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Desorption Kinetics of Benzene in a Sandy Soil in the Presence of Powdered Activated Carbon

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Abstract

Desorption kinetics of benzene was investigated with a modified biphasic desorption model in a sandy soil with five different powdered activated carbon (PAC) contents (0, 1, 2, 5, 10% w/w) as sorbents. Sorption experiments followed by series dilution desorption were conducted for each sorbent. Desorption of benzene was successively performed at two stages using deionized water and hexane. Modeling was performed on both desorption isotherm and desorption rate for water-induced desorption to elucidate the presence of sorption–desorption hysteresis and biphasic desorption and if present to quantify the desorption-resistant fraction (q irr) and labile fraction (F) of desorption site responsible for rapid process. Desorption isotherms revealed that sorption–desorption exhibited a severe hysteresis with a significant fraction of benzene being irreversibly adsorbed onto both pure sand and PAC, and that desorption-resistant fraction (q irr) increased with PAC content. Desorption kinetic modeling showed that desorption of benzene was biphasic with much higher (4–40 times) rate constant for rapid process (k 1) than that for slow process (k 2), and that the difference in the rate constant increased with PAC content. The labile fraction (F) of desorption site showed a decreasing tendency with PAC. The experimental results would provide valuable information on remediation methods for soils and groundwater contaminated with BTEX.

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References

  • Abu, A., & Smith, S. (2005). Assessing sequestration of selected polycyclic aromatic hydrocarbons by use of adsorption modeling and temperature-programmed desorption. Environmental Science & Technology, 39, 7585–7591.

    Article  CAS  Google Scholar 

  • Abu-Salah, K., Shelef, G., Levanon, D., Armon, R., & Dosoretz, C. G. (1996). Microbial degradation of aromatic and poluaromatic toxic compounds adsorbed on powdered activated carbon. Journal of Biotechnology, 51, 265–272.

    Article  CAS  Google Scholar 

  • Alexander, M. (1995). How toxic are toxic chemicals in soil?. Environmental Science & Technology, 29, 2713–2717.

    Article  CAS  Google Scholar 

  • Alexander, M. (2000). Aging, bioavailability, and overestimation of risk from environmental pollutants. Environmental Science & Technology, 34, 4259–4265.

    Article  CAS  Google Scholar 

  • Baek, D.-S., Kim, S.-B., & Kim, D.-J. (2003). Irreversible sorption of benzene in sandy aquifer materials. Hydrological Processes, 17, 1239–1251.

    Article  Google Scholar 

  • Ball, W. P., & Roberts, P. V. (1991). Long terms of sorption halogenated organic chemicals by aquifer material, 2: Intraparticle diffusion. Environmental Science & Technology, 25, 1237–1249.

    Article  CAS  Google Scholar 

  • Berg, M. S., Loehr, R. C., & Webster, M. W. (1998). Release of petroleum hydrocarbons from bioremediated soils. Journal of Soil Contamination, 7, 675–695.

    Article  CAS  Google Scholar 

  • Brusseau, M. L., Jessup, R. E., & Rao, P. S. C. (1990). Sorption kinetics of organic chemicals: Evaluation of gas-purge and miscible-displacement techniques. Environmental Science & Technology, 24, 727–735.

    Article  CAS  Google Scholar 

  • Carroll, K. M., Harkness, M. R., Bracco, A. A., & Balcarcel, R. R. (1994). Application of a permeant/polymer diffusional model to the desorption of polychlorinated biphenyls from Hudson River sediments. Environmental Science & Technology, 28, 253–258.

    Article  CAS  Google Scholar 

  • Chen, Y. X., Chen, H. L., Xu, Y. T., & Shen, M. W. (2004). Irreversible sorption of pentachlorophenol to sediments: Experimental observations. Environment International, 30, 31–37.

    Article  CAS  Google Scholar 

  • Connaughton, D. F., Stedlinger, J. R., Lion, L. W., & Shuler, M. L. (1993). Description of time-varying desorption kinetics: Release of naphthalene from contaminated soils. Environmental Science & Technology, 27, 2397–2403.

