Abstract
The pollution of heavy metals in soil caused by exposed coal gangue and its prevention and control has become a hot issue restricting the green mining of coal in China. Nemerow integrated pollution index (NIPI), potential ecological risk index (RI) and human health risk assessment model were used to evaluate the pollution and risk of heavy metals (Cu, Cr, As, Pb) in the soil around the typical coal gangue hill in Fengfeng mining area of China. The results show that: firstly, the accumulation of coal gangue leads to the enrichment of four heavy metals in the surrounding shallow soil, and NIPI and RI were 1.0–4.4 and 21.63–91.28, respectively. The comprehensive pollution level of heavy metals in soil reached the warning line and above, and the potential ecological risk level reached slightly and above. When the horizontal distance exceeded 300 m, 300 m and 200 m, respectively, the influence of coal gangue hill on the heavy metal content in shallow soil, the comprehensive pollution level of heavy metals and the potential ecological risk level basically disappeared. In addition, based on the potential ecological risk assessment results and main risk factors, the ecological risk configuration of the study area was divided into five categories: “strong ecological risk + As,” “intermediate ecological risk + As + Cu,” “intermediate ecological risk + As + Cu or Pb,” “minor ecological risk + As + Cu” and “minor ecological risk + As + Cu or Pb.” The hazard index (HI) and total carcinogenic risk (TCR) of shallow soil polluted by heavy metals in the study area were 0.24–1.07 and 0.41 × 10−4–1.78 × 10−4, respectively, which posed non-carcinogenic and carcinogenic risks to children, but the risks were controllable. This study will help to take strategic measures to accurately control and repair the heavy metal pollution in the soil around the coal gangue hill and provide a scientific basis for solving the safe use of agricultural land and realizing the construction of ecological civilization.
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References
Antoniadis, V., Shaheen, S. M., Levizou, E., Shahid, M., Niazi, N. K., Vithanage, M., & Rinklebe, J. (2019). A critical prospective analysis of the potential toxicity of trace element regulation limits in soils worldwide: Are they protective concerning health risk assessment?–A review. Environment International, 127, 819–847. https://doi.org/10.1016/j.envint.2019.03.039
Bhuiyan, M. A., Parvez, L., Islam, M. A., Dampare, S. B., & Suzuki, S. (2010). Heavy metal pollution of coal mine-affected agricultural soils in the northern part of Bangladesh. Journal of Hazardous Materials, 173(1–3), 384–392. https://doi.org/10.1016/j.jhazmat.2009.08.085
Chen, S., Li, J., & Deng, H. (2014). The relationship between physical and chemical properties of soil and heavy metal content in Fujian coastal farmland. Hubei Agricultural Sciences, 53(13), 3025–3029. https://doi.org/10.14088/j.cnki.issn0439-8114.2014.13.076
Chen, Y., Jiang, X., Wang, Y., & Zhuang, D. (2018). Assessment of ecological environment and human health of heavy metals in mining area based on GIS. Acta Scientiae Circumstantiae, 38(04), 1642–1652. https://doi.org/10.13671/j.hjkxxb.2017.0365
Chen, B., Zhu, Y., & Zhai, W. (2021a). Assessment of heavy metal and human health risk in surface soils in a decommissioned rare earth recycling plant. Nonferrous Metals Extractive Metallurgy, 10, 133–138. https://doi.org/10.3969/j.issn.1007-7545.2021.10.018
Chen, F., Yu, H., Bian, Z., & Yin, D. (2021b). How to handle the crisis of coal industry in China under the vision of carbon neutrality. Journal of China Coal Society, 46(06), 1808–1820. https://doi.org/10.13225/j.cnki.jccs.2021.0368
Chilikwazi, B., Onyari, J. M., & Wanjohi, J. M. (2022). Determination of heavy metals concentrations in coal and coal gangue obtained from a mine, in Zambia. International Journal of Environmental Science and Technology. https://doi.org/10.1007/s13762-022-04107-w
