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3-Alkyl-4-nitrofurazans – plasticizers for polymers

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Chemistry of Heterocyclic Compounds Aims and scope

Oxidation of 4-alkylfurazan-3-amines to the corresponding nitrofurazans was achieved using mixtures of hydrogen peroxide. The volatility of the products as a function of the size of substituent R, has been studied. The phase and relaxation transitions were characterized and the thermodynamic compatibility with polyester urethane was established. The melting points and melting enthalpies of alkylnitrofurazans were determined.

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Specific parts of this work were performed with financial support from OKhNM-04 programs of the Russian Academy of Sciences.

The authors would like to express their gratitude to Dr. M. I. Struchkova (Institute of Organic Chemistry, Russian Academy of Sciences) for acquisition of NMR spectra and to the leading engineer N. N. Il'icheva (D. I. Mendeleev Russian Chemical Technology University) for her assistance with performing calorimetric measurements.

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Authors and Affiliations

  1. D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow, 125047, Russia

    Yury M. Lotmentsev, Natalya N. Kondakova & Artem V. Bakeshko

  2. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow, 119991, Russia

    Andrei M. Kozeev & Aleksei B. Sheremetev

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  1. Yury M. Lotmentsev
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  2. Natalya N. Kondakova
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Correspondence to Yury M. Lotmentsev.

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Supplementary information file containing thermograms of compounds 1а–f is available from the journal website at http://link.springer.com/journal/10593.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2017, 53(6/7), 740–745

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Lotmentsev, Y.M., Kondakova, N.N., Bakeshko, A.V. et al. 3-Alkyl-4-nitrofurazans – plasticizers for polymers. Chem Heterocycl Comp 53, 740–745 (2017). https://doi.org/10.1007/s10593-017-2120-y

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