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Contamination characteristics of trace metals in dust from different levels of roads of a heavily air-polluted city in north China

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Abstract

Concentrations of eight trace metals (TMs) in road dust (RD) (particles < 25 μm) from urban areas of Xinxiang, China, were determined by inductively coupled plasma mass spectrometry. The geometric mean concentrations of Zn, Mn, Pb, As, Cu, Cr, Ni and Cd were 489, 350, 114, 101, 60.0, 39.7, 31.6, and 5.1 mg kg−1, respectively. When compared with TM levels in background soil, the samples generally display elevated TM concentrations, except for Cr and Mn, and for Cd the enrichment value was 69.6. Spatial variations indicated TMs in RD from park path would have similar sources with main roads, collector streets and bypasses. Average daily exposure doses of the studied TMs were about three orders of magnitude higher for hand-to-mouth ingestion than dermal contact, and the exposure doses for children were 9.33 times higher than that for adults. The decreasing trend of calculated hazard indexes (HI) for the eight elements was As > Pb > Cr > Mn > Cd > Zn > Ni > Cu for both children and adults.

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References

  • Adachi, K., & Tainosho, Y. (2004). Characterization of heavy metal particles embedded in tire dust. Environment International, 30, 1009–1017.

    Article  CAS  Google Scholar 

  • Akhter, M. S., & Madany, I. M. (1993). Heavy metals in street and house dust in Bahrain. Water, Air, and Soil pollution, 66, 111–119.

    Article  CAS  Google Scholar 

  • Ali, M. U., Liu, G., Yousaf, B., Abbas, Q., Ullah, H., Munir, M. A. M., et al. (2017). Pollution characteristics and human health risks of potentially (eco)toxic elements (PTEs) in road dust from metropolitan area of Hefei, China. Chemosphere, 181, 111–121.

    Article  CAS  Google Scholar 

  • Al-Khashman, O. A. (2007). Determination of metal accumulation in deposited street dusts in Amman, Jordan. Environmental Geochemistry and Health, 29, 1–10.

    Article  CAS  Google Scholar 

  • Al-Shayep, S. M., & Seaward, M. R. D. (2001). Heavy metal content of roadside soils along ring road in Riyadh (Saudi Arabia). Asian Journal of Chemistry, 13, 407–423.

    Google Scholar 

  • Anna, Bourliva, Christophoros, Christophoridis, Lambrini, Papadopoulou, Katerina, Giouri, Argyrios, Papadopoulos, Elena, Mitsika, et al. (2016). Characterization, heavy metal content and health risk assessment of urban road dusts from the historic center of the city of Thessaloniki, Greece. Environmental Geochemistry and Health, 39, 611–634.

    Google Scholar 

  • Arslan, H. (2001). Heavy metals in street dust in Bursa, Turkey. Journal of Trace and Microprobe Techniques, 19, 439–445.

    Article  CAS  Google Scholar 

  • Cao, Z. G., Yu, G., Chen, Y. S., Cao, Q. M., Fiedler, H., Deng, S. B., et al. (2012). Particle size: A missing factor in risk assessment of human exposure to toxic chemicals in settled indoor dust. Environment International, 49, 24–30.

    Article  CAS  Google Scholar 

  • Cao, Z. G., Yu, G., Lu, X. Y., Wang, M. L., Li, Q. L., Feng, J. L., et al. (2016). Particle size distribution, seasonal variation characteristics and human exposure assessment of heavy metals in typical settled dust from Beijing. Environmental Science, 37, 1272–1278.

    Google Scholar 

  • Charlesworth, S., Everett, M., McCarthy, R., Ordóñez, A., & de Miguel, E. (2003). A comparative study of heavy metal concentration and distribution in deposited street dusts in a large and a small urban area: Birmingham and Coventry, West Midlands, UK. Environment International, 29, 563–573.

    Article  CAS  Google Scholar 

  • China-National-Environmental-Monitoring-Centre. (1990). The soil background values of China (pp. 330–382). Beijing: China Environmental Science Press.

    Google Scholar 

  • Choate, L. D., Ranville, J. F., Bunge, A. L., & Macalady, D. L. (2006). Dermally adhered soil: 1. Amount and particle-size distribution. Integrated Environmental Assessment and Management, 2, 375–384.

    Article  CAS  Google Scholar 

  • Duzgoren-Aydin, N. S., Wong, C. S. C., Aydin, A., Song, Z., You, M., & Li, X. D. (2006). Heavy metal contamination and distribution in the urban environment of Guangzhou, SE China. Environmental Geochemistry and Health, 28, 375–391.

