Skip to main content
Log in

Urban and suburban aerosol in Yokohama, Japan: a comprehensive chemical characterization

  • Published:
Environmental Monitoring and Assessment Aims and scope Submit manuscript

Abstract

This article analyses elemental composition of suspended particulate matter (SPM) samples collected monthly from 1999 to 2005 at two locations in Yokohama, Japan. Microwave digestion and inductively coupled plasma mass spectroscopy was employed to measure Mg, Al, Ca, V, Cr, Mn, Ni, Cu, Zn, Ga, As, Se, Rb, Sr, Ag, Cd, Cs, Ba, Pb, and Bi. Water-soluble ions (Na + , NH4  + , K + , Ca2 + , Cl − , NO3  − , and SO4 2 − ) and carbonaceous mass (elemental and organic carbon) were detected using ion chromatograph and CHN analyzer, respectively. The results indicate that the composition of SPM on one of the sites is determined by automobile emissions and on the other by industrial combustions. The impact of the emission regulations for automobiles in large Japanese cities, which were enacted during 2002 and 2003, on the SPM composition of the samples is also studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Báez, P. A., García, M. R., Torres, B. M., Del, C., Padilla, H. G., Belmont, R. D., et al. (2007). Origin of trace elements and inorganic ions in PM10 aerosols to the South of Mexico City. Atmospheric Research, 85(1), 52–63.

    Article  CAS  Google Scholar 

  • Bem, H., Gallorini, M., Rizzio, E., & Krzemińska, M. (2003). Comparative studies on the concentrations of some elements in urban air particulate matter in Lodz City of Poland and in Milan, Italy. Environmental International, 29, 423–428.

    Article  CAS  Google Scholar 

  • Birmili, W., Allen, A. G., Bary, F., & Harrison, R. M. (2006). Trace metal concentrations and water solubility in size-fractionated atmospheric particles and influence of road traffic. Environmental Science and Technology, 40, 1144–1153.

    Article  CAS  Google Scholar 

  • Brunner, P. H., & Rechberger, H. (2004). Practical handbook of material flow analysis (pp. 287–288). Boca Raton: Lewis.

    Google Scholar 

  • Buzica, D., Gerboles, M., Borowiak, A., Trincherini, P., Passarella, R., & Pedroni, V. (2006). Comparison of voltammetry and inductively coupled plasma-mass spectrometry for the determination of heavy metals in PM10 airborne particulate matter. Atmospheric Environment, 40, 4703–4710.

    Article  CAS  Google Scholar 

  • Canepari, S., Cardarelli, E., Giuliano, A., & Pietrodangelo, A. (2006). Determination of metals, metalloids and non-volatile ions in airborne particulate matter by a new two-step sequential leaching procedure. Part A: Experimental design and optimization. Talanta, 69, 581–587.

    Article  CAS  Google Scholar 

  • De Miquel, E., Llamas, J. F., Chacón, E., Berg, T., Larssen, S., Royset, O., et al. (1997). Origin and patterns of distribution of trace element in street dust: Unleaded petrol and urban lead. Atmospheric Environment, 17, 2733–2740.

    Article  Google Scholar 

  • Dockery, D. W., Pope, C. A., Xu, X., Spengler, J. D., Ware, J. H., Fay, M. E., et al. (1993). An association between air pollution and mortality in six U.S. cities. The New England Journal of Medicine, 329, 1753–1759.

    Article  CAS  Google Scholar 

  • Fukuyama, T., & Fujiwara, H. (2008). Contribution of Asian dust to atmospheric deposition of radioactive cesium (137Cs). Science of the Total Environment, 405(1–3), 389–395.

    Article  CAS  Google Scholar 

  • Funasaka, K., Sakai, M., Shinya, M., Miyazaki, T., Kamiura, T., Kaneco, S., et al. (2003). Size distributions and characteristics of atmospheric inorganic particles by regional comparative study in Urban Osaka, Japan. Atmospheric Environment, 37, 4597–4605.

    Article  CAS  Google Scholar 

  • Garg, B., Cadle, S. H., Mulawa, P. A., Groblicki, P. J., Laroo, C., & Parr, G. A. (2000). Brake wear particulate matter emissions. Environmental Science and Technology, 21, 4463–4469.

    Article  CAS  Google Scholar 

  • Grossi, C. M., & Brimblecombe, P. (2002). The effect of atmospheric pollution on building materials. Journal of Physics IV France, 12, 10–197.

    Google Scholar 

  • Harrison, R. M., Jones, A. M., & Lawrence, R. G. (2003). A pragmatic mass closure model for airborne particulate matter at urban background and roadside locations. Atmospheric Environment, 37, 4927–4933.

    Article  CAS  Google Scholar 

  • Harrison, R. M., Smith, D. J. T., Pio, C. A., & Castro, L. M. (1996). Source apportionment of atmospheric polycyclic aromatic hydrocarbons collected from an urban location in Birmingham, UK. Environmental Science and Technology, 30(3), 825–832.

