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Impact of city effluents on water quality of Indus River: assessment of temporal and spatial variations in the southern region of Khyber Pakhtunkhwa, Pakistan

  • Ilham Khan
  • Azim Khan
  • Muhammad Sohail Khan
  • Shabnam Zafar
  • Asma Hameed
  • Shakeel Badshah
  • Shafiq Ur Rehman
  • Hidayat Ullah
  • Ghazala Yasmeen
Article
  • 127 Downloads

Abstract

The impact of city effluents on water quality of Indus River was assessed in the southern region of Khyber Pakhtunkhwa, Pakistan. Water samples were collected in dry (DS) and wet (WS) seasons from seven sampling zones along Indus River and the physical, bacteriological, and chemical parameters determining water quality were quantified. There were marked temporal and spatial variations in the water quality of Indus River. The magnitude of pollution was high in WS compared with DS. The quality of water varied across the sampling zones, and it greatly depended upon the nature of effluents entering the river. Water samples exceeded the WHO permissible limits for pH, EC, TDS, TS, TSS, TH, DO, BOD, COD, total coliforms, Escherichia coli, Ca2+, Mg2+, NO3, and PO42−. Piper analysis indicated that water across the seven sampling zones along Indus River was alkaline in nature. Correlation analyses indicated that EC, TDS, TS, TH, DO, BOD, and COD may be considered as key physical parameters, while Na+, K+, Ca2+, Mg2+, Cl, F, NO3, PO42−, and SO42− as key chemical parameters determining water quality, because they were strongly correlated (r > 0.70) with most of the parameters studied. Cluster analysis indicated that discharge point at Shami Road is the major source of pollution impairing water quality of Indus River. Wastewater treatment plants must be installed at all discharge points along Indus River for protecting the quality of water of this rich freshwater resource in Pakistan.

Keywords

City effluents Freshwater Indus River Pakistan Pollution Spatio-temporal variations Water quality Water chemistry 

Notes

Acknowledgements

The authors gratefully acknowledge funding from Higher Education Commission (HEC), Government of Pakistan, for conducting the laboratory analysis. We thank the staff of Institute of Chemical Sciences, Gomal University D.I.Khan; National Water Quality Lab. PCRWR, Islamabad, Pakistan; Department of Soil and Environmental Sciences, Faculty of Agriculture, Gomal University D.I.Khan; and Department of Chemistry, Faculty of Physical Sciences, Kohat University of Science and Technology, for their laboratory facilities provided.

