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Violation of Ericksen Inequalities in Lyotropic Chromonic Liquid Crystals

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Abstract

By analyzing elastic theory for nematic liquid crystals, we distinguish three regimes of elastic constants. In one regime, the Ericksen inequalities are satisfied, and the ground state of the director field is uniform. In a second regime, certain necessary inequalities are violated, and the free energy is thermodynamically unstable. Between those possibilities, there is an intermediate regime, where the Ericksen inequalities are violated but the system is still stable. Remarkably, lyotropic chromonic liquid crystals are in the intermediate regime. We investigate the nonuniform structure of the director field in that regime, show that it depends sensitively on system geometry, and discuss the implications for lyotropic chromonic liquid crystals.

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Acknowledgements

This work was supported by National Science Foundation Grant DMR-1409658.

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  1. Department of Physics, Advanced Materials and Liquid Crystal Institute, Kent State University, Kent, Ohio, 44242, USA

    Cheng Long & Jonathan V. Selinger

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  1. Cheng Long
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  2. Jonathan V. Selinger
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Correspondence to Jonathan V. Selinger.

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Long, C., Selinger, J.V. Violation of Ericksen Inequalities in Lyotropic Chromonic Liquid Crystals. J Elast 153, 599–612 (2023). https://doi.org/10.1007/s10659-022-09899-z

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