    Article  CAS  Google Scholar 

  • Japan Environmental Council (2003). Future policy for motor vehicle emission reduction (eighth report), February 22.

  • Kanai, Y., Ohta, A., Kamioka, H., Imai, N., Shimizu, H., Takahashi, Y., et al. (2005). Observation of mass concentration and particle size of atmospheric aerosol in East Asia and dry deposition in Tsukuba in combination with optical particle counter observation. Bulletin of the Geological Survey of Japan, 56(7–8), 273–301.

    Google Scholar 

  • Mar, T. F., Norris, G. A., Koenig, J. Q., & Larson, T. V. (2000). Association between air pollution and mortality in Phoenix, 1995–1997. Environmental Health Perspective, 108(4), 347–353.

    Article  CAS  Google Scholar 

  • Ministry of Land, Infrastructure and Transport, Japan (2005). Report of road traffic census in Yokohama.

  • Mori, I., Sun, Z., Ukachi, M., Nagano, K., Mcleod, C. W., Cox, A. G., et al. (2008). Development and certification of the new NIES CRM 28: Urban aerosols for the determination of multielements. Analytical & Bioanalytical Chemistry, 391, 1997–2003.

    Article  CAS  Google Scholar 

  • Murakami, Y., & Ono, M. (2006). Myocardial infarction deaths after high level exposure to particulate matter. Journal of Epidemiology and Community Health, 60, 262–266.

    Article  Google Scholar 

  • Okuda, T., Tenmoku, M., Kato, J., Junya, M., Sato, T., Yokochi, R., et al. (2006). Long-term observation of trace metal concentration in aerosols at a remote island, Rishiri, Japan by using inductively coupled plasma mass spectrometry equipped with laser ablation. Water, Air, & Soil Pollution, 174(1–4), 3–17.

    Article  CAS  Google Scholar 

  • Omori, T., Fujimoto, G., Yoshimura, I., Nitta, H., & Ono, M. (2003). Effects of particulate matter on daily mortality in 13 Japanese cities. Journal of Epidemiology, 13(6), 314–322.

    Google Scholar 

  • Oura, Y., Iguchi, H., Nagahata, T., Nakamatsu, H., Otoshi, T., & Ebihara, M. (2007). Elemental compositions of atmospheric particulates collected in Japan from 2002 to 2004. Journal of Radioanalytical and Nuclear Chemistry, 272(2), 381–385.

    Article  CAS  Google Scholar 

  • Pacyna, J. M. (1998). Source inventories for atmospheric trace metals. In R. M. Harrison, & R. E. van Grieken (Eds.), Atmospheric particles. IUPAC series on analytical and physical chemistry of environmental systems (Vol. 5, pp. 385–423). Chichester: Wiley.

    Google Scholar 

  • Perrino, C., Canepari, S., Cardarelli, E., Catrambone, M., & Sargolini, T. (2008). Inorganic constituents of urban air pollution in the Lazio region (Central Italy). Environmental Monitoring and Assessment, 136, 69–86.

    Article  CAS  Google Scholar 

  • Pope, C. A. 3rd, & Dockery, D. W. (2006). Health effects of fine particulate air pollution: Lines that connect. Journal of Air & Waste Management Association, 56, 709–742.

    CAS  Google Scholar 

  • Pope, C. A., Dockery, D. W., & Schwartz, J. (1995a). Review of epidemiological evidence of health effects of particulate air pollution. Inhalation Toxicology, 7, 1–18.

    Article  CAS  Google Scholar 

  • Pope, C. A. 3rd, Thun, M. J., Namboodiri, M. M., Dockery, D. W., Evans, J. S., Speizer, F. E., et al. (1995b). Particulate air pollution as a predictor of mortality in a prospective study of US adults. American Journal of Respiratory and Critical Care Medicine, 151, 669–674.

    Google Scholar 

  • Russell, L. M. (2003). Aerosol organic-mass-to-organic-carbon ratio measurements. Environmental Science & Technology, 37, 2982–2987.

    Article  CAS  Google Scholar 

  • Seinfeld, J., & Pandis, S. N. (2006). Atmospheric chemistry and physics: From air pollution to climate change. New York: Wiley.

    Google Scholar 

  • Slezakova, K., Pereira, M. C., Reis, M. A., & Alvim-Ferraz, M. C. (2007). Influence of traffic emissions on the composition of atmospheric particles of different sizes—part 1: Concentration and elemental characterization. Journal of Atmospheric Chemistry, 58, 55–68.

    Article  CAS  Google Scholar 

  • Smolders, E., & Degryse, F. (2002). Fate and effect of zinc from tyre debris in soil. Environmental Science & Technology, 36, 3706–3710.

    Article  CAS  Google Scholar 

  • Sörme, L., Bergbäck, B., & Lohm, U. (2001). Goods in the anthroposphere as a metal emissions source - a case study of Stockholm, Sweden. Water, Air, and Soil pollution: Focus, 1, 213–227.