    Article  CAS  Google Scholar 

  • Frederiksen, M., Vorkamp, K., Thomsen, M., & Knudsen, L. E. (2009). Human internal and external exposure to PBDEs—A review of levels and sources. International Journal of Hygiene and Environmental Health, 212, 109–134.

    Article  CAS  Google Scholar 

  • Guo, H., Ding, A. J., So, K. L., Ayoko, G., Li, Y. S., & Hung, W. T. (2009). Receptor modeling of source apportionment of Hong Kong aerosols and the implication of urban and regional contribution. Atmospheric Environment, 43, 1159–1169.

    Article  CAS  Google Scholar 

  • Hu, E. (2000). Environmental risk assessment and practical techniques and methods. Beijing: China Environmental Science Press. (in Chinese).

    Google Scholar 

  • Huang, S., Tu, J., Liu, H., Hua, M., Liao, Q., Feng, J., et al. (2009). Multivariate analysis of trace element concentrations in atmospheric deposition in the Yangtze River Delta, East China. Atmospheric Environment, 43, 5781–5790.

    Article  CAS  Google Scholar 

  • Jiries, A. G., Hussein, H. H., & Halaseh, Z. (2001). The quality of water and sediments of street runoff in Amman, Jordan. Hydrological Processes, 15, 815–824.

    Article  Google Scholar 

  • Johansson, C., Norman, M., & Burman, L. (2009). Road traffic emission factors for heavy metals. Atmospheric Environment, 43, 4681–4688.

    Article  CAS  Google Scholar 

  • Kong, S., Lu, B., Bai, Z., Zhao, X., Chen, L., Han, B., et al. (2011). Potential threat of heavy metals in re-suspended dusts on building surfaces in oilfield city. Atmospheric Environment, 45, 4192–4204.

    Article  CAS  Google Scholar 

  • Kovacik, J., Dudas, M., Hedbavny, J., & Martonfi, P. (2016). Dandelion Taraxacum linearisquameum does not reflect soil metal content in urban localities. Environmental Pollution, 218, 160–167.

    Article  CAS  Google Scholar 

  • Lin, Y., Fang, F., Wang, F., & Xu, M. (2015). Pollution distribution and health risk assessment of heavy metals in indoor dust in Anhui rural, China. Environmental Monitoring and Assessment, 187, 4763.

    Google Scholar 

  • Lu, X., Li, L. Y., Wang, L., Lei, K., Huang, J., & Zhai, Y. (2009). Contamination assessment of mercury and arsenic in roadway dust from Baoji, China. Atmospheric Environment, 43, 2489–2496.

    Article  CAS  Google Scholar 

  • Manno, E., Varrica, D., & Dongarrà, G. (2006). Metal distribution in road dust samples collected in an urban area close to a petrochemical plant at Gela, Sicily. Atmospheric Environment, 40, 5929–5941.

    Article  CAS  Google Scholar 

  • Men, C., Liu, R., Xu, F., Wang, Q., Guo, L., & Shen, Z. (2017). Pollution characteristics, risk assessment, and source apportionment of heavy metals in road dust in Beijing, China. The Science of the total environment, 612, 138–147.

    Article  Google Scholar 

  • Morawska, L., & Salthammer, T. (2003). Indoor environment—Airborne particles and settled dust. Weinheim: Wiley-VCH.

    Google Scholar 

  • Najmeddin, A., Keshavarzi, B., Moore, F., & Lahijanzadeh, A. (2017). Source apportionment and health risk assessment of potentially toxic elements in road dust from urban industrial areas of Ahvaz megacity, Iran. Environmental Geochemistry and Health. https://doi.org/10.1007/s10653-017-0035-2.

    Article  Google Scholar 

  • Offenberg, J. H., Eisenreich, S. J., Chen, L. C., Cohen, M. D., Chee, G., Prophete, C., et al. (2003). Persistent organic pollutants in the dusts that settled across lower Manhattan after September 11, 2001. Environmental Science and Technology, 37, 502–508.

    Article  CAS  Google Scholar 

  • Padoan, E., Rome, C., & Ajmone-Marsan, F. (2017). Bioaccessibility and size distribution of metals in road dust and roadside soils along a peri-urban transect. Science of the Total Environment, 601, 89–98.

    Article  Google Scholar 

  • Parka, S. S., & Kimb, Y. J. (2005). Source contributions to fine particulate matter in an urban atmosphere. Chemosphere, 59, 217–226.

    Article  Google Scholar 

  • Ruby, M. V., & Lowney, Y. W. (2012). Selective soil particle adherence to hands: Implications for understanding oral exposure to soil contaminants. Environmental Science and Technology, 46, 12759–12771.

