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2-Halo-2-organyl-4H-benzo[d][1,3,2]dioxasilin-4-ones

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Chemistry of Heterocyclic Compounds Aims and scope

Original method has been developed for the preparation of previously unknown cyclic organosilicon esters of salicylic acid, containing halogen–silicon bonds. This method is based on the reaction of trimethylsilyl ester of 2-(trimethylsiloxy)benzoic acid with organylhalosilanes RR1SiXY under mild conditions, where R, R1 = Cl, Me, CH=CH2, Ph; X, Y = Cl, F.

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Notes

  1. Maintaining PhOSiMe3 and PhSiCl3 in a sealed ampoule for one month at 20–25°С.

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This work received financial support from the Grants Council of the President of the Russian Federation (grant NSh-3649.2014.3). The main results were obtained by using the instruments at the Baikal Analytical Collective Use Center of the Siberian Branch of the Russian Academy of Sciences.

The autors would like to acknowledge the assistance by I. A. Gebel' and D. A. Shabalin in performing this work.

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Correspondence to Sergey V. Basenko.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2015, 51(3), 295–298

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Basenko, S.V., Zelenkov, L.E. 2-Halo-2-organyl-4H-benzo[d][1,3,2]dioxasilin-4-ones. Chem Heterocycl Comp 51, 295–298 (2015). https://doi.org/10.1007/s10593-015-1698-1

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