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Synthesis, spectral and electrochemical properties of halogenated 6-alkyl-5-aryl-1-(benzo[d]thiazol-2-yl)-3-phenylverdazyls and 5-aryl-1-(benzo[d]thiazol-2-yl)-3-phenyl-6-vinylverdazyls

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Chemistry of Heterocyclic Compounds Aims and scope

A sequence of alkylation, cyclization, and oxidation reactions was used to convert 5-aryl-1-(benzo[d]thiazol-2-yl)-3-phenylformazans into 6-alkyl-5-aryl-1-(benzo[d]thiazol-2-yl)-3-phenylverdazyls and 5-aryl-1-(benzo[d]thiazol-2-yl)-3-phenyl-6-vinylverdazyls. The paramagnetic and electrochemical properties of the obtained compounds were studied.

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This work was performed within the framework of State Assignment АААА-А19-119012290117-6 and received financial support from the Program of Ural Branch of the Russian Academy of Sciences (project 18-3-3-16), while using equipment at the Collective Use Center “Spectroscopy and Analysis of Organic Compounds” at the Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences.

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Authors and Affiliations

  1. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 S. Kovalevskoi / 20 Akademicheskaya St., Yekaterinburg, 620041, Russia

    Tatiana G. Fedorchenko, Galina N. Lipunova, Alexander V. Shchepochkin, Marina S. Valova & Pavel A. Slepukhin

  2. Ural Federal University named after the first President of Russia B. N. Yeltsin, 19 Mira St., Yekaterinburg, 620002, Russia

    Galina N. Lipunova, Alexander V. Shchepochkin, Anton N. Tsmokalyuk & Pavel A. Slepukhin

Authors
  1. Tatiana G. Fedorchenko
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  2. Galina N. Lipunova
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  3. Alexander V. Shchepochkin
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  4. Anton N. Tsmokalyuk
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  5. Marina S. Valova
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  6. Pavel A. Slepukhin
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Correspondence to Tatiana G. Fedorchenko.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2019, 55(6), 560–565

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Fedorchenko, T.G., Lipunova, G.N., Shchepochkin, A.V. et al. Synthesis, spectral and electrochemical properties of halogenated 6-alkyl-5-aryl-1-(benzo[d]thiazol-2-yl)-3-phenylverdazyls and 5-aryl-1-(benzo[d]thiazol-2-yl)-3-phenyl-6-vinylverdazyls. Chem Heterocycl Comp 55, 560–565 (2019). https://doi.org/10.1007/s10593-019-02496-4

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  • DOI: https://doi.org/10.1007/s10593-019-02496-4

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