    Article  CAS  Google Scholar 

  • Cornelissen, G., Van Noort, P. C., & Govers, H. A. J. (1997). Desorption kinetics of chlorobenzenes, polycyclic aromatic hydrocarbons, and polychlorinated biphenyls: Sediment extraction with tenax and effects of contact time and solute hydrophobicity. Environmental Toxicology and Chemistry, 16, 1351–1357.

    Article  CAS  Google Scholar 

  • Fu, G., Kan, A. T., & Tomson, M. B. (1994). Adsorption/desorption hysteresis of polycyclic aromatic hydrocarbons in surface sediment. Environmental Toxicology and Chemistry, 13, 1559–1567.

    CAS  Google Scholar 

  • Gess, P., & Pavlostathis, S. G. (1997). Desorption of chlorinated organic compounds from a contaminated estuarine sediment. Environmental Toxicology and Chemistry, 13, 1598–1605.

    Article  Google Scholar 

  • Kan, A. T., Fu, G., Hunter, M. A., & Tomson, M. B. (1997). Irreversible adsorption of naphthalene and tetrachlorobiphenyl to Lula and surrogate sediment. Environmental Science & Technology, 31, 2176–2181.

    Article  CAS  Google Scholar 

  • Kan, A. T., Fu, G., & Tomson, M. B. (1994). Adsorption/desorption hysteresis in organic pollutant and soil/sediment interaction. Environmental Science & Technology, 28, 859–867.

    Article  CAS  Google Scholar 

  • Kim, D.-J., Choi, N., & Kim, S.-B. (2004). Quantification of irreversible benzene sorption in sandy materials. Hydrological Processes, 18, 3229–3234.

    Article  Google Scholar 

  • Kim, S.-B., Hwang, I., Kim, D.-J., Lee, S. J., & Jury, W. A. (2003). Effect of sorption on benzene biodegradation in sandy soil. Environmental Toxicology and Chemistry, 22, 2306–2311.

    Article  CAS  Google Scholar 

  • Kraaij, R., Ciarelli, S., Tolls, J., Kater, B. J., & Belfroid, A. (2001). Bioavaliability of lab-contaminated and native polycyclic aromatic hydrocarbons to the amphipod Corophium volutator relates to chemical desorption. Environmental Toxicology and Chemistry, 20, 1716–1724.

    Article  CAS  Google Scholar 

  • Lee, S. J., Kommalapati, R. R., Valsaraj, K. T., Pardue, J. H., & Constant, W. D. (2002a). Rate-limited desorption of volatile organic compounds from soils and implications for the remediation of a Louisiana superfund site. Environmental Monitoring and Assessment, 75, 87–105.

    Article  CAS  Google Scholar 

  • Lee, S. J., Moe, W. M., Valsaraj, K. T., & Pardue, J. H. (2002b). Effect of sorption and desorption resistance on aerobic trichloroethylene biodegradation in soils. Environmental Toxicology and Chemistry, 21, 1609–1617.

    Article  CAS  Google Scholar 

  • Lueking, A. D., Huang, W., Soderstrom-Schwarz, S., Kim, M., & Weber, W. J. Jr. (2000). Relationship of soil organic matter characteristics to organic contaminant sequestration and bioavailability. Journal of Environmental Quality, 29, 317–323.

    Article  CAS  Google Scholar 

  • McGroddy, S. E., & Farrington, J. W. (1995). Sediment porewater partitioning of polycyclic aromatic hydrocarbons in three cores from Boston Harbor, Massachusetts. Environmental Science & Technology, 29, 1542–1550.

    Article  CAS  Google Scholar 

  • Miller, C. T., & Pedit, J. A. (1992). Use of a reactive surface-diffusion model to describe apparent sorption–desorption hysteresis and abiotic degradation of lindane in a subsurface material. Environmental Science & Technology, 26, 1417–1427.

    Article  CAS  Google Scholar 

  • Nam, K., Chung, N., & Alexander, M. (1998). Relationship between organic matter content of soil and the sequestration of phenanthrene. Environmental Science & Technology, 32, 3785–3788.

