The interaction of norbornene with the di(2-pyridyl) ditelluride–antimony pentachloride system in methylene chloride proceeds with the formation of exo-9-telluro-3-azoniatetracyclo-[9.2.1.02.10.03,8]tetradeca-3(8),4,6-triene chloroantimonates(III), which are the products of polar cycloaddition of tellurium-containing electrophiles at the multiple bond. The structure of the heterocyclization products was established by X-ray structural analysis.
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Translated from Chemistry of Heterocyclic Compounds, No. 7, pp. 1167–1171, July, 2012.
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Borisov, A.V., Matsulevich, Z.V., Osmanov, V.K. et al. Cycloaddition of di(2-pyridyl) ditelluride to norbornene stimulated by antimony pentachloride. Chem Heterocycl Comp 48, 1085–1089 (2012). https://doi.org/10.1007/s10593-012-1103-2
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DOI: https://doi.org/10.1007/s10593-012-1103-2