Abstract
This article analyses elemental composition of suspended particulate matter (SPM) samples collected monthly from 1999 to 2005 at two locations in Yokohama, Japan. Microwave digestion and inductively coupled plasma mass spectroscopy was employed to measure Mg, Al, Ca, V, Cr, Mn, Ni, Cu, Zn, Ga, As, Se, Rb, Sr, Ag, Cd, Cs, Ba, Pb, and Bi. Water-soluble ions (Na + , NH4 + , K + , Ca2 + , Cl − , NO3 − , and SO4 2 − ) and carbonaceous mass (elemental and organic carbon) were detected using ion chromatograph and CHN analyzer, respectively. The results indicate that the composition of SPM on one of the sites is determined by automobile emissions and on the other by industrial combustions. The impact of the emission regulations for automobiles in large Japanese cities, which were enacted during 2002 and 2003, on the SPM composition of the samples is also studied.
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Báez, P. A., García, M. R., Torres, B. M., Del, C., Padilla, H. G., Belmont, R. D., et al. (2007). Origin of trace elements and inorganic ions in PM10 aerosols to the South of Mexico City. Atmospheric Research, 85(1), 52–63.
Bem, H., Gallorini, M., Rizzio, E., & Krzemińska, M. (2003). Comparative studies on the concentrations of some elements in urban air particulate matter in Lodz City of Poland and in Milan, Italy. Environmental International, 29, 423–428.
Birmili, W., Allen, A. G., Bary, F., & Harrison, R. M. (2006). Trace metal concentrations and water solubility in size-fractionated atmospheric particles and influence of road traffic. Environmental Science and Technology, 40, 1144–1153.
Brunner, P. H., & Rechberger, H. (2004). Practical handbook of material flow analysis (pp. 287–288). Boca Raton: Lewis.
Buzica, D., Gerboles, M., Borowiak, A., Trincherini, P., Passarella, R., & Pedroni, V. (2006). Comparison of voltammetry and inductively coupled plasma-mass spectrometry for the determination of heavy metals in PM10 airborne particulate matter. Atmospheric Environment, 40, 4703–4710.
Canepari, S., Cardarelli, E., Giuliano, A., & Pietrodangelo, A. (2006). Determination of metals, metalloids and non-volatile ions in airborne particulate matter by a new two-step sequential leaching procedure. Part A: Experimental design and optimization. Talanta, 69, 581–587.
De Miquel, E., Llamas, J. F., Chacón, E., Berg, T., Larssen, S., Royset, O., et al. (1997). Origin and patterns of distribution of trace element in street dust: Unleaded petrol and urban lead. Atmospheric Environment, 17, 2733–2740.
Dockery, D. W., Pope, C. A., Xu, X., Spengler, J. D., Ware, J. H., Fay, M. E., et al. (1993). An association between air pollution and mortality in six U.S. cities. The New England Journal of Medicine, 329, 1753–1759.
Fukuyama, T., & Fujiwara, H. (2008). Contribution of Asian dust to atmospheric deposition of radioactive cesium (137Cs). Science of the Total Environment, 405(1–3), 389–395.
Funasaka, K., Sakai, M., Shinya, M., Miyazaki, T., Kamiura, T., Kaneco, S., et al. (2003). Size distributions and characteristics of atmospheric inorganic particles by regional comparative study in Urban Osaka, Japan. Atmospheric Environment, 37, 4597–4605.
Garg, B., Cadle, S. H., Mulawa, P. A., Groblicki, P. J., Laroo, C., & Parr, G. A. (2000). Brake wear particulate matter emissions. Environmental Science and Technology, 21, 4463–4469.
Grossi, C. M., & Brimblecombe, P. (2002). The effect of atmospheric pollution on building materials. Journal of Physics IV France, 12, 10–197.
Harrison, R. M., Jones, A. M., & Lawrence, R. G. (2003). A pragmatic mass closure model for airborne particulate matter at urban background and roadside locations. Atmospheric Environment, 37, 4927–4933.
Harrison, R. M., Smith, D. J. T., Pio, C. A., & Castro, L. M. (1996). Source apportionment of atmospheric polycyclic aromatic hydrocarbons collected from an urban location in Birmingham, UK. Environmental Science and Technology, 30(3), 825–832.