Cong, X., Lei, X., Fu, L., Shang, S., Ding, J., & Bi, R. (2017a). Pollution characteristics and ecological risk assessment of heavy metals in soils around the gangue heap of HaiZhou Coal Mine, Chaina. Earth and Environment, 45(03), 329–335. https://doi.org/10.14050/j.cnki.1672-9250.2017.03.011
Cong, X., Zhang, R., Hu, F., Zheng, L., Li, Y., & Wang, S. (2017b). Distribution characteristics and influence factors of heavy metals in soils around coal waste piles nearby mining city. Ecology and Environment Sciences, 26(03), 479–485. https://doi.org/10.16258/j.cnki.1674-5906.2017.03.017
Ding, Q., Cheng, G., Wang, Y., & Zhuang, D. (2017). Effects of natural factors on the spatial distribution of heavy metals in soils surrounding mining regions. Science of the Total Environment, 578, 577–585. https://doi.org/10.1016/j.scitotenv.2016.11.001
Fan, J., Meng, Z., Li, Y., Hun, L., & Liu, H. (2011). Discussion on heavy metal potential ecological risk of the coal gangue dump of one mine. Industrial Safety and Environmental Protection, 37(06), 11–12+15. https://doi.org/10.3969/j.issn.1001-425X.2011.06.005
Gopinathan, P., Jha, M., Singh, A. K., Mahato, A., Subramani, T., Singh, P. K., & Singh, V. (2022a). Geochemical characteristics, origin and forms of sulphur distribution in the Talcher coalfield. India. Fuel, 316, 123376. https://doi.org/10.1016/j.fuel.2022.123376
Gopinathan, P., Santosh, M. S., Dileepkumar, V. G., Subramani, T., Reddy, R., Masto, R. E., & Maity, S. (2022b). Geochemical, mineralogical and toxicological characteristics of coal fly ash and its environmental impacts. Chemosphere, 307, 135710. https://doi.org/10.1016/j.chemosphere.2022.135710
Gopinathan, P., Singh, A. K., Singh, P. K., & Jha, M. (2022c). Sulphur in Jharia and Raniganj coalfields: Chemical fractionation and its environmental implications. Environmental Research, 204, 112382. https://doi.org/10.1016/j.envres.2021.112382
Guo, W., Dai, J., & Wang, R. (2012). Progress in the effect of dissolved organic matter on adsorption of heavy metals by soil. Chinese Journal of Soil Science, 43(03), 761–768. https://doi.org/10.19336/j.cnki.trtb.2012.03.043
Hakanson, L. (1980). An ecological risk index for aquatic pollution control.a sedimentological approach. Water Research, 14(8), 975–1001. https://doi.org/10.1016/0043-1354(80)90143-8
Han, Y., Li, Q., & Liu, N. (2020). Heavy metal accumulation of 13 native plant species around a coal gangue dump and their potentials for phytoremediation. Nature Environment and Pollution Technology, 19(1), 191–199.
Hou, J., Yu, H., Mu, S., & Bian, Z. (2020). Spatial-temporal characteristics of land degradation and its influencing factors in coal mine in Western China. Coal Science and Technology, 48(11), 206–216. https://doi.org/10.13199/j.cnki.cst.2020.11.026
Huang, Y., Chen, Q., Deng, M., Japenga, J., Li, T., Yang, X., & He, Z. (2018). Heavy metal pollution and health risk assessment of agricultural soils in a typical peri-urban area in southeast China. Journal of Environmental Management, 207(1), 159–168. https://doi.org/10.1016/j.jenvman.2017.10.072
Kawatra, B. L., & Bakhetia, P. (2008). Consumption of heavy metal and minerals by adult women through food in sewage and tube-well irrigated area around Ludhiana city (Punjab, India). Journal of Human Ecology, 23(4), 351–354. https://doi.org/10.1080/09709274.2008.11906089
Kumar, V., Pandita, S., & Setia, R. (2022). A meta-analysis of potential ecological risk evaluation of heavy metals in sediments and soils. Gondwana Research, 103, 487–501. https://doi.org/10.1016/j.gr.2021.10.028
Kumar, V., Pandita, S., Singh, S., & Sharma, A. (2022a). An integration of health risk indices and statistical techniques to appraise the associated human risks and source apportionment of potentially toxic elements in roadside soils. Arabian Journal of Geosciences. https://doi.org/10.1007/s12517-022-10547-y
Kumar, V., Sharma, A., & Setia, R. (2022b). Appraisal of Metal (loids) in the Ecosystem: Elsevier.
