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Synthesis of novel N,O-macrocyclic ligands, functionalized by phosphine oxide groups

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Chemistry of Heterocyclic Compounds Aims and scope

As a result of the implementation of two approaches, the Pudovik reaction (the reaction of macrocyclic azomethines with secondary phosphine oxides) and the Kabachnik–Fields reaction (three-component one-pot process involving dialdehydes, diamines, and secondary phosphine oxides), novel N,O-containing macrocyclic ligands with phosphine oxide groups were first obtained. The synthesized macrocycles are a kind of α-aminophosphoryl compounds that can be used in the synthesis of supramolecular systems.

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Authors and Affiliations

  1. Higher School of Technology and Energy, Saint Petersburg State University of Industrial Technologies and Design, 4 Ivana Chernykh St., Saint Petersburg, 198095, Russia

    Elena А. Alexandrova, Kristina А. Lotsman & Yuri G. Trishin

  2. A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova St., Moscow, 119991, Russia

    Konstantin А. Lyssenko

Authors
  1. Elena А. Alexandrova
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  2. Kristina А. Lotsman
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  3. Konstantin А. Lyssenko
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  4. Yuri G. Trishin
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Corresponding author

Correspondence to Yuri G. Trishin.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2019, 55(9), 875–881

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Alexandrova, E.А., Lotsman, K.А., Lyssenko, K.А. et al. Synthesis of novel N,O-macrocyclic ligands, functionalized by phosphine oxide groups. Chem Heterocycl Comp 55, 875–881 (2019). https://doi.org/10.1007/s10593-019-02551-0

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  • DOI: https://doi.org/10.1007/s10593-019-02551-0

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