References

  1. Ahmed, K., & Ali, W. (2000). Evaluation of Ravi River water quality. Pakistan Journal of Drainage Water Management, 4, 10–15.Google Scholar
  2. Amin, A., Ahmad, T., Ehsanullah, M., Khatak, M. M., Masror, M., & Khan, M. A. (2010). Evaluation of industrial and city effluent quality using physicochemical and biological parameters. Electronic Journal of Environmental, Agricultural and Food Chemistry, 9(5), 931–939.Google Scholar
  3. AOAC (Association of Official Analytical Chemistry) (2000). Official methods of analysis of the association of official analytical chemists. International 17th ed. Gaithersburg: Association of Analytical Communities.Google Scholar
  4. AOAC (Association of Official Analytical Chemistry) (2002). Official methods of analysis of the association of official analytical chemists. International 17th ed. Gaithersburg: Association of Analytical Communities.Google Scholar
  5. APHA (American Public Health Association). (1998). Standard methods for the examination of water and wastewater (20th ed.). Washington, DC: APHA.Google Scholar
  6. APHA (American Public Health Association). (2005). Standard methods for the examination of water and wastewater (21st ed.). Washington, DC: APHA.Google Scholar
  7. ASTM (American Society for Testing and Materials). (1998). Standard test methods for calcium and magnesium in water. West Conshohocken: ASTM International.Google Scholar
  8. Benson, H.J. (1998). Microbiological applications: Laboratory manual in general microbiology, 7th edition, pp. 208˗211.Google Scholar
  9. Bhutta, M.N., Ramzan, M., & Hafeez, C.A. (2002). Ground water quality and availability in Pakistan. Proceedings of seminar on ‘strategies to address the present and future water quality issues’, March 6–7, 2002. Pakistan Council of Research in Water Resources. Islamabad, Pakistan.Google Scholar
  10. Borgmann, U., Couillard, Y., Doyle, P., & Dixon, D. G. (2005). Toxicity of sixty-three metals and metalloids to Hyalella azteca at two levels of water hardness. Environmental Toxicology and Chemistry, 24, 641–652.CrossRefGoogle Scholar
  11. Bukola, D., Zaid, A., Olalekan, E. A., & Falilu, A. (2015). Consequences of anthropogenic activities on fish and the aquatic environment. Poultry, Fisheries & Wildlife Sciences, 3(2), 1–12.CrossRefGoogle Scholar
  12. Carr, G.M., & Neary, J.P. (2008). Water quality for ecosystem and human health, 2nd edition. UNEP Global Environmental Monitoring System Water Programme with International Institute, PAS-European Regional Centre for Eco-hydrology UNESCO IAP Water Programme, pp. 9˗17.Google Scholar
  13. Chaubey, S., & Patil, M. K. (2015). Correlation study and regression analysis of water quality assessment of Nagpur City, India. International Journal of Scientific and Research Publications, 5, 753–757.Google Scholar
  14. David, C. (2004). Small water supplies. Trowbridge: Cromwell Press.Google Scholar
  15. Eaton, A. D., Clesceri, L. S., & Berg, A. E. G. (1995). Standard methods for the examination of water and wastewater (19th ed.). Washington: American Public Health Association.Google Scholar
  16. Egemen, Ö. (2000). Environment and water pollution. Ege University, Faculty of Fisheries. No. 42, Izmir, Turkey, pp. 120.Google Scholar
  17. FAO (Food and Agriculture Organization of the United Nations). (2017). Water pollution from agriculture: A global review. Rome: FAO.Google Scholar
  18. Foster, S. S. D., Morris, B. L., Lawrence, A. R., & Chilton, P. J. (1999). Groundwater impacts and issues in developing cities an introductory review. In J. Chilton (Ed.), Groundwater in urban environment: selected city profiles (pp. 3–16). the Netherlands: Balkema.Google Scholar
  19. Hashmi, S.K., & Shahab, S. (1999). The need for water quality guide lines for Pakistan. (In Proceedings: Water resources achievements and issues in 20th century and challenges for next millennium. Pakistan Council of Research in Water Resources, Islamabad, Pakistan.Google Scholar
  20. Helmer, R., Hespanhol, I. 1997. Water pollution control—A guide to the use of water quality management principles. World Health Organization (WHO), pp. 459.Google Scholar
  21. Heydari, M. M., Abbas, A., Rohani, S. M., & Hosseini, S. M. A. (2013). Correlation study and regression analysis of drinking water quality in Kashan City, Iran. Walailak Journal of Science and Technology, 10, 315–324.Google Scholar
  22. Iqbal, A. R. (2013). Environmental issues of Indus River basin: An analysis. ISSRA Papers. Institute for Strategic Studies, Research & Analysis (ISSRA), National Defence University, Islamabad, Pakistan, 5(1), 89–112.Google Scholar
