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New heterobimetallic ruthenium(II) complex with imidazo[4,5-f][1,10]phenanthroline-based ligand: synthesis, optical and electrochemical properties

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Chemistry of Heterocyclic Compounds Aims and scope

Ditopic ligand with coordination centers of different types was synthesized. Ligand contains 1,10-phenanthroline fragment for Ru(II) coordination and azadithiacrown ether moiety for Cu(II) cation binding. At first step, new ruthenium complex was synthesized and then its complexation with Cu(II) perchlorate was studied by optical and electrochemical means. The complex obtained in this work represents a rare type of bimetallic complexes, in which both cations are located in one ligand system, but their effect on each other is measurable.

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Financial support from the Russian Science Foundation (RSF № 20-73-00352) and equipment facilities from Center of collective facilities of the A. N. Nesmeyanov Institute of Organoelement compounds of Russian Academy of Sciences are gratefully acknowledged. There are no conflicts to declare.

Elemental analysis was performed in the A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences.

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  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova St, Moscow, 119991, Russia

    Sergey D. Tokarev, Anatoly Botezatu, Yurii V. Fedorov & Olga A. Fedorova

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  1. Sergey D. Tokarev
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  2. Anatoly Botezatu
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  3. Yurii V. Fedorov
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  4. Olga A. Fedorova
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Correspondence to Sergey D. Tokarev.

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Published in Khimiya Geterotsiklicheskikh Soedinenii, 2021, 57(7/8), 799–805

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Tokarev, S.D., Botezatu, A., Fedorov, Y.V. et al. New heterobimetallic ruthenium(II) complex with imidazo[4,5-f][1,10]phenanthroline-based ligand: synthesis, optical and electrochemical properties. Chem Heterocycl Comp 57, 799–805 (2021). https://doi.org/10.1007/s10593-021-02983-7

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