Japan Environmental Council (2003). Future policy for motor vehicle emission reduction (eighth report), February 22.
Kanai, Y., Ohta, A., Kamioka, H., Imai, N., Shimizu, H., Takahashi, Y., et al. (2005). Observation of mass concentration and particle size of atmospheric aerosol in East Asia and dry deposition in Tsukuba in combination with optical particle counter observation. Bulletin of the Geological Survey of Japan, 56(7–8), 273–301.
Mar, T. F., Norris, G. A., Koenig, J. Q., & Larson, T. V. (2000). Association between air pollution and mortality in Phoenix, 1995–1997. Environmental Health Perspective, 108(4), 347–353.
Ministry of Land, Infrastructure and Transport, Japan (2005). Report of road traffic census in Yokohama.
Mori, I., Sun, Z., Ukachi, M., Nagano, K., Mcleod, C. W., Cox, A. G., et al. (2008). Development and certification of the new NIES CRM 28: Urban aerosols for the determination of multielements. Analytical & Bioanalytical Chemistry, 391, 1997–2003.
Murakami, Y., & Ono, M. (2006). Myocardial infarction deaths after high level exposure to particulate matter. Journal of Epidemiology and Community Health, 60, 262–266.
Okuda, T., Tenmoku, M., Kato, J., Junya, M., Sato, T., Yokochi, R., et al. (2006). Long-term observation of trace metal concentration in aerosols at a remote island, Rishiri, Japan by using inductively coupled plasma mass spectrometry equipped with laser ablation. Water, Air, & Soil Pollution, 174(1–4), 3–17.
Omori, T., Fujimoto, G., Yoshimura, I., Nitta, H., & Ono, M. (2003). Effects of particulate matter on daily mortality in 13 Japanese cities. Journal of Epidemiology, 13(6), 314–322.
Oura, Y., Iguchi, H., Nagahata, T., Nakamatsu, H., Otoshi, T., & Ebihara, M. (2007). Elemental compositions of atmospheric particulates collected in Japan from 2002 to 2004. Journal of Radioanalytical and Nuclear Chemistry, 272(2), 381–385.
Pacyna, J. M. (1998). Source inventories for atmospheric trace metals. In R. M. Harrison, & R. E. van Grieken (Eds.), Atmospheric particles. IUPAC series on analytical and physical chemistry of environmental systems (Vol. 5, pp. 385–423). Chichester: Wiley.
Perrino, C., Canepari, S., Cardarelli, E., Catrambone, M., & Sargolini, T. (2008). Inorganic constituents of urban air pollution in the Lazio region (Central Italy). Environmental Monitoring and Assessment, 136, 69–86.
Pope, C. A. 3rd, & Dockery, D. W. (2006). Health effects of fine particulate air pollution: Lines that connect. Journal of Air & Waste Management Association, 56, 709–742.
Pope, C. A., Dockery, D. W., & Schwartz, J. (1995a). Review of epidemiological evidence of health effects of particulate air pollution. Inhalation Toxicology, 7, 1–18.
Pope, C. A. 3rd, Thun, M. J., Namboodiri, M. M., Dockery, D. W., Evans, J. S., Speizer, F. E., et al. (1995b). Particulate air pollution as a predictor of mortality in a prospective study of US adults. American Journal of Respiratory and Critical Care Medicine, 151, 669–674.
Russell, L. M. (2003). Aerosol organic-mass-to-organic-carbon ratio measurements. Environmental Science & Technology, 37, 2982–2987.
Seinfeld, J., & Pandis, S. N. (2006). Atmospheric chemistry and physics: From air pollution to climate change. New York: Wiley.
Slezakova, K., Pereira, M. C., Reis, M. A., & Alvim-Ferraz, M. C. (2007). Influence of traffic emissions on the composition of atmospheric particles of different sizes—part 1: Concentration and elemental characterization. Journal of Atmospheric Chemistry, 58, 55–68.
Smolders, E., & Degryse, F. (2002). Fate and effect of zinc from tyre debris in soil. Environmental Science & Technology, 36, 3706–3710.
Sörme, L., Bergbäck, B., & Lohm, U. (2001). Goods in the anthroposphere as a metal emissions source - a case study of Stockholm, Sweden. Water, Air, and Soil pollution: Focus, 1, 213–227.
