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Phosphorus sorption–desorption behaviour of river bed sediments in the Abshineh river, Hamedan, Iran, related to their composition

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Abstract

Phosphorus (P) sorption by sediments may play a vital role in buffering P concentration in the overlying water column. To characterize P sorption–desorption in the river bed sediments, 17 bed sediment samples collected from Abshineh river, in a semi arid region, Hamedan, western Iran were studied through a batch experiment and related to sediment composition. The sorbed fraction ranged from 4.4% to 5.4% and from 38.5% to 86.0% of sorption maxima when 20 and 1,500 mg P kg−1, respectively, was added to the sediment samples. Phosphorus sorption curves were well fitted to the Langmuir model. Zero equilibrium P concentration ranged from 0.10 to 0.51 mg P l−1 and varied with sediment characteristics. Phosphorus desorption differed strongly among the studied bed sediments and ranged from 10.8% to 80.2% when 1,500 mg P kg−1 was added. The results of the geochemical modelling indicated that even under low P addition (2 mg l−1), the solutions are mainly saturated with respect to hydroxyapatite and ß-tricalcium phosphate minerals and undersaturated with respect to other Ca and Mg minerals, whereas under higher P addition (150 mg l−1), most Ca–P solid phases, except the most soluble mineral (brushite), will likely precipitate. A Langmuir sorption maximum was positively correlated with carbonate calcium. Estimated P retention capacity of the bed sediments are generally lower and zero equilibrium P concentration values higher in upstream sites than at the downstream sites, suggesting that sediments in upstream and downstream may act as source and sink of P, respectively.

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  1. Department of Soil Science, College of Agriculture, Bu-Ali Sina University, Hamedan, Iran

    Mohsen Jalali & Elahe Naderi Peikam

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Jalali, M., Peikam, E.N. Phosphorus sorption–desorption behaviour of river bed sediments in the Abshineh river, Hamedan, Iran, related to their composition. Environ Monit Assess 185, 537–552 (2013). https://doi.org/10.1007/s10661-012-2573-5

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