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Tetrakis(hydroxymethyl)glycoluril in N-methylenation reactions with arylamines

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Chemistry of Heterocyclic Compounds Aims and scope

This work shows for the first time the use of tetrakis(hydroxymethyl)glycoluril in the melt N-methylenation reactions of arylamines, based on the ability of tetrakis(hydroxymethyl)glycoluril to eliminate a formaldehyde molecule. It was shown by HPLC that tetrakis-(hydroxymethyl)glycoluril under the studied conditions is subject to dehydroxymethylation processes.

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Authors and Affiliations

  1. National Research Tomsk State University, 36 Lenina Ave, Tomsk, 634050, Russia

    Svetlana Yu. Panshina, Abdigali А. Bakibayev & Victor S. Malkov

  2. National Research Tomsk Polytechnic University, 30 Lenina Ave, Tomsk, 634050, Russia

    Svetlana Yu. Panshina

  3. L. N. Gumilyov Eurasian National University, 2 Sambaeva St., Nur-Sultan, Kazakhstan, 010000

    Oksana V. Ponomarenko

Authors
  1. Svetlana Yu. Panshina
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  2. Oksana V. Ponomarenko
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  3. Abdigali А. Bakibayev
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  4. Victor S. Malkov
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Corresponding author

Correspondence to Svetlana Yu. Panshina.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2020, 56(1), 112–115

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Panshina, S.Y., Ponomarenko, O.V., Bakibayev, A.А. et al. Tetrakis(hydroxymethyl)glycoluril in N-methylenation reactions with arylamines. Chem Heterocycl Comp 56, 112–115 (2020). https://doi.org/10.1007/s10593-020-02633-4

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  • DOI: https://doi.org/10.1007/s10593-020-02633-4

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