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Beckmann rearrangement of 11-deoxo-glycyrrhetic acid 3-ketoxime

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Chemistry of Natural Compounds Aims and scope

A-Homo-4-aza-3-oxo- and 3-cyano-3,4-seco-olean-4,12-diene derivatives of 11-deoxo-glycyrrhetic acid were synthesized by first- and second-order Beckmann rearrangement of 3-hydroxyiminoolean-12-en-30-oic acid methyl ester.

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Acknowledgment

The work was supported financially by the RFBR (Grant 08-03-00366a).

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, 450054, prosp. Oktyabrya, 71, Ufa, Russia

    L. R. Mikhailova, M. V. Khudobko, L. A. Baltina Jr. & L. A. Baltina

Authors
  1. L. R. Mikhailova
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  2. M. V. Khudobko
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  3. L. A. Baltina Jr.
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  4. L. A. Baltina
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Corresponding author

Correspondence to M. V. Khudobko.

Additional information

Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 441–443, July–August, 2009.

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Mikhailova, L.R., Khudobko, M.V., Baltina, L.A. et al. Beckmann rearrangement of 11-deoxo-glycyrrhetic acid 3-ketoxime. Chem Nat Compd 45, 519 (2009). https://doi.org/10.1007/s10600-009-9395-x

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  • DOI: https://doi.org/10.1007/s10600-009-9395-x

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