Skip to main content
Log in

Leaching behaviour of chlorpyriphos and cypermethrin in sandy loam soil

  • Published:
Environmental Monitoring and Assessment Aims and scope Submit manuscript

Abstract

The mobility of chlorpyriphos and cypermethrin in sandy loam soil was studied in soil columns under laboratory conditions at two application rates, 25 and 50 μg, with simulated rainfall of 300 mm. Residues of chlorpyriphos and cypermethrin in soil and leachate were estimated by gas–liquid chromatography and confirmed by gas chromatography–mass spectrometry. Though maximum concentration of both the insecticides was found in the top 10-cm layer, chlorpyriphos was found distributed in the soil up to a depth of 35 cm and cypermethrin remained up to 15 cm. Results indicated the low mobility of both the insecticides under saturated moisture condition and hence may not contaminate ground water. No residues of any insecticide were detected in the leachate fractions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  • Burauel, P., & Bassmann, F. (2005). Soils as filter and buffer for pesticides- experimental concepts to understand soil functions. Environmental Pollution, 133, 11–16.

    Article  CAS  Google Scholar 

  • Chapman, R. A., & Harris, C. R. (1981). Persistence of four pyrethroid insecticides in a mineral and an organic soil. Journal of Environmental Science and Health, B16(5), 605–615.

    Article  CAS  Google Scholar 

  • Chapman, R. A., Tu, C. M., Harris, C. R., & Cole, C. (1981). Persistence of five pyrethroid insecticides in sterile and natural, mineral and organic soil. Bulletin of Environmental Contamination and Toxicology, 26, 513–519.

    Article  CAS  Google Scholar 

  • Chia, L. K., & Zaidel, N. D. (2011). Sorption, degradation and leaching of cypermethrin in Malaysian soils. Malaysian Journal of Chemistry, 13(1), 001–007.

    Google Scholar 

  • Crisanto, T., Sanchez-Martin, M. J., & Sanchez-Camazano, M. (2000). Mobility of pesticides in soils influence of soil properties and pesticide structure. Toxicology and Environmental Chemistry, 47, 97–104.

    Google Scholar 

  • Goring, C. A. I., & Hamakers, J. W. (1975). Principle of pesticide degradation in soil. In R. Haque & V. H. Freed (Eds.), Environmental Dynamics of Pesticides. New York: Plenum Press.

    Google Scholar 

  • Gupta, S., & Gajbhiye, V. T. (2002). Persistence and leaching of β-cyfluthrin in alluvial soil of India. Pest Management Science, 58(12), 1256–1259.

    Article  Google Scholar 

  • Halimah, M., Zulkifli, M., Tan, Y. A., Hasnol, O., & Ismail, B. S. (2011). Leaching of chlorpyriphos in peat soil of an oil palm plantation in Malaysia. American-Eurasian Journal of Sustainable Agriculture, 5(2), 209–215.

    Google Scholar 

  • Halimah, M. N., Nashriyah, M., Tan, Y. A., & Ismail, B. S. (2004). Adsorption and desorption study of 14C-chlorpyriphos in two Malaysian agricultural soils. Journal of Nuclear and Related Technology, 1(1), 31–40.

    Google Scholar 

  • Ismail, B. S., & Kalithasan, K. (2003). Dissipation and mobility of permethrin in the field with repeated applications under tropical conditions. Journal of Environmental Science and Health. Part. B, 34, 355–364.

    Google Scholar 

  • Ismail, B. S., Ngan, C. K., Cheah, U. B., & Abdullah, W. Y. (2004). Leaching potential of pesticides in a vegetable farm in the Cameron highlands, Malaysia. Bulletin of Environmental Contamination and Toxicology, 72(4), 836–843.

    Article  CAS  Google Scholar 

  • Jin, H., & Webster, G. R. B. (1998a). Dissipation of chlorpyrifos, oxon and 3,5,6- trichloro-2-pyridinol in litter and elm forest soil. International Journal of Environmental Analytical Chemistry, 69, 307–316.

    Article  CAS  Google Scholar 

  • Jin, H., & Webster, G. R. B. (1998b). Persistence, penetration, and surface availability of cypermethrin and its major degradation products in elm bark. Journal of Agricultural and Food Chemistry, 46, 2851–2857.

    Article  CAS  Google Scholar 

  • Kidd, H., & James, D. R. (Eds.). (1991). The agrochemicals handbook (3rd ed.). Cambridge: Royal Society of Chemistry, Information Services.

    Google Scholar 

  • Kotoula-Syka, E., Eleftherohoninos, I. G., Gagiana, A. A., & Scifas, A. G. (1993). Persistence and pre-emergence application of chlorsulfuron, metasulfaron, tri-sulfuron and tribenuron in thee soils in Greece. Weed Science, 41, 246–250.

