach. Applied Water Science, 7(6), 3137–3150.
Sharma, D. A., Rishi, M. S., Keesari, T., Pant, D., Singh, R., Thakur, N., & Sinha, U. K. (2017b). Distribution of uranium in groundwaters of Bathinda and Mansa districts of Punjab, India: inferences from an isotope hydrochemical study. Journal of Radioanalytical and Nuclear Chemistry, 313(3), 625–633.
Sherman, H. M., Gierke, J. S., & Anderson, C. P. (2007). Controls on spatial variability of uranium in sandstone aquifers. Groundwater Monitoring & Remediation, 27(2), 106–118.
Singh, K., Hundal, H. S., & Singh, D. (2011). Geochemistry and assessment of hydrogeochemical processes in groundwater in the southern part of Bathinda district of Punjab, northwest India. Environment and Earth Science, 64(7), 1823–1833.
Singh, L., Kumar, R., Kumar, S., Bajwa, B. S., & Singh, S. (2013). Health risk assessments due to uranium contamination of drinking water in Bathinda region, Punjab state, India. Radioprotection, 48(2), 191–202.
Singh, G., Şengör, S. S., Bhalla, A., Kumar, S., De, J., Stewart, B., & Sani, R. K. (2014). Reoxidation of biogenic reduced uranium: a challenge toward bioremediation. Critical Reviews in Environmental Science and Technology, 44(4), 391–415.
Stalder, E., Blanc, A., Haldimann, M., & Dudler, V. (2012). Occurrence of uranium in Swiss drinking water. Chemosphere, 86(6), 672–679.
Statistical Abstract of Punjab. (2014). Economic and statistical organization, government of Punjab. Publication No. 948, p. 758.
Statistical Abstract of Punjab. (2015). Economic and statistical organization, government of Punjab. Publication No. 951, p. 780.
Thivya, C., Chidambaram, S., Keesari, T., Prasanna, M. V., Thilagavathi, R., Adithya, V. S., & Singaraja, C. (2016). Lithological and hydrochemical controls on distribution and speciation of uranium in groundwaters of hard-rock granitic aquifers of Madurai District, Tamil Nadu (India). Environmental Geochemistry and Health, 38(2), 497–509.
Thomas, A., Verma, V. K., Sood, A., Litoria, P. K., Sharma, P. K., & Ravindran, K. (1995). Hydrogeology of Talwandi Sabo tehsil, Bathinda District (Punjab): a remote sensing approach. Journal of the Indian Society of Remote Sensing, 23(2), 47–56.
Tripathi, A., Mishra, A. K., & Verma, G. (2016). Impact of preservation of subsoil water act on groundwater depletion: the case of Punjab, India. Environmental Management, 58(1), 48–59.
Villalobos, M., Trotz, M. A., & Leckie, J. O. (2001). Surface complexation modeling of carbonate effects on the adsorption of Cr (VI), Pb (II), and U (VI) on goethite. Environmental Science & Technology, 35(19), 3849–3856.
WHO. (2012). Uranium in drinking water, background document for development of WHO guidelines for drinking-water quality, Geneva, Switzerland, WHO/SDE/WSH/03.04/118/Rev/1, 29.
Winde, F., & van der Walt, I. J. (2004). The significance of groundwater–stream interactions and fluctuating stream chemistry on waterborne uranium contamination of streams—a case study from a gold mining site in South Africa. Journal of Hydrology, 287(1–4), 178–196.
Acknowledgements
The authors sincerely thank the constant support and encouragement by Dr. U.K. Sinha, Head, Isotope Hydrology Section; Shri K.S.S.Sarma, Head, Isotope and Radiation Application Division; and Dr. B.S. Tomar, former Director, Radiochemistry and Isotope Group, Bhabha Atomic Research Centre, Mumbai. The authors would also like to thank the Water Resources Bhawan, Department of Irrigation, Chandigarh, Punjab, for providing the lithological data and Dr. Thilagavathi, Researcher, Annamalai University of Tamil Nadu for preparing lithological section maps.
Funding
This study was financially supported by the Board of Research in Nuclear Sciences, Department of Atomic Energy, and the Government of India (letter no. 35/14/11/2014-BRNS-193)
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Research highlights
• There is a good correlation between spatial and temporal trends in water levels and dissolved U concentration.
• Changes in the concentration of U in shallow groundwater during the post-monsoon season are controlled by geomorphological features like sand dunes and canal networks.
• The seasonal variations in dissolved U concentration were found to be statistically significant.
• Seasonal and spatial fluctuations of U concentrations were more dominant in shallow groundwater than in deep groundwater.
• Hydraulic interaction between shallow and deep aquifers seems to be unlikely.
• Bicarbonate, dissolved oxygen, nitrate, and sulphate are potential factors facilitating U mobilization in groundwater.
• A conceptual diagram depicting the processes/factors controlling the U occurrence in alluvial aquifers is presented.
Rights and permissions
About this article
Cite this article
Sharma, D.A., Keesari, T., Rishi, M.S. et al. A study on the role of hydrogeology on the distribution of uranium in alluvial aquifers of northwest India. Environ Monit Assess 190, 746 (2018). https://doi.org/10.1007/s10661-018-7112-6
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10661-018-7112-6