  23. Iqbal, F., Raza, N., Ali, M., & Athar, M. (2006). Contamination of Kallar Kahar Lake by inorganic elements and heavy metals and their temporal variation. Journal of Applied Science and Environmental Management, 10, 95–98.Google Scholar
  24. Iscen, C. F., Emiroğlu, Ö., Ilhan, S., Arslan, N., Yilmaz, V., & Ahiska, S. (2008). Application of multivariate statistical techniques in the assessment of surface water quality in Uluabat Lake, Turkey. Environmental Monitoring and Assessment, 144, 269–276.CrossRefGoogle Scholar
  25. Javaid, S., Shah, S. G. S., Chaudhary, A. J., & Khan, M. H. (2008). Assessment of trace metal contamination of drinking water in the Pearl Valley, Azad Jammu and Kashmir. Clean, 36, 216–221.Google Scholar
  26. Jurate, V., & Sillanpä, M. (2006). Chemical evaluation of potable water in Eastern Qinghai Province, China: Human health aspects. Chemical evaluation of potable water in Eastern Qinghai Province, China: Human health aspects. Environment International, 32, 80–86.CrossRefGoogle Scholar
  27. Kalyanaraman, S. B., & Geetha, G. (2005). Correlation analysis and prediction of characteristic parameters and water quality index of ground. Water Pollution Research, 24(1), 197–200.Google Scholar
  28. Khan, I., Ullah, H., & Imran, M. (2007). Nitrate and phosphate pollution in surface and ground water in western Malaysia. Journal of Chemical Society of Pakistan, 29, 315–320.Google Scholar
  29. Khan, R. U., Rashid, A., Khan, M. S., & Ozturk, E. (2010). Impact of humic acid and chemical fertilizer application on growth and grain yield of rainfed wheat (Triticum aestivum L.) Pakistan Journal of Agricultural Research, 23, 113–121.Google Scholar
  30. Khatri, N., & Tyagi, S. (2015). Influences of natural and anthropogenic factors on surface and groundwater quality in rural and urban areas. Frontiers in Life Science, 8(1), 23–39.CrossRefGoogle Scholar
  31. Laluraj, C. M., & Gopinath, G. (2006). Assessment of seasonal variation of groundwater quality of Pheretic aquifer—A river basin system. Environmental Monitoring and Assessment, 117, 45–57.CrossRefGoogle Scholar
  32. Mahajan, S. V., Khare, S., & Shrivastava, V. S. (2005). A correlation and regression study. Indian Journal of Environmental Protection, 25, 254–259.Google Scholar
  33. Meadows, P. (1999). The Indus River: Biodiversity, resource, human kind (1st ed.). Karachi: Oxford University Press.Google Scholar
  34. Mechenich, C., & Andrews, E. (2004). Home water safety: Interpreting drinking water test results. Cooperative Extension Publishing, University of Wisconsin–Extension.Google Scholar
  35. Mehdi, T., Mustafa, T., Chaudhry, R., Butt, S., Hoat, A., Ali, M., Amin, K., & Tariq, S. (2009). Profile of district Dera Ismail Khan with focus on livelihood related issues. South Asia Partnership-Pakistan. Haseeb Memorial Trust Building, Nasirabad, 2 km Raiwind Road, P.O. Box Thokar Niaz Beg, Lahore-53700, Pakistan, pp. 1–39.Google Scholar
  36. Memon, M., Soomro, M. S., Akhtar, M. S., & Memon, K. S. (2011). Drinking water quality assessment in Southern Sindh (Pakistan). Environmental Monitoring and Assessment, 177, 39–50.CrossRefGoogle Scholar
  37. Mohsin, M., Safdar, S., Asghar, F., & Jamal, F. (2013). Assessment of drinking water quality and its impact on residents health in Bahawalpur City. International Journal of Humanities and Social Science, 3, 114–128.Google Scholar
  38. Murphy, S. (2007). General information on solids. In City of Boulder: USGS Water Quality Monitoring. http://www.bcn.boulder.co.us/basin/data/NEW/info/TSS.html.
  39. Oram, B. (2012). A drinking water guide for Pennsylvania. Water Research Center B.F. Environmental Consultants Inc. 15 Hillcrest Drive, Dallas, PA 18612.Google Scholar
  40. Pathak, H., Pathak, D., & Limaye, S. N. (2012). Studies on the physico-chemical status of two water bodies at Sagar city under anthropogenic influences. Advances in Applied Science Research, 3(1), 31–44.Google Scholar
  41. Payne, R. W., Murra, Y. D. A., Harding, S. A., Baird, D. B., & Soutar, D. M. (2009). GenStat for Windows (12th ed.). Hemel, Hempstead: VSN International.Google Scholar
  42. Piper, M. (1944). A graphic procedure in the geochemical interpretation of water-analyses. EOS, Transactions, American Geophysical Union, 25, 914–928.CrossRefGoogle Scholar
  43. Popa, P., Timofti, M., Voiculescu, M., Dragan, S., Trif, C., & Georgescu, L. P. (2012). Study of physico-chemical characteristics of wastewater in an urban agglomeration in Romania. The Scientific World Journal.  https://doi.org/10.1100/2012/549028.
  44. PSQCA (Pakistan Standard & Quality Control Authority) (2008). Guidelines and standards for drinking-water quality.Google Scholar