Srivastava, A., Gupta, S., & Jain, V. K. (2008). Source apportionment of total suspended particulate matter in coarse and fine size ranges over Delhi. Aerosol and Air Quality Research, 8(2), 188–200.
Takahashi, K., Minoura, H., & Sakamoto, K. (2008). Chemical composition of atmospheric aerosols in the general environment and around a trunk road in the Tokyo metropolitan area. Atmospheric Environment, 42, 113–125.
Takegawa, N., Miyazaki, Y., Kondo, Y., Komazaki, Y., Miyakawa, T., & Jimenez, J. L. (2005). Characterization of an aerodyne aerosol mass spectrometer (AMS): Intercomparison with other aerosol instruments. Aerosol Science and Technology, 39, 760–770.
Torfs, K., & Van Grieken, R. (1997). Chemical relations between atmospheric aerosols, deposition and stone decay layers on historic buildings at the Mediterranean coast. Atmospheric Environment, 31, 2179–2192.
Turpin, B. J., & Lim, H.-J. (2001). Species contributions to PM2.5 mass concentrations: Revising common assumptions for estimating organic mass. Aerosol Science and Technology, 35, 602–610.
Var, F., Narita, Y., & Tanaka, S. (2000). The concentration, trend and seasonal variation of metals in the atmosphere in 16 Japanese cities shown by the results of National Air Surveillances Network (NASN) from 1974 to 1996. Atmospheric Environment, 34, 2755–2770.
Wang, H., & Shooter, D. (2001). Water soluble ions of atmospheric aerosols in three New Zealand cities: seasonal changes and sources. Atmospheric Environment, 35, 6031–6040.
Wang, X., Sato, T., & Xing, B. (2006). Size distribution and anthropogenic sources apportionment of airborne trace metals in Kanazawa, Japan. Chemosphere, 65, 2440–2448.
Wang, X., Sato, T., Xing, B., Tamamura, S., & Tao, S. (2005). Source identification, size distribution and indicator screening of airborne trace metals in Kanazawa, Japan. Journal of Aerosol Science, 36, 197–210.
Wang, Y. F., Huang, K. L., Li, C. T., Mi, H. H., Luo, J. H., & Tsai, P. J. (2003). Emissions of fuel metals content from a diesel vehicle engine. Atmospheric Environment, 37, 4637–4643.
Watson, J. G. (2002). Visibility: Science and regulation. Journal of Air & Waste Management Association, 52, 628–713.
Wei, F., Teng, E., Wu, G., Hu, W., Wilson, W. E., Chapman, R. S., et al. (1999). Ambient concentrations and elemental compositions of PM10 and PM2.5 in four Chinese cities. Environmental Science & Technology, 33, 4188–4193.
Yamazaki, S., Nitta, H., Ono, M., Green, J., & Fukuhara, S. (2007). Intracerebral haemorrhage associated with hourly concentration of ambient particulate matter: Case-crossover analysis. Occupational & Environmental Medicine, 64, 17–24.
Yaroshevsky, A. A. (2006). Abundances of chemical elements in the Earth’s crust. Geochemical International, 44(1), 48–55.
Yorifuji, T., Yamamoto, E., Tsuda, T., & Kawakami, N. (2005). Health impact assessment of particulate matter in Tokyo, Japan. Archives of Environmental & Occupational Health, 60(4), 79–85.
Yue, W., Li, X., Liu, J., Li, Y., Zhang, G., & Li, Y. (2007). Source tracing of chromium-, manganese-, nickel-, and zince-containing particles (PM10) by micro-PIXE spectrum. Journal of Radioanalytical and Nuclear Chemistry, 274(1), 115–121.
Zhang, F. S., Yamasaki, S., & Nanzyo, M. (2002). Waste ashes for use in agricultural production: I. Liming effect, contents of plant nutrients and chemical characteristics of some metals. Science of the Total Environment, 284, 215–225.
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Khan, M.F., Shirasuna, Y., Hirano, K. et al. Urban and suburban aerosol in Yokohama, Japan: a comprehensive chemical characterization. Environ Monit Assess 171, 441–456 (2010). https://doi.org/10.1007/s10661-009-1290-1
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DOI: https://doi.org/10.1007/s10661-009-1290-1