    CAS  Google Scholar 

  • Kumari, B., Madan, V. K., & Kathpal, T. S. (2008). Status of insecticide contamination of soil and water in Haryana, India. Environmental Monitoring and Assessment, 136, 239–244.

    Article  CAS  Google Scholar 

  • Lehmann, R. G., Miller, J. R., & Cleveland, C. B. (1993). Fate of fluroxypyr in water. Weed Research, 33, 197–204.

    Article  CAS  Google Scholar 

  • Manoj, V. B., & Gajbhiye, V. T. (2007). Adsorption—desorption and leaching of bifenthrin in soil. Pesticide Research Journal, 19(2), 257–261.

    CAS  Google Scholar 

  • Mishra, M. P. (2002). Field evaluation of some newer insecticides against aphids (Aphis gossypii) and jassids (Amrasca biguttula) on okra. Indian Journal of Entomology, 64(1), 80–84.

    Google Scholar 

  • Muhamad, H., Tan, Y. A., Sahid, I., & Nashriyah, M. (2010). Downward movement of chlorpyriphos in the soil of an oil palm plantation in Sepang, Selangor, Malaysia. Journal of Oil Palm Research, 22, 721–728.

    Google Scholar 

  • Oppong, F. K., & Sagar, G. R. (1992). Degradation of triasulfuron in soil under laboratory conditions. Weed Research, 32, 157–165.

    Article  CAS  Google Scholar 

  • Racke, K. D. (1993a). Environmental fate of chlorpyrifos. Review of Environmental Contamination and Toxicology, 131, 1–151.

    CAS  Google Scholar 

  • Racke, K. D. (1993b). Environmental fate of chlorpyrifos. Rev Environ Contam Toxicol, 131, 1–150.

    CAS  Google Scholar 

  • Rao, S., & Satpathy, S. (1999). Influence of sowing date and insecticides on the incidence of jassid and fruit borer on okra. Vegetable Science, 26(1), 74–79.

    Google Scholar 

  • Regupathy, A., Ramasubramania, T., & Ayyasamy, R. (2004). Rationale behind the use of insecticide mixtures for the management of insecticide resistance in India. International Journal of Food Agricultural Environment, 2(2), 278–284.

    CAS  Google Scholar 

  • Sakata, S., Nobuyoshi, M., Matsuda, T., & Miyamoto, J. (1986). Degradation and leaching behavior of the pyrethroid insecticide cypermethrin in soils. Journal of Pesticide Science, 11, 71–79.

    Article  CAS  Google Scholar 

  • Tariq, M. Y., Afzal, S., & Hussain, I. (2006). Degradation and persistence of cotton pesticides in sandy loam soils from Punjab. Pakistan and Environmental Research, 100, 184–196.

    Article  CAS  Google Scholar 

  • Thompson, M., Ellison, S. L. R., & Wood, R. (2002). Harmonized guidelines for single laboratory validation of methods of analysis. (IUPAC Technical Report). Pure and Applied Chemistry, 74, 835–855.

    Article  CAS  Google Scholar 

  • Tomlin, C. (1994). The pesticide manual: a world compendium (10th ed.). Alton: The British Crop Protection Council.

    Google Scholar 

  • Tripathi, D. M., Bisht, R. S., & Mishra, P. N. (2003). Bio-efficacy of some synthetic insecticides and biopesticides against black cutworm, Agrotis ipsilon infesting potato (Solanum tuberosum) in Garhwal Himalaya. Indian Journal of Entomology, 65(4), 468–473.

    Google Scholar 

  • Walker, A., & Exposito, M. J. (1998). Adsorption of isoproturon, diuron and metsulfuron methyl in two soils at high soil-solution ratio. Weed Research, 38, 229–238.

    Article  CAS  Google Scholar 

  • Walker, A., Cotterill, E. G., & Welch, S. J. (1989). Adsorption and degradation of chlorsulfuron and metsulfuron-methyl and triasulfuron in soils from different depths. Weed Science, 29, 281–287.

    CAS  Google Scholar 

  • Ware, G. W., & Whitacre, D. M. (2004). The pesticide book (6th ed.). Willoughby: MeisterPro Information Resources.

    Google Scholar 

Download references

Acknowledgments

The authors wish to express their gratitude to the Head, Department of Entomology for providing research facilities.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Beena Kumari.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rani, M., Saini, S. & Kumari, B. Leaching behaviour of chlorpyriphos and cypermethrin in sandy loam soil. Environ Monit Assess 186, 175–182 (2014). https://doi.org/10.1007/s10661-013-3364-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10661-013-3364-3

Keywords

Navigation