Li, J. (2004). Study on temporal and spatial characteristics of heavy metal pollutionin coal gangue piles in mining area. Multipurpose Utilization of Mineral Resources, 32(5), 15–17. https://doi.org/10.3969/j.issn.1000-6532.2022.02.032
Li, X., & Shen, X. (2006). Experimental study on the distribution characteristics of the saltation particle of aeolian sediment in bare tillage. Transactions of the Chinese Society of Agricultural Engineering, 22(5), 74–77. https://doi.org/10.3321/j.issn:1002-6819.2006.05.017
Li, D., Fang, Y., Ren, Y., Hu, B., & Matthien, F. (2004). Analysis of heavy metal pollution in vicinity soil of coal gangue dump–Taking Zhongmacun Mine of Jiaozuo. Coal Geology & Exploration, 32(5), 15–17. https://doi.org/10.3969/j.issn.1001-1986.2004.05.006
Li, Y., Liu, J., Zhu, J., Fu, Q., & Hu, H. (2012b). Effect of dissolved organic on competitive adsorption of Cd and Zn by an alkaline soil. Guangdong Agricultural Sciences, 39(21), 79–81. https://doi.org/10.3969/j.issn.1004-874X.2012.21.024
Li, J., Hao, Y., Sun, J., Zhou, Y., & Yi, F. (2021). Evaluation of ecological environment’s patio-temporal variation in urban mine based on Rsei. Urban Development Studies, 28(01), 17–22. https://doi.org/10.3969/j.issn.1006-3862.2021.01.014
Li, Q., & Huang, S. (2015). On particle size distribution characteristics of heavy metal in weathered coal gangue from Suzhou mine area. Journal of Fuyang Normal University Natural Science, 32(02), 35–40. https://doi.org/10.3969/j.issn.1004-4329.2015.02.008
Li, S., Zhang, Y., Fan, Q., Yu, N., & Liu, C. (2012a). Effects of irrigation mode on soil acidification in protected field. Acta Pedologica Sinica, 49(05), 909–915. https://doi.org/10.11766/trxb201111250467
Lian, M., Wang, J., Sun, L., Xu, Z., Tang, J., Yan, J., & Zeng, X. (2019). Profiles and potential health risks of heavy metals in soil and crops from the watershed of Xi River in Northeast China. Ecotoxicology and Environmental Safety, 169, 442–448. https://doi.org/10.1016/j.ecoenv.2018.11.046
Liu, C., Qin, Y., & Zhao, X. (2020). Long-term effect of fertilization on accumulation and availability of heavy metal in a calcareous paddy soil. Journal of Agro-Environment Science, 39(7), 1494–1502. https://doi.org/10.11654/jaes.2020-0012
Liu, H., Qu, M., Chen, J., Guang, X., Zhang, J., Liu, M., & Huang, B. (2022). Heavy metal accumulation in the surrounding areas affected by mining in China: Spatial distribution patterns, risk assessment, and influencing factors. Science of the Total Environment, 825, 154004. https://doi.org/10.1016/j.scitotenv.2022.154004
Liu, M., & Hao, C. (2021). Evaluation and quantitative source analysis of heavy metal pollution Fengfeng Mine drainage irrigation area. Science Technology and Engineering, 21(17), 7377–7384. https://doi.org/10.3969/j.issn.1671-1815.2021.17.057
Liu, W. (2021). Scale control method of gangue hill in Fengfeng Mining area. Clean Coal Technology, 27(S2), 363–366. https://doi.org/10.1322/j.issn.1006-6772.21032901
Ma, J., Han, C., & Jiang, Y. (2020). Some problems in the application of potential ecological risk index. Geographical Research, 39(06), 1233–1241. https://doi.org/10.1182/dlyj020190632
Masto, R. E., Ram, L. C., George, J., Selvi, V. A., Sinha, A. K., Verma, S. K., & Prabal, P. (2011). Impacts of opencast coal mine and mine fire on the trace elements’ content of the surrounding soil vis-a-vis human health risk. Toxicological & Environmental Chemistry, 93(2), 223–237. https://doi.org/10.1080/02772248.2010.510922
Mehmood, K., Ahmad, H. R., Abbas, R., & Murtaza, G. (2019). Heavy metals in urban and peri-urban soils of a heavily-populated and industrialized city: Assessment of ecological risks and human health repercussions. Human and Ecological Risk Assessment: An International Journal, 26(6), 1705–1722. https://doi.org/10.1080/10807039.2019.1601004
Okedeyi, O. O., Dube, S., Awofolu, O. R., & Nindi, M. M. (2014). Assessing the enrichment of heavy metals in surface soil and plant (Digitaria eriantha) around coal-fired power plants in South Africa. Environmental Science and Pollution Research, 21(6), 4686–4696. https://doi.org/10.1007/s11356-013-2432-0
Pandey, B., Agrawal, M., & Singh, S. (2015). Ecological risk assessment of soil contamination by trace elements around coal mining area. Journal of Soils and Sediments, 16(1), 159–168. https://doi.org/10.1007/s11368-015-1173-8