    Article  CAS  Google Scholar 

  • Soltani, N., Keshavarzi, B., Moore, F., Tavakol, T., Lahijanzadeh, A. R., Jaafarzadeh, N., et al. (2015). Ecological and human health hazards of heavy metals and polycyclic aromatic hydrocarbons (PAHs) in road dust of Isfahan metropolis. Iran. Science of the Total Environment, 505, 712–723.

    Article  CAS  Google Scholar 

  • Sulaiman, F. R., Bakri, N. I., Nazmi, N., & Latif, M. T. (2017). Assessment of heavy metals in indoor dust of a university in a tropical environment. Environmental forensics, 18, 74–82.

    Article  CAS  Google Scholar 

  • USEPA. (2002). Supplemental guidance for developing soil screening levels for superfund sites. Washington: US Environmental Protection Agency.

    Google Scholar 

  • Wang, X., & Feng, W. (2011). Granularity Analysis of road dust in Beijing. Environmental Sanitation Engineering, 19, 2.

    Google Scholar 

  • Wang, J., Li, S., Cui, X., Li, H., Qian, X., Wang, C., et al. (2016). Bioaccessibility, sources and health risk assessment of trace metals in urban park dust in Nanjing, Southeast China. Ecotoxicology and Environmental Safety, 128, 161–170.

    Article  CAS  Google Scholar 

  • Yu, L., Wang, G., Zhang, R., Zhang, L., Song, Y., Wu, B., et al. (2013). Characterization and source apportionment of PM2.5 in an urban environment in Beijing. Aerosol and Air Quality Research, 13, 574–583.

    Article  CAS  Google Scholar 

  • Yuan, G.-L., Sun, T.-H., Han, P., Li, J., & Lang, X.-X. (2014). Source identification and ecological risk assessment of heavy metals in topsoil using environmental geochemical mapping: Typical urban renewal area in Beijing, China. Journal of Geochemical Exploration, 136, 40–47.

    Article  CAS  Google Scholar 

  • Zhang, M., Buekens, A., & Li, X. (2016). Brominated flame retardants and the formation of dioxins and furans in fires and combustion. Journal of Hazardous Materials, 304, 26–39.

    Article  CAS  Google Scholar 

  • Zhang, J., Hua, P., & Krebs, P. (2017). Influences of land use and antecedent dry-weather period on pollution level and ecological risk of heavy metals in road-deposited sediment. Environmental Pollution, 228, 158–168.

    Article  CAS  Google Scholar 

  • Zhang, F., Zhao, S., Wang, S., Zhu, H., & Yang, Z. (2014). Pollution status and health risk assessment of heavy metals in street dust of Xinxiang. Journal of Environmental Health, 31, 435–437.

    CAS  Google Scholar 

  • Zhao, H., & Li, X. (2013a). Risk assessment of metals in road-deposited sediment along an urban–rural gradient. Environmental Pollution, 174, 297–304.

    Article  CAS  Google Scholar 

  • Zhao, H., & Li, X. (2013b). Understanding the relationship between heavy metals in road-deposited sediments and washoff particles in urban stormwater using simulated rainfall. Journal of Hazardous Materials, 246–247, 267–276.

    Article  Google Scholar 

  • Zhao, H., Li, X., Wang, X., & Tian, D. (2010). Grain size distribution of road-deposited sediment and its contribution to heavy metal pollution in urban runoff in Beijing, China. Journal of Hazardous Materials, 183, 203–210.

    Article  CAS  Google Scholar 

  • Zhao, H., Wang, X., & Li, X. (2017). Quantifying grain-size variability of metal pollutants in road-deposited sediments using the coefficient of variation. International Journal of Environmental Research and Public Health, 14, 850.

    Article  Google Scholar 

  • Zhao, H., Zhao, J., Yin, C., & Li, X. (2014). Index models to evaluate the potential metal pollution contribution from washoff of road-deposited sediment. Water Research, 59, 71–79.

    Article  CAS  Google Scholar 

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Acknowledgements

The research is supported by National Natural Science Foundation of China (21607038), China Postdoctoral Science Foundation (2015M570629, 2016T90668), the Scientific Research Starting Foundation (5101219170102) and Science Foundation (5101219279007) of Henan Normal University and Science and Technology Research Project of Henan Province (162102110090).

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Correspondence to Mohai Shen or Jianhui Sun.

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Cao, Z., Chen, Q., Wang, X. et al. Contamination characteristics of trace metals in dust from different levels of roads of a heavily air-polluted city in north China. Environ Geochem Health 40, 2441–2452 (2018). https://doi.org/10.1007/s10653-018-0110-3

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