Abstract
Dissipation of chlorpyriphos and cypermethrin in chilli was studied following three applications of a combination formulation of Nurelle-D 505 (chlorpyriphos 50 % + cypermethrin 5 %) at 1 and 2 L ha−1 at an interval of 15 days. Residues of chlorpyriphos and cypermethrin in chilli were estimated by gas–liquid chromatography and confirmed by gas chromatography–mass spectrometry. Half-life periods for chlorpyriphos were found to be 4.43 and 2.01 days, whereas for cypermethrin these values were observed to be 2.51 and 2.64 days at single and double the application rates, respectively. Residues of chlorpyriphos dissipated to more than 80 % after 10 days at both the dosages. However, residues of cypermethrin dissipated to the extent of more than 70 % in 7 days. Soil samples collected after 15 days of the last application did not show the presence of chlorpyriphos and cypermethrin at their respective determination limit of 0.01 mg kg−1. The use of chlorpyriphos and cypermethrin mixture at the recommended dosage does not seem to pose any hazards to the consumers, and a waiting period of 1 day is suggested to reduce the risk before consumption of green chilli.
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References
Anonymous. (2000). Chlorpyriphos. Office of Prevention, Pesticide and Toxic Substance, US Environmental Protection Agency Washington, DC, June 20.
Anonymous. (2002). Opinion of the Scientific Committee on Food on capsaicin. European Commission Health & Consumer Protection Directorate-General. http://ec.europa.eu/food/fs/sc/scf/out120_en.pdf. Accessed 15 May 2012.
Anonymous. (2010) Package of practices for cultivation of vegetables. Punjab Agricultural University, Ludhiana, India, pp. 41–43.
Chahal, K. K., Singh, B., Kang, B. K., Battu, R. S., & Joia, B. S. (1997). Insecticide residues in farm gate vegetable samples in Punjab. Pesticide Research Journal, 9, 256–260.
Chahal, K. K., Singh, B., Battu, R. S., & Kang, B. K. (1999). Monitoring of farmgate vegetables for insecticide residues in Punjab. Indian Journal of Ecology, 26, 50–55.
Chaudhary, B. (2000). Solanaceous fruits and cole crops vegetables (pp. 63–84). India: National Book Trust.
Cochran, R. C., Kishiyama, J., Aldous, C., Carr, W. C., & Pfeifer, K. F. (1995). Chlorpyriphos: hazard assessment based on a review of the effects of short-term and long-term exposure in animals and humans. Food and Chemical Toxicology, 33, 165–172.
Gunther, F. A., & Blinn, R. C. (1955). Analysis of insecticides and acaricides. New York: Interscience Publishers. 696 pp.
Gupta, S., Gajbhiye, V. T., Sharma, R. K., & Gupta, R. K. (2011). Dissipation of cypermethrin, chlorpyriphos, and profenofos in tomato fruits and soil following application of pre-mix formulations. Environmental Monitoring and Assessment, 174, 337–345.
Hoskins, W. M. (1961). Mathematical treatments of loss of pesticide residues. FAO Plant Protection Bulletin, 9, 163–168.
Jee, J. H., Masroor, F., & Kang, J. C. (2005). Responses of cypermethrin-induced stress in haematological parameters of Korean rockfish, Sebastes schlegeli (Hilgendorf). Aquatic Research, 36, 898–905.
Khan, M. A. M., Reddy, D. J., & Rao, S. V. (1999). Dissipation of cypermethrin residues in okra fruits. Pesticide Research Journal, 11, 84–85.
Kumar, P., Singh, S. P., & Tanwar, R. S. (1998). Dissipation of cypermethrin residue on chickpea. Pesticide Research Journal, 10, 242–245.
Kumar, K. P., Reddy, D. J., Reddy, K. N., Babu, T. R., & Narendranath, V. V. (2000). Dissipation and decontamination of triazophos and acephate residues in chilli (Capsicum annum Linn). Pesticide Research Journal, 12, 26–29.