    Article  Google Scholar 

  • Srivastava, A., Gupta, S., & Jain, V. K. (2008). Source apportionment of total suspended particulate matter in coarse and fine size ranges over Delhi. Aerosol and Air Quality Research, 8(2), 188–200.

    CAS  Google Scholar 

  • Takahashi, K., Minoura, H., & Sakamoto, K. (2008). Chemical composition of atmospheric aerosols in the general environment and around a trunk road in the Tokyo metropolitan area. Atmospheric Environment, 42, 113–125.

    Article  CAS  Google Scholar 

  • Takegawa, N., Miyazaki, Y., Kondo, Y., Komazaki, Y., Miyakawa, T., & Jimenez, J. L. (2005). Characterization of an aerodyne aerosol mass spectrometer (AMS): Intercomparison with other aerosol instruments. Aerosol Science and Technology, 39, 760–770.

    CAS  Google Scholar 

  • Torfs, K., & Van Grieken, R. (1997). Chemical relations between atmospheric aerosols, deposition and stone decay layers on historic buildings at the Mediterranean coast. Atmospheric Environment, 31, 2179–2192.

    Article  CAS  Google Scholar 

  • Turpin, B. J., & Lim, H.-J. (2001). Species contributions to PM2.5 mass concentrations: Revising common assumptions for estimating organic mass. Aerosol Science and Technology, 35, 602–610.

    Article  CAS  Google Scholar 

  • Var, F., Narita, Y., & Tanaka, S. (2000). The concentration, trend and seasonal variation of metals in the atmosphere in 16 Japanese cities shown by the results of National Air Surveillances Network (NASN) from 1974 to 1996. Atmospheric Environment, 34, 2755–2770.

    Article  CAS  Google Scholar 

  • Wang, H., & Shooter, D. (2001). Water soluble ions of atmospheric aerosols in three New Zealand cities: seasonal changes and sources. Atmospheric Environment, 35, 6031–6040.

    Article  CAS  Google Scholar 

  • Wang, X., Sato, T., & Xing, B. (2006). Size distribution and anthropogenic sources apportionment of airborne trace metals in Kanazawa, Japan. Chemosphere, 65, 2440–2448.

    Article  CAS  Google Scholar 

  • Wang, X., Sato, T., Xing, B., Tamamura, S., & Tao, S. (2005). Source identification, size distribution and indicator screening of airborne trace metals in Kanazawa, Japan. Journal of Aerosol Science, 36, 197–210.

    Article  CAS  Google Scholar 

  • Wang, Y. F., Huang, K. L., Li, C. T., Mi, H. H., Luo, J. H., & Tsai, P. J. (2003). Emissions of fuel metals content from a diesel vehicle engine. Atmospheric Environment, 37, 4637–4643.

    Article  CAS  Google Scholar 

  • Watson, J. G. (2002). Visibility: Science and regulation. Journal of Air & Waste Management Association, 52, 628–713.

    Google Scholar 

  • Wei, F., Teng, E., Wu, G., Hu, W., Wilson, W. E., Chapman, R. S., et al. (1999). Ambient concentrations and elemental compositions of PM10 and PM2.5 in four Chinese cities. Environmental Science & Technology, 33, 4188–4193.

    Article  CAS  Google Scholar 

  • Yamazaki, S., Nitta, H., Ono, M., Green, J., & Fukuhara, S. (2007). Intracerebral haemorrhage associated with hourly concentration of ambient particulate matter: Case-crossover analysis. Occupational & Environmental Medicine, 64, 17–24.

    Article  CAS  Google Scholar 

  • Yaroshevsky, A. A. (2006). Abundances of chemical elements in the Earth’s crust. Geochemical International, 44(1), 48–55.

    Article  Google Scholar 

  • Yorifuji, T., Yamamoto, E., Tsuda, T., & Kawakami, N. (2005). Health impact assessment of particulate matter in Tokyo, Japan. Archives of Environmental & Occupational Health, 60(4), 79–85.

    Article  Google Scholar 

  • Yue, W., Li, X., Liu, J., Li, Y., Zhang, G., & Li, Y. (2007). Source tracing of chromium-, manganese-, nickel-, and zince-containing particles (PM10) by micro-PIXE spectrum. Journal of Radioanalytical and Nuclear Chemistry, 274(1), 115–121.

    Article  CAS  Google Scholar 

  • Zhang, F. S., Yamasaki, S., & Nanzyo, M. (2002). Waste ashes for use in agricultural production: I. Liming effect, contents of plant nutrients and chemical characteristics of some metals. Science of the Total Environment, 284, 215–225.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Md. Firoz Khan.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Khan, M.F., Shirasuna, Y., Hirano, K. et al. Urban and suburban aerosol in Yokohama, Japan: a comprehensive chemical characterization. Environ Monit Assess 171, 441–456 (2010). https://doi.org/10.1007/s10661-009-1290-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10661-009-1290-1

Keywords

Navigation