    Article  CAS  Google Scholar 

  • Northcott, G. L., & Jones, K. C. (2001). Partitioning, extractability, and formation of nonextractable PAH residues in soil. 1. Compound differences in aging and sequestration. Environmental Science & Technology, 35, 1103–1110.

    Article  CAS  Google Scholar 

  • Park, J. H., Zhao, X., & Voice, T. C. (2001). Biodegradation of non-desorbable naphthalene in soils. Environmental Science & Technology, 35, 2734–2740.

    Article  CAS  Google Scholar 

  • Pavslostathis, S. G., & Jaglal, K. (1991). Desorption behavior of trichloroethylene in contaminated soil. Environmental Science & Technology, 25, 274–279.

    Article  Google Scholar 

  • Pavslostathis, S. G., & Mathavan, G. N. (1992). Desorption kinetics of selected volatile organic compounds from field contaminated soils. Environmental Science & Technology, 26, 532–528.

    Google Scholar 

  • Pignatello, J. J. (1990). Slowly reversible sorption of aliphatic halocarbons in soils. 1. Formation of residual fractions. Environmental Toxicology and Chemistry, 9, 1107–1115.

    CAS  Google Scholar 

  • Pignatello, J. J., Ferrandino, F. J., & Huang, L. Q. (1993). Elution of aged and freshly added herbicides from a soil. Environmental Science & Technology, 27, 1563–1571.

    Article  CAS  Google Scholar 

  • Pignatello, J. J., & Xing, B. (1996). Mechanisms of slow sorption of organic chemicals to natural particles. Environmental Science & Technology, 30, 1–11.

    Article  CAS  Google Scholar 

  • Opdyke, D. R., & Loehr, R. C. (1999). Determination of chemical release rates from soils: Experimental design. Environmental Science & Technology, 33, 1193–1199.

    Article  CAS  Google Scholar 

  • Steinberg, S. M., Pignatello, J. J., & Sawhney, B. L. (1987). Persistence of 1, 2-dibromoethane in soils: Entrapment in intraparticle micropores. Environmental Science & Technology, 21, 1201–1208.

    Article  CAS  Google Scholar 

  • ten Hulscher, Th. E. M., Vrind, B. A., ven den Heuvel, H., van der Velde, L. E., van Noort, P. C. M., Beurskens, J. E. M., & Govers, H. A. J. (1999). Triphasic desorption of highly resistant chlorobenzenes, polychlorinated biphenyls, and polycyclic aromatic hydrocarbons in field contaminated sediment. Environmental Science & Technology, 33, 126–132.

    Article  Google Scholar 

  • Williamson, D. G., Loehr, R. C., & Kimura, Y. (1998). Release of chemicals from contaminated soils. Journal of Soil Contamination, 7, 543–558.

    Article  CAS  Google Scholar 

  • White, J. C., Hunter, M., Nam, K., Pignatello, J., & Alexander, M. (1999). Correlation between biological and physical availabilities of phenanthrene in soils and soil humin in aging experiments. Environmental Toxicology and Chemistry, 18, 1720–1727.

    Article  CAS  Google Scholar 

  • Zhang, Y., Wu, R. S. S., Hong, H. S., Poon, K. F., & Lam, M. H. W. (2000). Field study on desorption rates of polynuclear aromatic hydrocarbons from contaminated marine sediment. Environmental Toxicology and Chemistry, 19, 2431–2435.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Earth and Environmental Sciences, Korea University, Seoul, 136-701, Korea

    J.-W. Choi & D.-J Kim

  2. Environmental Remediation Engineering Laboratory, Program in Rural System Engineering, Seoul National University, Seoul, 151-921, Korea

    S.-B. Kim

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  1. J.-W. Choi
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  2. S.-B. Kim
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  3. D.-J Kim
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Correspondence to D.-J Kim.

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Choi, JW., Kim, SB. & Kim, DJ. Desorption Kinetics of Benzene in a Sandy Soil in the Presence of Powdered Activated Carbon. Environ Monit Assess 125, 313–323 (2007). https://doi.org/10.1007/s10661-006-9524-y

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