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A novel pollution index based on the bioavailability of elements: a study on Anzali wetland bed sediments

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Abstract

In this research, we study on the distribution of several elements in bed sediments of Anzali wetland. Anzali, one of the most important international wetlands, is located on the southern coast of the Caspian Sea in Iran. This wetland receives discharges of domestic, agricultural, and industrial wastewater, which affect the distribution of elements. Our contribution in this study is threefold. First, we measured the total concentration of metals as well as their chemical partitioning and bioavailability in the sediments. Second, we calculated anthropogenic portions of metals in the sediment of this area. The results reveal anthropogenic portion of metals as Mo > Mn > Cd > As > Zn > Hg > Co > Sn > Cu > V > Ag > Ni > Pb > Fe > Cr > Al, respectively. We evaluated the intensity of pollution by using an enrichment factor, the geo-accumulation index and the pollution index. All these indices do not take into consideration the bioavailability of the elements. As our third and most important contribution, we introduced a new formula that takes into account the bioavailability of different elements. In comparison with aforementioned pollution indices, our newly introduced pollution index has a higher Pearson correlation with anthropogenic portion of metals. This high-correlation coefficient shows that our proposed pollution index is an effective indicator for determining the level of pollution, while other indices preserve their own merits.

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Authors and Affiliations

  1. Department of Environment and Energy, Science and Research Branch, Islamic Azad University, Tehran, Iran

    Fariba Zamani Hargalani & Seyed Masoud Monavari

  2. Graduate Faculty of Environment, University of Tehran, 14155-6135, Tehran, Iran

    Abdolreza Karbassi

  3. Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran

    Parviz Abroomand Azar

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  1. Fariba Zamani Hargalani
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  2. Abdolreza Karbassi
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  3. Seyed Masoud Monavari
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  4. Parviz Abroomand Azar
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Correspondence to Fariba Zamani Hargalani.

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Zamani Hargalani, F., Karbassi, A., Monavari, S.M. et al. A novel pollution index based on the bioavailability of elements: a study on Anzali wetland bed sediments. Environ Monit Assess 186, 2329–2348 (2014). https://doi.org/10.1007/s10661-013-3541-4

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