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Synthesis of 1H-1,5,7-triazacyclopenta[c,d]phenalenes by the electrophilic amination of perimidines using sodium azide in PPA

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Chemistry of Heterocyclic Compounds Aims and scope

A method was developed for the synthesis of 1H-1,5,7-triazacyclopenta[c,d]phenalenes by the electrophilic amination of perimidines using the new sodium azide/PPA reagent system and a subsequent one-pot reaction with 1,3,5-triazines. A multicomponent variant of this reaction is possible in the case of 2,4,6-trimethyl- and 2,4,6-triphenyl-1,3,5-triazines.

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Correspondence to A. V. Aksenov.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1563-1568, October, 2010.

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Aksenov, A.V., Lyakhovnenko, A.S. & Andrienko, A.V. Synthesis of 1H-1,5,7-triazacyclopenta[c,d]phenalenes by the electrophilic amination of perimidines using sodium azide in PPA. Chem Heterocycl Comp 46, 1266–1270 (2011). https://doi.org/10.1007/s10593-011-0662-y

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  • DOI: https://doi.org/10.1007/s10593-011-0662-y

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