Lindsay, D. G. (1997). Pesticide residue in food: the need for fairer cost–benefit analysis. Pesticide Outlook, 8, 6–10.
Mukherjee, I., & Gopal, M. (2000). Environmental behaviour and translocation of imidacloprid in eggplant, cabbage and mustard. Pest Management Science, 56, 932–936.
Oliver, G. R., Bolles, H. G., & Shurdut, B. A. (2000). Chlorpyriphos: probabilistic assessment of exposure and risk. Neurotoxic, 21, 203–208.
Puttarudraih, M. (1959). Short review on the chilli leaf curl complex and spray programme for its control. Mysore Journal of Agricultural Science, 34, 93–95.
Raina, A. K., & Raina, M. (2008). Dissipation of chlorpyriphos on cauliflower (Brassica oleracea L. var. botrytis). Pesticide Research Journal, 20, 263–265.
Rao, C. S., Bour, T. B., & Reddy, K. N. (2005). Pesticide residues: impact on Indian Agriculture exports in WTO era. Proceedings of the National Symposium on Pesticide Residues and Their Risk Assessment, January 20–21, 2005, pp. 54–57.
Reddy, D. N. R., & Puttaswamy, M. (1983). Pests infesting chilli in the transplanted crop. Mysore Journal of Agricultural Science, 17, 246–251.
Reddy, D. N. R., & Puttaswamy, M. (1984). Pests infesting chilli (Capsicum annum L.) in nursery. Mysore Journal of Agricultural Science, 18, 122–125.
Reddy, K. D., Reddy, K. N., & Mahalingappa, P. B. (2007a). Dissipation of fipronil and profenofos residues in chillies (Capsicum annum L.). Pesticide Research Journal, 19, 106–107.
Reddy, K. N., Satyanarayana, S., & Reddy, K. D. (2007b). Persistence of some insecticides in chillies. Pesticide Research Journal, 19, 234–236.
Regupathy, A., Ramasubramanian, T., & Ayyasamy, R. (2004). Rationale behind the use of insecticide mixtures for the management of insecticide resistance in India. International Journal of Food Agriculture Environment, 2, 278–284.
Samriti, Chauhan, R., & Kumari, B. (2011). Persistence and effect of processing on reduction of chlorpyriphos residues in okra fruits. Bulletin of Environmental Contamination and Toxicology, 87, 198–201.
Shah, P. G., Raj, M. F., Patel, B. A., Patel, B. K., Diwan, K. D., Patel, J. A., & Talati, J. G. (2000). Pesticidal contamination status in farm gate vegetables in Gujarat. Pesticide Research Journal, 12, 95–99.
Sharma, K. K. (2007). Pesticide residue analysis manual. Directorate of Information and Publications of Agriculture, Indian Council of Agricultural Research, New Delhi, 294 pp.
Singh, P. P., Singh, B., & Battu, R. S. (1990). Residues of cypermethrin, fenvalerate and deltamethrin on cauliflower. Phytoparasitica, 18, 153–158.
Singh, B., Gupta, A., Bhatnagar, A., & Parihar, N. S. (1999). Monitoring of pesticide residues in farm gate samples of chillies. Pesticide Research Journal, 11, 207–209.
Worthing, C. R. (1987). Pesticide manual. A world compendium. UK: British Crop Protection Council. 1081 pp.
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The authors are thankful to the Professor and Head of the Department of Entomology, PAU, Ludhiana, for providing the necessary research facilities. Financial assistance provided by the Indian Council of Agricultural Research (ICAR), New Delhi. India, is also gratefully acknowledged.
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Jyot, G., Mandal, K., Battu, R.S. et al. Estimation of chlorpyriphos and cypermethrin residues in chilli (Capsicum annuum L.) by gas–liquid chromatography. Environ Monit Assess 185, 5703–5714 (2013). https://doi.org/10.1007/s10661-012-2977-2
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DOI: https://doi.org/10.1007/s10661-012-2977-2