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Ecological conditions of ponds situated on blast furnace slag deposits located in South Gare Site of Special Scientific Interest (SSSI), Teesside, UK

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Abstract

Slag, a by-product from the iron and steel industry, has a range of applications within construction and is used in wastewater treatment. Historically considered a waste material, little consideration was given to the environmental impacts of its disposal. South Gare (a Site of Special Scientific Interest) located at the mouth of the Tees estuary, UK, formed on slag deposits used to create a sea wall and make the land behind permanent. Over time, ponds formed in depressions with the water chemistry, being significantly impacted by the slag deposits. Calcium levels reached 504 mg/L, nitrate 49.0 mg/L and sulphate 1,698 mg/L. These levels were also reflected in the composition of the sediment. pH (5.10–9.90) and electrical conductivity (2,710–3,598 µS/cm) were variable but often notably high. Pb, Cu and Cd were not present within the water, whilst Zn ranged from 0.027 to 0.37 mg/L. Heavy metal levels were higher in surface sediments. Zinc was most dominant (174.3–1,310.2 mg/L) followed by Pb (9.9–431 mg/L), Cu (8.4–41.8 mg/L) and Cd (0.4–1.1 mg/L). A sediment core provided a historical overview of the ponds. The ponds were unfavourable for aquatic biodiversity and unsuitable for drinking water abstraction.

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References

  • Bayless, B. E. R., Greeman, T. K., & Harvey, C. C. (1998). Hydrology and geochemistry of a slag-affected aquifer and chemical characteristics of slag-affected ground water. Indianapolis, Indiana: Northwestern Indiana and Northeastern Illinois.

    Google Scholar 

  • Bayless, E. R., & Schulz, M. S. (2003). Mineral precipitation and dissolution at two slag-disposal sites in northwestern Indiana, USA. Environmental Geology, 45, 252–261.

    Article  CAS  Google Scholar 

  • Beeby, A. (1993). Applying ecology. Great Britain: Chapman & Hall.

    Google Scholar 

  • Camargo, J. A., Alonso, A., & Salamanca, A. (2005). Nitrate toxicity to aquatic animals: A review with new data for freshwater invertebrates. Chemosphere, 58, 1255–1267.

    Article  CAS  Google Scholar 

  • Céréghino, R. et al. (2008). The ecology of European ponds: Defining the characteristics of a neglected freshwater habitat. Hydrobiologia, 597(1), 1–6. http://link.springer.com/10.1007/s10750-007-9225-8. Accessed March 22, 2014.

  • Conti, M. E. (Ed.). (2008). Biological monitoring: Theory and applications, Southampton, UK: WIT Press.

  • Croudace, I. W., Rindby, A., & Rothwell, R. G. (2006). ITRAX: Description and evaluation of a new multi-function X-ray core scanner. Geological Society, London, Special Publications, 267, 51–63. doi:10.1144/GSL.SP.2006.267.01.04.

  • Davies, B. R. et al. (2008). A comparison of the catchment sizes of rivers, streams, ponds, ditches and lakes: implications for protecting aquatic biodiversity in an agricultural landscape. Hydrobiologia, 597(1), 7–17. http://link.springer.com/10.1007/s10750-007-9227-6. Accessed March 21, 2014.

  • Davies, T. D., Pickard, J. S., & Hall, K. J. (2003). Sulphate toxicity ot freshwater organisms and molybdenum toxicity to Rainbow Trout embryos/alevins. http://hdl.handle.net/2429/8807.

  • Drake, M., Williams, P., Biggs, J., & Whitefield, M. (1996). Managing ponds for wildlife. Peterborough: English Nature.

  • English Nature, Site notified to the Secretary of State on 19 October 1988 County: Cleveland Site Name: South Gare and Coatham Sands. http://www.english-nature.org.uk/citation/citation_photo/1000178.pdf. Accessed August 22, 2009.

  • Environment Agency. (2007). Blast furnace slag (BFS): A technical report on the manufacturing of blast furnace slag and material status in the UK. http://www.handapp.co.uk/web/BF%20Slag%20%20a%20technical%20report%20on%20manufacturing%20of%20BF%20Slag%20&%20material%20status%20in%20UK.pdf.

  • Environment Agency. (2014). Environment agency quality protocol for steel slag consultation. https://consult.environment-agency.gov.uk/portal/ho/waste/quality_protocol/steel_slag?pointId=2837038. Accessed July 27, 2014.