Qu, C., Sun, K., Wang, S., Huang, L., & Bi, J. (2012). Monte carlo simulation-based health risk assessment of heavy metal soil pollution: A case study in the Qixia mining area, China. Human and Ecological Risk Assessment: An International Journal, 18(4), 733–750. https://doi.org/10.1080/10807039.2012.688697
Santosh, M. S., Purushotham, S., Gopinathan, P., Guna, V., Dileepkumar, V. G., Kumar, M., & Reddy, N. (2023). Natural sub-bituminous coal as filler enhances mechanical, insulation and flame retardant properties of coir-polypropylene bio-composites. Environmental Geochemistry and Health. https://doi.org/10.1007/s10653-023-01489-9
Song, T., Su, X., He, J., Liang, Y., & Zhou, T. (2017). Source apportionment and health risk assessment of heavy metals in agricultural soils in Xinglonggang, Northeastern China. Human and Ecological Risk Assessment: An International Journal, 24(2), 509–521. https://doi.org/10.1080/10807039.2017.1392232
Sun, T., Song, S., Chang, Q., Wang, C., Zhang, Y., Peng, R., & Wang, Y. (2022). Spatial variation characteristics of soil heavy metal speciation and bioavailability in coal gangue accumulation area-Taking Fengfeng Mining area as an example. Coal Geology & Exploration, 50(10), 85–95. https://doi.org/10.12363/issn.1001-1986.22.03.0159
Vega, F. A., Covelo, E. F., & Andrade, M. L. (2006). Competitive sorption and desorption of heavy metals in mine soils: Influence of mine soil characteristics. Journal of Colloid and Interface Science, 298(2), 582–592. https://doi.org/10.1016/j.jcis.2006.01.012
Verma, F., Singh, S., Singh, J., Dhaliwal, S. S., Parkash, C., Kumar, V., & Kumar, R. (2021b). Assessment of heavy metal contamination and its effect on earthworms in different types of soils. International Journal of Environmental Science and Technology, 19(5), 4337–4350. https://doi.org/10.1007/s13762-021-03297-z
Verma, F., Singh, S., Dhaliwal, S. S., Kumar, V., Kumar, R., Singh, J., & Parkash, C. (2021a). Appraisal of pollution of potentially toxic elements in different soils collected around the industrial area. Heliyon, 7(10), e08122. https://doi.org/10.1016/j.heliyon.2021.e08122
Wang, G., Deng, W., & Yao, R. (2008). Influence of coal gangue pile on the concentration of heavy metals in farming soil. Journal of xi’an University of Science and Technology, 28(03), 489–492. https://doi.org/10.3969/j.issn.1672-9315.2008.03.019
Wang, L. F., Bai, Y. X., & Gai, S. N. (2011). Single-factor and nemerow multi-factor index to assess heavy metals contamination in soils on railway side of harbin-suifenhe railway in Northeastern China. Applied Mechanics and Materials, 1366(71–78), 3033–3036. https://doi.org/10.4028/www.scientific.net/AMM.71-78.3033
Wang, Y., Li, F., Wang, X., Yang, Z., Han, K., & Ruan, X. (2019). Spatial distribution and risk assessment of heavy metal contamination in surface farmland soil around a lead and zinc smelter. Environmental Science and Pollution Research, 40(01), 437–444. https://doi.org/10.13227/j.hjkx.201803031
Wang, X., Li, J., Meng, X., Li, X., & Liu, F. (2020). Effects of exposure to lead, manganese and cadmium on growth and neurocognitive function in children. Chinese Journal of Child Health Care, 28(11), 1193–1196. https://doi.org/10.11852/zgetbjzz2020-0514
Wei, B., Hu, Z., Wang, X., Zhao, P., Zhao, Y., & Xiao, W. (2016). Study on spontaneous combustion rule of gangue dump and its comprehensive control measures. Mining Safety & Environmental Protection, 43(01), 92–95. https://doi.org/10.3969/j.issn.1008-4495.2016.01.024
Wei, Y., Zhou, C., Wang, J., Fan, Z., & Liu, G. (2017). Distribution and ecological risk assessment of 6 typical trace elements in mining soils in Huainan coalfield. Journal of University of Science and Technology of China, 47(05), 413–420. https://doi.org/10.3969/j.issn.0253-2778.2017.05.006
Xu, P., Zhu, J., Fu, Q., Chen, J., Hu, H., & Huang, Q. (2018). Structure and biodegradability of dissolved organic matter from Ultisol treated with long-term fertilizations. Journal of Soils and Sediments, 18(5), 1865–1872. https://doi.org/10.1007/s11368-018-1944-0
Yang, F., Yun, Y., Li, G., & Sang, N. (2021). Heavy metals in soil from gangue stacking areas increases children health risk and causes developmental neurotoxicity in zebrafish larvae. Science of the Total Environment, 794, 148629. https://doi.org/10.1016/j.scitotenv.2021.148629
