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3,4-Bis(bromomethyl)furazan and its N-oxide

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Chemistry of Heterocyclic Compounds Aims and scope

The conditions for bromination of the methyl groups of dimethylglyoxime were found, and the resulting product, a 1,4-dioxane solvate of bis(bromomethyl)glyoxime, was used as a precursor for heterocyclizations involving cyclodehydration or oxidative cyclization of the oxime groups leading to the formation of furazan and furoxan rings, respectively.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave, Moscow, 119991, Russia

    Artem V. Khakhalev & Aleksei B. Sheremetev

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Ave, Moscow, 119991, Russia

    Aleksei А. Anisimov

Authors
  1. Artem V. Khakhalev
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  2. Aleksei А. Anisimov
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  3. Aleksei B. Sheremetev
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Correspondence to Aleksei B. Sheremetev.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2022, 58(4/5), 263–266

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Khakhalev, A.V., Anisimov, A.А. & Sheremetev, A.B. 3,4-Bis(bromomethyl)furazan and its N-oxide. Chem Heterocycl Comp 58, 263–266 (2022). https://doi.org/10.1007/s10593-022-03082-x

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  • DOI: https://doi.org/10.1007/s10593-022-03082-x

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