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Chemistry of (dinitromethyl)azines

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Chemistry of Heterocyclic Compounds Aims and scope

This review covers the methods applicable for the synthesis of (dinitromethyl)azines: nitration of azine derivatives, azine ring formation,nucleophilic su bstitution in azine rings by the action of dinitrocarbanions, and denitration of trinitromethylazines. Further reactions with the conservation of dinitromethyl group, as well as its transformations into other functional groups, or modification of other substituents in (dinitromethyl)azines are also considered. Dinitromethylazines are of interest as energetic materials with low sensitivity and as biologically active compounds.

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  1. Samara State Technical University, 244 Molodogvardeiskaya St., Samara, 443100, Russia

    Vladimir V. Bakharev, Alexander A. Gidaspov & Victor E. Parfenov

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  1. Vladimir V. Bakharev
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2017, 53(6/7), 659–669

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Bakharev, V.V., Gidaspov, A.A. & Parfenov, V.E. Chemistry of (dinitromethyl)azines. Chem Heterocycl Comp 53, 659–669 (2017). https://doi.org/10.1007/s10593-017-2107-8

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