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3-(Nitromethyl)-3,4-dihydroquinoxalin-2(1H)-ones: synthesis and structure

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Chemistry of Heterocyclic Compounds Aims and scope

Reactions of ethyl 3-nitroacrylate with o-phenylenediamine and its substituted derivatives were used for the synthesis of 3-(nitromethyl)-3,4-dihydroquinoxalin-2(1H)-ones, followed by structural characterization. These compounds were found to undergo elimination of nitromethane, leading to quinoxalin-2(1H)-ones.

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This work received financial support from the Ministry of Education and Science of Russian Federation, within the framework of baseline of the State Assignment.

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Authors and Affiliations

  1. Herzen State Pedagogical University of Russia, 48 Moyka River Embankment, Saint Petersburg, 191186, Russia

    Vasilii V. Pelipko, Sergey V. Makarenko, Valentina M. Berestovitskaya & Ruslan I. Baichurin

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  1. Vasilii V. Pelipko
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  2. Sergey V. Makarenko
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  3. Valentina M. Berestovitskaya
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  4. Ruslan I. Baichurin
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Correspondence to Valentina M. Berestovitskaya.

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Supplementary information file containing spectral data for the synthesized compounds is available at http://link.springer.com/journal/10593.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2016, 52(8), 574–577

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Pelipko, V.V., Makarenko, S.V., Berestovitskaya, V.M. et al. 3-(Nitromethyl)-3,4-dihydroquinoxalin-2(1H)-ones: synthesis and structure. Chem Heterocycl Comp 52, 574–577 (2016). https://doi.org/10.1007/s10593-016-1934-3

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  • DOI: https://doi.org/10.1007/s10593-016-1934-3

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