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The structure of product from an unusual cyclization of 2,2'-methylenedicyclohexanone diphenylhydrazone

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Chemistry of Heterocyclic Compounds Aims and scope

Heating of 2,2'-methylenedicyclohexanone diphenylhydrazone in diethylene glycol was shown to result in unexpected formation of a bridged polyheterocyclic compound with a previously unknown skeleton, the structure of which was established by spectral methods and X-ray structural analysis. An explanation has been provided for the peculiar course of this reaction leading to a tetracyclic product.

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Authors and Affiliations

  1. Far Eastern Federal University, 8 Suhanova St., Vladivostok, 690950, Russia

    Taisiya V. Moskovkina

  2. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, 159 100-letiya Vladivostoka Ave., Vladivostok, 690022, Russia

    Kseniya A. Gaivoronskaya

  3. G. B. Elyakov Pacific Institute of Bioorganic Chemistry, Far Eastern Branch, Russian Academy of Sciences, 159 100-letiya Vladivostoka St., Vladivostok, 690022, Russia

    Anatoly I. Kalinovskii & Ekaterina G. Lyakhova

Authors
  1. Taisiya V. Moskovkina
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  2. Kseniya A. Gaivoronskaya
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  3. Anatoly I. Kalinovskii
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  4. Ekaterina G. Lyakhova
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Corresponding authors

Correspondence to Taisiya V. Moskovkina or Ekaterina G. Lyakhova.

Additional information

The Supplementary information file containing spectra and the complete X-ray structural dataset for compound 6 is available for the authorized users.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2015, 51(8), 769–771

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Moskovkina, T.V., Gaivoronskaya, K.A., Kalinovskii, A.I. et al. The structure of product from an unusual cyclization of 2,2'-methylenedicyclohexanone diphenylhydrazone. Chem Heterocycl Comp 51, 769–771 (2015). https://doi.org/10.1007/s10593-015-1773-7

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  • DOI: https://doi.org/10.1007/s10593-015-1773-7

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