Zeng, F., Ali, S., Zhang, H., Ouyang, Y., Qiu, B., Wu, F., & Zhang, G. (2011). The influence of pH and organic matter content in paddy soil on heavy metal availability and their uptake by rice plants. Environmental Pollution, 159(1), 84–91. https://doi.org/10.1016/j.envpol.2010.09.019
Zerizghi, T., Guo, Q., Tian, L., Wei, R., & Zhao, C. (2022). An integrated approach to quantify ecological and human health risks of soil heavy metal contamination around coal mining area. Science of the Total Environment, 814, 152653. https://doi.org/10.1016/j.scitotenv.2021.152653
Zhang, L., Han, G., Chen, H., & MaGuo, M. H. (2008). Study on heavy metal contaminants in soil come from coal mining spoil in the Loess Plateau. Journal of China Coal Society, 33(10), 1141–1146. https://doi.org/10.3321/j.issn:0253-9993.2008.10.013
Zhang, S., Wu, L., Zhang, G., Wang, D., & Wu, P. (2022). Soil heavy metal pollution analysis and health risk assessment in Karst areas along the upper reaches of the Du Liujiang River. Acta Scientiae Circumstantiae, 42(07), 421–433. https://doi.org/10.13671/j.hjkxxb.2021.0474
Zhang, M., Yue, X., & Yang, S. (2011). Characteristics of heavy metals release from coal waste and potential ecological risk assessment of contaminated soil around coal waste piles. Journal of Soil and Water Conservation, 25(04), 249–252. https://doi.org/10.13870/j.cnki.stbcxb.2011.04.002
Zhang, H., Zhang, F., Song, J., Tan, M. L., Kung, H. T., & Johnson, V. C. (2021). Pollutant source, ecological and human health risks assessment of heavy metals in soils from coal mining areas in Xinjiang, China. Environmental Research, 202, 111702. https://doi.org/10.1016/j.envres.2021.111702
Zhang, L., Peng, X., Ma, Y., Kang, L., Zhang, Y.-E., Wang, Q., & Zhang, S. (2022). Risk assessment and attribution analysis of “Five Toxic” heavy metals in cultivated land in Lanzhou. Environmental Science and Pollution Research, 43(9), 4767–4778. https://doi.org/10.13227/j.hjkx.202112226
Zhang, Z. (2018). Heavy metal pollution on farmlands and near coal mines in Minzhong region. Fujian Journal of Agricultural Sciences, 33(07), 739–743. https://doi.org/10.19303/j.issn.1008-0384.2018.07.016
Zhou, T., & Zhou, Z. (2018). Effects of lead exposure and co-exposure with other heavy metals on children’s neurodevelopment. Journal of Environmental and Occupational Medicine, 35(1), 73–77. https://doi.org/10.13213/j.cnki.jeom.2018.17404
Zhou, N., Yao, Y., Song, W., He, Z., Meng, G., & Liu, Y. (2020). Present situation and prospect of coal gangue treatment technology. Journal of Mining & Safety Engineering, 43(01), 92–95. https://doi.org/10.13545/j.cnki.jmse.2020.01.015
Acknowledgements
The paper has been supported by the key fund of Shaanxi Key Laboratory of Coal Green Development Geological Security (DZBZ2022Z-03) and the planned project of Hebei Academy of Sciences (19108). Thanks to Yanjie Zhang, an engineer from the Institute of Geographic Sciences, Hebei Academy of Sciences, for his support to relevant field research and indoor experiments.
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This work was supported by the key fund of Shaanxi Key Laboratory of Coal Green Development Geological Security (DZBZ2022Z-03) and the planned project of Hebei Academy of Sciences (19108).
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SS contributed to conceptualization, methodology and writing–review and editing; RP was involved in methodology, software drawing, data curation, writing—original draft, and experiment; YW contributed to investigation, software drawing and experiment; XC was involved in investigation and writing—review and editing; and RN and HR contributed to writing—review and editing. All the authors reviewed the manuscript.
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Song, S., Peng, R., Wang, Y. et al. Spatial distribution characteristics and risk assessment of soil heavy metal pollution around typical coal gangue hill located in Fengfeng Mining area. Environ Geochem Health 45, 7215–7236 (2023). https://doi.org/10.1007/s10653-023-01530-x
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DOI: https://doi.org/10.1007/s10653-023-01530-x