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Synthesis of 28-homobrassinosteroids modified in the 26-position

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Chemistry of Natural Compounds Aims and scope

28-Homobrassinosteroids modified in the 26-position were synthesized from 22-hydroxy-23-ensteroids using Claisen rearrangement and subsequent cis-hydroxylation of the resulting Δ22-derivative.

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Authors and Affiliations

  1. Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus, 220141, Minsk, ul. Kuprevicha, 5/2, Belarus

    R. P. Litvinovskaya, M. E. Raiman & V. A. Khripach

Authors
  1. R. P. Litvinovskaya
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  2. M. E. Raiman
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  3. V. A. Khripach
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Correspondence to R. P. Litvinovskaya.

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Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 544–548, September–October, 2009.

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Litvinovskaya, R.P., Raiman, M.E. & Khripach, V.A. Synthesis of 28-homobrassinosteroids modified in the 26-position. Chem Nat Compd 45, 647–652 (2009). https://doi.org/10.1007/s10600-009-9439-2

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  • DOI: https://doi.org/10.1007/s10600-009-9439-2

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