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Chemistry of Natural Compounds

, Volume 44, Issue 6, pp 724–727 | Cite as

Oxidation of secondary terpene alcohols by chlorine dioxide

  • L. L. FrolovaEmail author
  • A. V. Popov
  • S. A. Rubtsova
  • A. V. Kuchin
Article

Secondary terpene alcohols cis- and trans-verbenol, neo-iso-verbanol, borneol, iso-borneol, and menthol were oxidized by chlorine dioxide into the corresponding ketones. It was shown that the nature of the solvent and catalyst and the structure of the starting compound, including the stereochemistry of the hydroxyl, influenced the oxidation process.

Key words

cis- and trans-verbenol neo-iso-verbanol borneol iso-borneol menthol chlorine dioxide oxidation catalysts 

Notes

Acknowledgment

The work was supported by the RF President (Program of Support for Leading Scientific Schools, Grant NSh-4028.2008.3) and the Russian Foundation for Basic Research (Grant No. 05-03-33005).

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Copyright information

© Springer Science+Business Media, Inc. 2008

Authors and Affiliations

  • L. L. Frolova
    • 1
    Email author
  • A. V. Popov
    • 1
  • S. A. Rubtsova
    • 1
  • A. V. Kuchin
    • 1
  1. 1.Institute of Chemistry, Komi Scientific Center, Ural BranchRussian Academy of Sciences, Russian Federationul. PervomaiskayaRussia

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