  • European Community. (1975). Council Directive of 16 June 1975 concerning the quality of surface water intended for the abstraction of drinking water in the Member States. http://faolex.fao.org/cgi-bin/faolex.exe?rec_id=015478&database. Accessed January 5, 2010.

  • Farmer, J. G. (1991). The perturbation of historical pollution records in aquatic sediments. Environmental Geochemistry and Health, 13(2), 76–83.

    Article  CAS  Google Scholar 

  • Gupta, V. K., et al. (1997). Process development for the removal of zinc and cadmium from wastewater using slag—A blast furnace waste material. Separation Science and Technology, 32(17), 2883–2912.

    Article  CAS  Google Scholar 

  • Harrison, J. K., & Almond, J. K. (1978). Industrial archaeology in Cleveland—A guide. Great Britain: The Cleveland Industrial Archaeology Society.

    Google Scholar 

  • Korkusuz, E., Beklioglu, M., & Demirer, G. N. (2005). Comparison of the treatment performances of blast furnace slag-based and gravel-based vertical flow wetlands operated identically for domestic wastewater treatment in Turkey. Ecological Engineering, 24, 187–200.

    Article  Google Scholar 

  • Lind, O. T. (1985). Handbook of common methods in Limnology (2nd ed.). USA: Kendall/Hunt Publishing Company.

    Google Scholar 

  • Mayes, W. M., Younger, P. L., & Aumônier, J. (2008). Hydrogeochemistry of Alkaline Steel Slag Leachates in the UK. Water, Air, and Soil pollution, 195(1–4), 35–50.

    Article  CAS  Google Scholar 

  • NSA. (2013). Common uses for slag. http://www.nationalslag.org/common-uses-slag. Accessed April 30, 2014.

  • Oertli, B. et al. (2005). Conservation and monitoring of pond biodiversity: Introduction. Aquatic Conservation: Marine and Freshwater Ecosystems, 15(6), 535–540. doi:10.1002/aqc.752. Accessed March 21, 2014.

  • Piatak, N. M., Parsons, M. B., & Seal, R. R. I. (2014). Characteristics and environmental aspects of slag: A review. Applied Geochemistry. doi:10.1016/j.apgeochem.2014.04.009.

  • Pollard, A. I., & Yuan, L. (2009). Community response patterns: Evaluating benthic invertebrate composition in metal-polluted streams. Ecological Applications, 16(2), 645–655.

    Article  Google Scholar 

  • Roadcap, G. S., Kelly, W. R., & Bethke, C. M. (2005). Geochemistry of extremely alkaline (pH < 12) ground water in slag-fill aquifers. Ground Water, 43(6), 806–816.

    Article  CAS  Google Scholar 

  • Rosenberg, D. M., & Resh, V. H. (Eds.). (1993). Freshwater biomonitoring and benthic macroinvertebrates. New York: Chapman & Hall.

    Google Scholar 

  • Shilton, A. N., et al. (2006). Phosphorus removal by an “active” slag filter—A decade of full scale experience. Water Research, 40, 113–118.

    Article  CAS  Google Scholar 

  • Singer, M. J., & Munns, D. N. (1996). Soils an introduction (3rd ed.). USA: Prentice-Hall Inc.

    Google Scholar 

  • Tees Conservancy Commissioners. (1906). Ports of the river tees [online]. Great Britain: The Tees Conservancy Commissioners.

    Google Scholar 

  • Vareschi, E. (1979). The ecology of Lake Nakuru (Kenya). II. Biomass and spatial distribution of fish (Tilapia grahami Boulenger = Sarotherodon alcalicum grahami Boulenger). Oecologia, 37(3), 321–335.

    Article  Google Scholar 

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Acknowledgments

This work was supported by Tata Steel and Industry Nature Conservation Association (INCA) operating in the Tees Valley. With Special thanks to INCA members Ken Smith (MBE. JP. MPhil. MRSC), Dr. Robert Woods and Bob Pailor (MBE) for their support during the work.

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Correspondence to A. Soares.

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Raper, E., Davies, S., Perkins, B. et al. Ecological conditions of ponds situated on blast furnace slag deposits located in South Gare Site of Special Scientific Interest (SSSI), Teesside, UK. Environ Geochem Health 37, 545–556 (2015). https://doi.org/10.1007/s10653-014-9672-x

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