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Synthesis and copolymerization of azidomethyl-substituted oxetanes: the morphology of statistical block copolymers

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Chemistry of Heterocyclic Compounds Aims and scope

3,3-Bis(azidomethyl)oxetane and 3-azidomethyl-3-methyloxetane were obtained by bromination of pentaerythritol and metriol with a mixture of hydrobromic, acetic, and sulfuric acids, followed by cyclization in the presence of a phase-transfer catalyst TBAB, with the formation of oxetane ring and replacement of bromide substituents with azide ions. The copolymerization reaction of 3,3-bis-(azidomethyl)oxetane and 3-azidomethyl-3-methyloxetane was performed in the presence of a catalytic system prepared from triisobutylaluminum and water. The methods of small-angle and wide-angle X-ray diffraction analysis were used to determine the amorphous-crystalline and domain structures of the synthesized copolymers. We also present data about conformational and relaxation transitions in these statistical copolymers.

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Authors and Affiliations

  1. Kazan National Research Technological University, 68 Karl Marx St., Kazan, 420015, Russia

    Timur I. Mukhametshin, Aleksei I. Petrov, Nina V. Kuznetsova, Vladimir A. Petrov, Natalia V. Averianova, Ilgiz Kh. Garaev & Anatoly V. Kostochko

  2. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, 8 Akademika Arbuzova St., Kazan, 420088, Russia

    Aidar T. Gubaidullin

  3. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow, 119991, Russia

    Dmitry B. Vinogradov & Pavel V. Bulatov

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  1. Timur I. Mukhametshin
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  2. Aleksei I. Petrov
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  3. Nina V. Kuznetsova
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Correspondence to Timur I. Mukhametshin.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2017, 53(6/7), 811–821

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Mukhametshin, T.I., Petrov, A.I., Kuznetsova, N.V. et al. Synthesis and copolymerization of azidomethyl-substituted oxetanes: the morphology of statistical block copolymers. Chem Heterocycl Comp 53, 811–821 (2017). https://doi.org/10.1007/s10593-017-2128-3

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