  45. Radha, K. R., Dharmaraj, K., & Kumari, B. D. R. (2007). A comparative study on the physicochemical and bacterial analysis of drinking, borewell and sewage water in the three different places of Sivakasi. Journal of Environmental Biology, 28(1), 105–108.Google Scholar
  46. Rasheed, B. (2013). Impact assessment of hydroclimatic change on water stress in the Indus Basin. M.Sc. Thesis. Massachusetts Institute of Technology, pp. 114.Google Scholar
  47. SDPI (Sustainable Development Policy Institute, Islamabad, Pakistan) (1993). Policy Paper Series No. 3. http://www.sdpi.org.
  48. Shafiq, H. B., Ajaz, M., & Rasool, S. A. (2011). Bacterial and toxic pollutants in lakes of River Indus. Pakistan Journal of Botany, 43, 1765–1772.Google Scholar
  49. Shah, M. T., Alizai, A. H., & Khan, S. D. (2012). Environmental geochemistry of surface and subsurface water from Dera Ismail Khan Division, Khyber Pakhtunkhwa, Pakistan. Journal of Chemical Society of Pakistan, 34, 243–250.Google Scholar
  50. Shar, A. H., Kazi, Y. F., & Soomro, I. H. (2008). Impact of seasonal variation on bacteriological quality of drinking water. Bangladesh Journal of Microbiology, 25, 69–72.Google Scholar
  51. Sunitha, V., Sudharshan, V., & Reddy, B. R. (2005). Hydrogeochemistry of ground water, Gooty area, Anantapur district, AndhraPradesh, India. Pollution Research, 24(1), 217–224.Google Scholar
  52. Tahir, M.A., & Bhatti, M.A. (1994). Survey of drinking water quality in the rural areas of Rawalpindi district. Proceedings of Pakistan Council of Research in Water Resources, Islamabad.Google Scholar
  53. Trivedi, P., Bajpai, A., & Thareja, S. (2009). Evaluation of water quality: Physico-chemical characteristics of Ganga River at Kanpur by using correlation study. Nature and Science, 1, 91–94.Google Scholar
  54. UNICEF (United Nations International Children’s Emergency Fund) (2010). Intervention report on D.I.Khan. http://www.complex.pakresponse.info.
  55. USEPA (United States Environmental Protection Agency Office of Water) (1999). Engineering and Analysis Division1200 Pennsylvania Avenue, NW (4303T) Washington, DC 20460.Google Scholar
  56. Usharani, K., Umarani, K., Ayyasamy, P. M., Shanthi, K., & Lakshmanaperumalsamy, P. (2010). Physico-chemical and bacteriological characteristics of Noyyal River and ground water quality of Perur, India. Journal of Applied Science and Environmental Management, 14(2), 29–35.Google Scholar
  57. Westcot, D.W. (1997). Quality control of wastewater for irrigated crop production. FAO water reports no. 10 Rome, pp. 86.Google Scholar
  58. WHO (World Health Organization) (2000). Global water supply and sanitation assessment report.Google Scholar
  59. WHO (World Health Organization) (2003). Total dissolved solids in drinking-water. Background document for development of WHO “Guidelines for Drinking-water Quality”.Google Scholar
  60. WHO (World Health Organization) (2011a). Guidelines for drinking water quality, 4th Edition, pp. 564.Google Scholar
  61. WHO (World Health Organization) (2011b). Nitrate and nitrite in drinking-water. Background document for development of WHO “Guidelines for Drinking-water Quality”.Google Scholar
  62. Wurts, W.A., & Masser, M.P. (2004). Southern Regional Aquaculture Center, Publication No. 4100.Google Scholar
  63. WWAP (World Water Assessment Programme) (2003). Water for people, water for life (2003): 3rd World Water Forum in Kyoto, Japan. http://www.norman-network.net.
  64. WWAP (World Water Assessment Programme) (2017). The United Nations world water development report: Wastewater, the untapped resource. United Nations Educational, Scientific and Cultural Organization, Paris.Google Scholar
  65. Zafar, S., Khan, A., Ullah, H., Khan, M. S., Khan, I., Hameed, A., Rehman, S. U., & Yasmeen, G. (2017). Assessing impact of effluent discharge on irrigation water quality in southern region of Khyber Pakhtunkhwa, Pakistan. Environmental Monitoring and Assessment, 189, 156.CrossRefGoogle Scholar

Copyright information

© Springer International Publishing AG, part of Springer Nature 2018

Authors and Affiliations

  • Ilham Khan
    • 1
  • Azim Khan
    • 1
  • Muhammad Sohail Khan
    • 2
  • Shabnam Zafar
    • 1
  • Asma Hameed
    • 1
  • Shakeel Badshah
    • 3
  • Shafiq Ur Rehman
    • 4
  • Hidayat Ullah
    • 1
  • Ghazala Yasmeen
    • 5
  1. 1.Institute of Chemical SciencesGomal UniversityDera Ismail KhanPakistan
  2. 2.Faculty of AgricultureGomal UniversityDera Ismail KhanPakistan
  3. 3.National Water Quality Laboratory, PCRWRIslamabadPakistan
  4. 4.National Water Quality Laboratory, PCRWRDera Ismail KhanPakistan
  5. 5.Institute of Chemical SciencesBahauddin Zakariya UniversityMultanPakistan

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