Abstract
A sensitive adsorptive stripping voltammetric method for the determination of simeton with universal buffer solution has been described. The method was based on the adsorption accumulation of simeton at a hanging mercury drop electrode. The overall reduction process is under controlled diffusion. The adsorptive peak was observed at −0.8 V vs SCE in acidic solution 2 < pH < 6. The peak response was characterized with respect to pH, accumulation potential, time, and scan rate. The calibration plot was found to be linear from 1.13 × 10 − 5 to 3.5 × 10 − 8 M with a limit of detection of 2.0 × 10 − 8 M. Finally, the method has been applied for the determination of simeton in its formulations and vegetable samples.
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Benfield, C. A., & Chilwell, E. D. (1964). The determination sum triazine herbicides by gas–liquid chromatography with particular reference to atraton in soil. Analyst, 89, 475.
Hauson, D. (1998).Chemical & Engineering News, 4, 38.
Henkel, H. G. (1964). Bundesanstalt land—Forestwirtschaft (Vol. 18, pp. 252). Berlin: Dahlem Chimia (Aaran).
Hileman, B. (1998). Trace measurement of dithiocarbonate based pesticide by adsorptive stripping voltammetry. Chemical & Engineering News, 18, 24.
Kaune, A., Brueggemann, R. J., Sharma, M., & Kettrup, A. (1998). Soil adsorption coefficients of S-triazines estimated with a new gradient HPLC method. Journal of Agricultural and Food Chemistry, 46, 335.
Lee, H. B., & Stokker, Y. D. (1986). Analysis of eleven triazines in natural water. Analytical Chemists, 69, 568.
Marion Gfrerer, Martens, D., Gawlik, M., Zhang, A., Xie Quan, C., Chen, J., et al. (2002). Triazines in the aquatic systems of the eastern Chinese river Liao-He and Yangtse. Chemosphere, 47, 455.
Matisova, E., Krupcik, J., Liska, O., & Szentivanyi, N. (1979). Qualitative analysis of multi-component S-triazine herbicides by gas liquid chromatography. Journal of Chromatography, 169, 261.
Summan, Li, & Korea, N. (1974). Punsok Hwahak, 12, 139.
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Sreedhar, N.Y., Nayak, M.S., Shashi Kumar, K.N. et al. Differential pulse adsorptive stripping voltammetric determination of simeton in its formulations and vegetables. Environ Monit Assess 170, 59–63 (2010). https://doi.org/10.1007/s10661-009-1214-0
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DOI: https://doi.org/10.1007/s10661-009-1214-0