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The efficiency of Amberlite XAD-4 resin loaded with 1-(2-pyridylazo)-2-naphthol in preconcentration and separation of some toxic metal ions by flame atomic absorption spectrometry

Environmental Monitoring and Assessment volume 175, pages 201–212 (2011)Cite this article

Abstract

A selective method has been developed for the determination of trace amount of metal ions after preconcentration on 1-(2-pyridylazo)-2-naphthol loaded Amberlite XAD-4 resin. The chelating resin was characterized on the basis of infra red spectra, thermal and chemical stability, and hydrogen ion capacity. High preconcentration factor of 160–400 up to a low preconcentration limit of 10 μg L − 1 has been achieved for almost all the metals. The chelating resin was highly selective even in the presence of large concentrations of alkali and alkaline earth metals and various matrix components. Chromatographic separation of metal ions in binary mixtures has been accomplished. The analytical utility of the resin for metal ions was explored by analyzing natural water and standard reference materials.

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Authors and Affiliations

  1. Department of Chemistry, Aligarh Muslim University, Aligarh, Uttar Pradesh, India, 202002

    Aminul Islam, Mohammad Asaduddin Laskar & Akil Ahmad

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  1. Aminul Islam
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  2. Mohammad Asaduddin Laskar
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  3. Akil Ahmad
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Correspondence to Aminul Islam.

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Islam, A., Laskar, M.A. & Ahmad, A. The efficiency of Amberlite XAD-4 resin loaded with 1-(2-pyridylazo)-2-naphthol in preconcentration and separation of some toxic metal ions by flame atomic absorption spectrometry. Environ Monit Assess 175, 201–212 (2011). https://doi.org/10.1007/s10661-010-1506-4

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  • DOI: https://doi.org/10.1007/s10661-010-1506-4

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