A study of the chemical composition of polar compounds from seeds of Trigonella caerulea (L.) Ser. (Fabaceae) revealed the presence of monosaccharides (2 and 3); oligosaccharides (4–7); pinitol (8) and galactopinitols (1 and 9–11), including the new compound 1; glycosides of diosgenin (12–15); and alkaloids (16–22). Mass spectrometry, chemical transformations, and NMR spectroscopy established that 1 was O-(α-Dgalactopyranosyl)-(1→6)-O-(α-D-galactopyranosyl)-(1→6)-O-(α-D-galactopyranosyl)-(1→6)-O-(α-Dgalactopyranosyl)-(1→2)-4-O-methyl-chiro-inositol (tetragalactopinitol A).
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The research was supported by the Ministry of Science and Higher Education of the Russian Federation (Project No. 121030100227-7).
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Translated from Khimiya Prirodnykh Soedinenii, No. 6, November–December, 2023, pp. 878–881.
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Olennikov, D.N. New Galactopinitol from Seeds of Trigonella caerulea. Chem Nat Compd 59, 1038–1041 (2023). https://doi.org/10.1007/s10600-023-04191-5
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DOI: https://doi.org/10.1007/s10600-023-04191-5